Basf Se Corporation

Bernd Zoels

Grigorios Kolios

Jens Bernnat

Friedrich Glenk

Dirk Klingler

Matthias Kern

Gerhard Olbert

Rene Koenig

Frederik Scheiff

Achim Wechsung

Stephan Andreas Schunk

Bilge Yilmaz

Andreas Bode

Heinrich Laib

Dieter Flick

Christopher Alec Anderlohr

Hagen Appel

Dirk Grossschmidt

Guido Wasserschaff

Carlos Tellaeche Herranz

Sven Thate

Sabine Schmidt

Stephan Schunk

Rene Konig

Rene KÖNIG

An apparatus contains at least one pressure-rated apparatus shell and at least one modular framework system containing ceramic fiber composite materials and arranged within the apparatus shell. A modular lining apparatus includes the modular framework system and refractory bricks. The apparatus can be used for high-temperature reactors, especially electrically heated high-temperature reactors.

Device comprising a pressure-bearing device shell and an interior scaffolding system

The present invention relates to an electrically heatable packed pressure-bearing apparatus for conducting endothermic reactions having an upper (), middle () and lower () apparatus section, where at least one pair of electrodes () in a vertical arrangement is installed in the middle section () and all electrodes are disposed in an electrically conductive solid-state packing (), the upper and lower apparatus sections have a specific conductivity of 105 S/m to 108 S/m, and the middle apparatus section is electrically insulated against the solid-state packing, wherein the upper and lower apparatus sections are electrically insulated from the middle apparatus section, the upper electrode is connected via the upper apparatus section and the lower electrodes via the lower apparatus section or the electrodes are each connected via one or more connecting elements () that are in electrical contact with these sections and the ratio of the cross-sectional areas of the upper and lower electrode to the cross-sectional area of the respective current-conducting connecting element or, without use of a connecting element, the ratio of the cross-sectional area of the upper and lower electrode to the cross-sectional area of the respective current-conducting apparatus section is 0.1 to 10.

Solids-packed apparatus for performance of endothermic reactions with direct electrical heating

The present invention relates to a process for conducting endothermic gas phase or gas-solid reactions, wherein the endothermic reaction is conducted in a production phase in a first reactor zone, the production zone, which is at least partly filled with solid particles, where the solid particles are in the form of a fixed bed, of a moving bed and in sections/or in the form of a fluidized bed, and the product-containing gas stream is drawn off from the production zone in the region of the highest temperature level plus/minus 200 K and the product-containing gas stream is guided through a second reactor zone, the heat recycling zone, which at least partly comprises a fixed bed, where the heat from the product-containing gas stream is stored in the fixed bed, and, in the subsequent purge step, a purge gas is guided through the production zone and the heat recycling zone in the same flow direction, and, in a heating zone disposed between the production zone and the heat recycling zone, the heat required for the endothermic reaction is introduced into the product-containing gas stream and into the purge stream or into the purge stream, and then, in a regeneration phase, a gas is passed through the two reactor zones in the reverse flow direction and the production zone is heated up; the present invention further relates to a structured reactor comprising three zones, a production zone containing solid particles, a heating zone and a heat recycling zone containing a fixed bed, wherein the solid particles and the fixed bed consist of different materials.

Method and device for carrying out endothermic gas phase-solid or gas-solid reactions

The present invention relates to a gastight multilayer composite tube having a heat transfer coefficient of &#x3e;500 W/m/K and comprising at least two layers, namely a layer of nonporous monolithic oxide ceramic and a layer of oxidic fiber composite ceramic, a connecting piece comprising at least one metallic gas-conducting conduit which in the longitudinal direction of the composite tube overlaps in a region at least two ceramic layers, where the one ceramic layer comprises a nonporous monolithic ceramic and the other ceramic layer comprises a fiber composite ceramic, and also the use of the multilayer composite tube as reaction tube for endothermic reactions, radiation tubes, flame tubes or rotary tubes.

Gas-tight, heat-permeable multilayer ceramic composite tube

The invention relates to a process for the parallel preparation of hydrogen, carbon monoxide and a carbon-comprising product, wherein one or more hydrocarbons are thermally decomposed and at least part of the pyrolysis gas formed is taken off from the reaction zone of the decomposition reactor at a temperature of from 800 to 1400&#xb0; C. and reacted with carbon dioxide to form a gas mixture comprising carbon monoxide and hydrogen (synthesis gas).

Parallel preparation of hydrogen, carbon monoxide and a carbon-comprising product

Described is an iron-containing zeolite wherein the number of iron sites, based on the zeolite, is greater than the number of cationic positions in the zeolite. Also described is an iron-containing zeolite preparable by gas phase reaction with iron pentacarbonyl, said zeolite having a greater specific surface area than iron-containing zeolites prepared analogously by ion exchange and/or being more hydrothermally stable than iron-containing zeolites prepared analogously by ion exchange, or wherein the number of iron clusters larger than 10 nm is less than 15% by weight, based on the total amount of iron. Further described is a process for preparing an iron-containing zeolitic material, which comprises doping with iron by means of a gas phase reaction using iron pentacarbonyl. Further described is a process for catalytic reduction of nitrogen oxides using catalysts comprising said iron-containing zeolitic materials.

Ferrous zeolite, method for producing ferrous zeolites, and method for catalytically reducing nitrous oxides

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Obrigheim, Germany

Bernd Zoels