Degussa Aktiengesellschaft

Other

Degussa - Huls Ag

Degussa Gmbh

Degusaa Aktiengesellschaft (degussa Ag)

Bernd Engler

Edgar Koberstein

Rainer Domesle

Egbert Lox

Reinhold Brand

Herbert Voelker

Wolfgang Honnen

Peter Kleine-Moellhoff

Johannes Ohmer

Peter Schubert

Peter K Kleinschmit

Herbert M Volker

Klaus Ostgathe

Stephan Blumrich

Akos Kiss

Rudolf Schwarz

Werner Hartmann

Mustafa Siray

Michael Baacke

Felix Schmidt

Jurgen Leyrer

Juergen Leyrer

Oliver Fehnle

Wolfgang Honen

Martin Foerster

Reinhold Beand

Peter Kleine-Mollhoff

Andreas Niemann-Weber

Wolfgang Kuhl

Walter Leibold

A coating dispersion is shown for the production of catalysis-promoting coatings on an inert, structure-reinforcing element. The solids of the dispersion are present in various particle fractions and lead to a relatively rough coating surface with improved exchange between the exhaust gas and the catalyst surface. This results in improved heat-up behavior of the catalyst.

Coating dispersion for exhaust gas catalysts

A method for the sealing of flow channels in an annular zone of a cylindrical honeycomb body. The sealing of the flow channels takes place by introduction of a ceramic compound into the flow channels by means of a nozzle, wherein nozzle and honeycomb body are moved relative to one another with simultaneous guiding of the nozzle past the lateral surface and/or past the end face contour of the honeycomb body.

Method for the unilateral or bilateral sealing or filling of flow

A method is disclosed for manufacturing a monolithic metal support with a coated, gas-permeable shaped body. The shaped body is formed of one or more smooth and/or corrugated metal foil strips previously coated with a dispersion coating. During or after formation of the shaped body, the metal foil strips are joined by soldering or welding to at least one adjacent metal foil strip or to at least one adjacent layer of the same metal foil strip.

Process for manufacturing a coated, monolithic metal support

A process and apparatus for accelerating the rate of heating of a fixed bed catalyst to a light-off temperature for a catalytic reaction is disclosed. Supplementary energy from an external energy source is provided to a predetermined area of the catalyst bed for a limited period of time. The fixed bed catalyst may be present as a solid body or in bulk form and has a gas inlet area defined by a cross-section of the flow through channels of the reaction media. The supplementary energy is supplied to one or more isolated sections of the gas inlet area of the catalyst. Such a system significantly reduces the energy required in order to effectuate at least partial conversion of harmful emissions during initial operation of the converter.

System for accelerating the heating rate of a fixed bed catalyst by

A process for applying a coating to honeycomb structures in an exhaust gas converter which contains two such honeycomb structures in a common housing or enveloping tube which are arranged one after the other and which are separated from each other by a gap. The coating dispersion is first supplied from one end of the exhaust gas converter up to the gap between the two honeycomb structures. Then excess coating dispersion is driven out using a blast of air from the direction of the uncoated honeycomb structure. To coat the second honeycomb structure, the exhaust gas converter is inverted and the coating dispersion is then applied in the same way but from the uncoated end. Following the dispersion coating procedure, production of the catalyst is completed by drying and optionally calcining.

Process for applying a coating to honeycomb structures in an exhaust gas

An open-cell, monolithic catalyst for the purification of diesel-engine exhaust gas with a coating of finely divided inorganic oxides containing vanadium and platinum group metal as active components. The active components of the oxidic coating are added as water-soluble precursors which are then converted by means of tempering, preferably in an atmosphere of hydrogen, into the active component.

Method for using a catalyst to purify exhaust gases from a diesel engine

Monolithic catalysts with a metal carrier that includes a catalytically coated matrix having at least one stack of several sheet-metal strips of corrugated or alternately corrugated and flat metal strips folded or intertwined with one another are described. The free ends of the metal strips are connected by a joining process with a surrounding jacket tube of any required cross-section. The monolithic catalyst is produced very economically and with a catalytic coating that has a uniform thickness. The at least one stack of sheet-metal strips required for the monolithic catalyst with a metal carrier is assembled from coated metal ribbons cut to length so as to form metal stacks. The stacks may be folded and/or intertwined with themselves or with one another so as to form the matrix. The matrix with intertwined and coated strips is inserted into the jacket tube and the free ends of the metal strips are secured by joining to the jacket tube. The coated metal strips may be formed by coating long metal ribbons with catalytic coating in a continuous operation prior to cutting the ribbons to the required length. The metal ribbon is also preferably corrugated prior to the coating step but can also be corrugated after the coating step. In another embodiment, the matrix is formed of a single, continuous and at least partially corrugated metal strip which is folded on to itself so as to form a stack arrangement.

Monolithic catalyst with a metal carrier

An oxidative diesel control catalyst is disclosed which has a high conversion rate for hydrocarbons and carbon monoxide and an inhibited oxidation effect on nitrogen oxides and sulfur dioxides and which contains a monolithic catalyst element with throughflow passages of ceramic or metal coated with an activity-promoting dispersion coating of the fine-particle metal oxides aluminum oxide, titanium oxide, silicon oxide, zeolite or mixtures thereof as support of the catalytically active components, the active components being present in the form of platinum, palladium, rhodium and/or iridium doped with vanadium or in contact with an oxidic vanadium compound. The reduced oxidation effect on sulfur dioxide is obtained by virtue of the fact that the fine-particle metal oxides are surface-modified aluminum oxide, titanium oxide, silicon oxide, zeolite or mixtures thereof. The surface modification is a coating of the specific surface of the metal oxides with a layer of titanium dioxide or silicon dioxide of 1 to 5 monolayers.

Oxidative diesel control catalyst

A catalyst is described for reducing the quantity of nitrogen oxides in lean exhaust gas of motor vehicle engines. The catalyst contains, on a structure reinforcing body, a first catalytic coating of an aluminum oxide and/or cerium oxide of large surface area impregnated with a mixture of iridium and platinum as catalytically active noble metal components. A second catalytic coating including a zeolite of the mordenite type containing copper and/or iron is applied to the first coating layer.

Reduction in the quantity of NO.sub.x in lean exhaust gas of motor

A catalyst for the selective reduction of nitrous oxide with ammonia contains, in addition to titanium oxide as component (A), at least one oxide of W, Si, B, Al, P, Zr, Ba, Y, La, Ce and at least one oxide of Y, Nb, Mo, Fe, Cu as component (B), whereby the atomic ratio between the elements of components (A) and (B) amounts to 1:0.001 up to 1. The catalyst can be obtained by kneading reactive titanium oxide with a high specific surface of predominantly anatase with the substances of component (B) or their preliminary stages, adding processing agents, winding up with a homogeneous kneaded mass, extruding the latter, drying the extrudate and calcining in air at 300.degree.-800.degree. C.

Catalyst for selective reduction of nitrous oxides with ammonia

A solid catalyst for the oxidation of sulfur dioxide in gas currents containing oxygen, which catalyst includes vanadium oxide and alkali metal oxides, alkali metal sulfates or mixtures thereof, as an active substance, silicon, aluminum, or mixtures thereof, in oxide form, for surface area enlargement, and titanium dioxide in anatase form, rutile form, or mixtures thereof, as a carrier material and a ceramic binder. The metals in these finely sintered components which impart discrete functions are present in certain atomic ratios. The fine sintering takes place according to a production method especially by means of differentiated conditions of drying, calcining and sintering. One use for the invention is the desulfurization of waste gases from combustion processes and industrial plants.

Catalyst for the oxidation of sulfur dioxide and method for the

A catalyst for the selective reduction of nitrous oxide with ammonia contains, in addition to titanium oxide as component (A), at least one oxide of W, Si, B, Al, P, Zr, Ba, Y, La, Ce and at least one oxide of V, Nb, Mo, Fe, Cu as component (B), whereby the atomic ratio between the elements of components (A) and (B) amounts to 1:0.001 up to 1. The catalyst can be obtained by kneading reactive titanium oxide with a high specific surface of predominantly anatase with the substances of component (B) or their preliminary stages, adding processing agents, winding up with a homogeneous kneaded mass, extruding the latter, drying the extrudate and calcining in air at 300.degree.-800.degree. C.

Process for producing a catalyst for selective reduction of nitrous

A catalyst for purifying the exhaust gases of internal combustion engines with improved light-off behavior and improved durability with reduced specific noble-metal content is disclosed which uses active aluminum oxide provided with customary promoters as carrier and platinum and/or palladium and rhodium in customary amounts as noble metals. In addition, it contains one or more base metals in amounts up to 5 times the mass of the total noble metal which are brought into the immediate vicinity of the rhodium by means of a special manufacturing technique.

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Hanau, Germany

Bernd Engler