Petrolite Corporation

Baker Hughes Corporation

Other

Bernardus A Oude Alink

Neil E Thompson

Benjamin T Outlaw

Derek Redmore

Richard Martin

Jo Ann McMahon

Thomas G Braga

Sayed Sadiq Shah

James A Dougherty

Ronald P Hutton

Benjie T Outlaw

Jacob Mathew

William F Fahey

Carol S Claywell

Joe A Kelley

A method and corrosion inhibitor for inhibiting corrosion of metal equipment in an aqueous medium comprising components selected from the group consisting of fish, other algae, and a combination thereof. The method comprises incorporating into the medium a corrosion inhibiting amount of a water soluble corrosion inhibitor comprising an N-ethoxy, 2-substituted imidazoline. The N-ethoxy substituent comprises a quantity of ethylene oxide effective to render the imidazoline water soluble. The corrosion inhibitor is rendered more environmentally compatible by shortening the number of carbon atoms in the fatty acid chain at the 2-position of the imidazoline. The fatty acid chain consists essentially about 18 carbon atoms or less, preferably about 10 carbon atoms or less, most preferably from about 6 to about 8 carbon atoms. As the number of carbon atoms in the fatty acid chain is reduced, the efficacy of the corrosion inhibitor is increased by combination with a wetting agent, preferably an ethoxylated alcohol having from about 8 to about 10 carbon atoms.

Combinations of imidazolines and wetting agents as environmentally acceptable corrosion inhibitors

A novel method for preparing an aryl-substituted fatty acid or fatty ester is disclosed. According to the method, an olefinic composition selected from among mono-unsaturated fatty acids, mono-unsaturated fatty esters and mixtures thereof is introduced to a reaction zone comprising a liquid aromatic hydrocarbon and a catalytic amount of a clay catalyst to produce a reaction that is allowed to proceed for a time and at a temperature sufficient to produce a reaction product comprising a desired yield of aryl-substituted fatty acid or fatty ester. Preferably, the introduction of the olefinic composition is conducted slowly, such as over a period of one to four, more preferably, two to four, hours. Related methods and compositions, including xylylstearic acid, are also disclosed.

Catalyzed synthesis of aryl-substituted fatty acids and fatty esters and

A method for inhibiting corrosion in an aqueous medium is disclosed. The method comprises incorporating into the medium an amount of a water-soluble corrosion inhibitor sufficient to inhibit corrosion. The corrosion inhibitor comprises an N-ethoxy, 2-substituted imidazoline, the N-ethoxy substituent having from one to about thirty ethoxy units and the 2-substituent being an unsaturated or polyunsaturated fatty chain of from about six to about thirty carbons. If the medium is sweet, the inhibitor further comprises a phosphate ester derived from a water-soluble oxyethylated, straight chain alcohol of from about two to about thirty carbons. Corrosion inhibitor compositions useful in such method are also disclosed.

Biodegradable corrosion inhibitors of low toxicity

A method for inhibiting corrosion of a metal surface bearing a corrosion product including ferrous ions is disclosed. The method comprises applying to the surface a salt of an ethoxylated amine and a reaction product of an alcohol and a fatty acid maleic anhydride adduct produced by a reaction between maleic anhydride and an unsaturated fatty acid. Related compositions are also disclosed.

Corrosion inhibition by ethoxylated fatty amine salts of maleated

A method for inhibiting corrosion of a metal surface in a liquid medium is described. The method comprises incorporating into the medium a corrosion inhibiting amount of a combination of a surfactant that forms a bilayer on the metal surface in the fluid and a corrosion inhibitor that solubilizes in the medium in the presence of the surfactant. The amount of surfactant is sufficient to produce a bilayer on the metal surface in the medium. The combination is a. an anionic surfactant that forms a bilayer on the metal surface and a cationic corrosion inhibitor; b. a cationic surfactant that forms a bilayer on the metal surface and an anionic corrosion inhibitor; c. an ionic surfactant that forms a bilayer on the metal surface and an ionic corrosion inhibitor having a pendent, generally straight chain hydrocarbon or substituted hydrocarbon moiety of from about 10 to about 18 carbon atoms; or d. an ionic surfactant that forms a bilayer on the metal surface and a non-ionic corrosion inhibitor. Related compositions and methods are also disclosed.

Corrosion inhibition with bilayer-forming surfactants

A method for inhibiting corrosion in an aqueous medium is disclosed. The method comprises incorporating into the medium an amount of a water-soluble corrosion inhibitor sufficient to inhibit corrosion. The corrosion inhibitor comprises an N-ethoxy,2-substituted imidazoline, the N-ethoxy substituent having from one to about thirty ethoxy units and the 2-substituent being an unsaturated or polyunsaturated fatty chain of from about six to about thirty carbons. If the medium is sweet, the inhibitor further comprises a phosphate ester derived from a water-soluble oxyethylated, straight chain alcohol of from about two to about thirty carbons. Corrosion inhibitor compositions useful in such method are also disclosed.

A method for inhibiting corrosion of ferrous surfaces in an acidic, aqueous medium is disclosed. The method comprises incorporating into the medium a corrosion-inhibiting amount of a pyridine salt composition (comprising a quaternary pyridine salt composition and/or a pyridine.HCL salt composition) and a cationic surfactant that forms a bilayer on the ferrous surfaces in the medium. Highly quaternized pyridine salt compositions useful in such method and a method for preparation of such compositions are also disclosed.

Corrosion inhibition in highly acidic environments by use of pyridine

Water-soluble 1,2-dithiole-3-thione derivatives are prepared by reacting a polyoxyalkylated starting material with sulfur. These derivatives are useful as corrosion inhibitors, particularly in aqueous environments.

Water soluble 1,2-dithio-3-thiones

A method is disclosed for volatile inhibition and transport of inhibitor in the volatile phase to produced liquids of corrosion in a gas lift process in which a lift gas is pumped into a well to facilitate petroleum production of the well. The method comprises introducing to the lift gas a corrosion-inhibiting amount of a dihydrothiazole of the formula ##STR1## wherein R, R', R', R'', and R.sup.4 are independently selected from among hydrogen and alkyl groups of up to about 3 carbon atoms, provided that the total number of carbon atoms of R, R', R', R'' does not exceed about 14.

Volatile corrosion inhibitors for gas lift

Compounds containing sulfur and amino groups

This invention relates to novel highly branched amines and to a process of preparing same which comprises:

Preparation of diamines from aldehydes and ammonia

A process for inhibiting the corrosion of ferrous metals in aqueous acidic or briny media comprising the step of adding a composition of the formula ##STR1## where R.sub.1 is a hydrocarbon group, O is a pyridine or substituted pyridine, and X is an anion.

Process of corrosion inhibition using compounds containing sulfur and

This invention relates to amino hexahydropyridines, and to the preparation and use thereof as corrosion inhibitors.

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St. Louis, MO, United States of America

Bernardus A Oude Alink