The Superior Oil Company

Multi Mineral Corporation

Bernard E Weichman

John H Knight

A method for the in situ processing of oil shale ore includes the establishment of underground stopes by removing from each a portion of the oil shale ore therein, rubblizing the remaining ore in each stope, extracting the rubblized ore and crushing it to obtain a desired particle size for subsequent processing, and restoring the sized oil shale particles to the stope by backfilling the stope as the rubble is extracted. The stope is maintained substantially filled with ore to provide lateral support to the side walls and reduce the likelihood of caving in the stope. The oil shale is retorted by injection of hot gas into the stope, and residual carbon is recovered from the retorted ore as producer fuel gas. The sensible heat in the ore may thereafter be recovered for use in retorting oil shale ore in an adjacent stope.

Method for in situ shale oil recovery

A method for the in situ processing of mineral-bearing oil shale ore includes the establishment of a plurality of underground stopes by removing from each a portion of the oil shale ore therein, rubblizing the remaining ore in each stope, extracting the rubblized ore and crushing it to obtain a nahcolite fraction and an oil shale fraction having a desired particle size for subsequent processing, and restoring sized oil shale particles to the stope by back filling the stope as the rubble is extracted so as to maintain the stope substantially filled with particles to provide lateral support to the side walls and reduce the likelihood of caving in the stope. The nahcolite fraction is recovered from the crushed ore prior to backfilling of the stopes for retorting to recover shale oil, while soda ash and alumina may be recovered from the spent shale by leaching the stopes after retorting. A method of retorting is also disclosed in which three retorts are operated in series, the first retort comprising a gas heating retort, the second a carbon recovery retort and the third an active retort.

Integrated in situ shale oil and mineral recovery process

A method for the recovery of products from nahcolite-bearing oil shale ore deposits which comprises, in pertinent part, in situ retorting of oil shale ore from which a major portion of the nahcolite has been separated.

In situ processing of mined oil shale

A plurality of hydrocarbon fractions are recovered from hydrocarbon-bearing material such as oil shale in a continuous retort wherein a bed of the material is moved through a heating chamber, the heating being for a time and at a temperature effective to strip increasingly heavier hydrocarbon fractions from the material as it moves through the heating chamber. The hydrocarbon fractions are collected by a plurality of collection means disposed along the path of movement of the bed for recovery of a corresponding plurality of hydrocarbon fractions.

Method for recovery of hydrocarbon fractions from hydrocarbon-bearing

A method of reducing the sulfur and nitrogen content of a hydrocarbon, specifically, a liquid or gaseous phase hydrocarbon which comprises contacting the hydrocarbon with nahcolite in an amount effective to remove sulfur and nitrogen compounds from the hydrocarbon. The nahcolite containing combined sulfur and nitrogen can be removed from the hydrocarbon, producing a hydrocarbon having a reduced sulfur and nitrogen content. The method is particularly applicable to the reduction of the sulfur and nitrogen content in shale oil by contacting shale oil and nahcolite in a shale oil retort or process.

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Houston, TX, United States of America

Bernard E Weichman