Blue Current, Inc.

Lawrence Livermore National Security, LLC

Esionic Es, Inc.

Alliance for Sustainable Energy, LLC

Benjamin Rupert

Alexander Teran

Joanna Burdynska

Eduard Nasybulin

Simmi Kaur Uppal

Saranya Venugopal

Stephen Anthony Payne

Nerine Jane Cherepy

Steven Zhichao Shi

M Leslie Carman

Natalia P Zaitseva

Andrew M Glenn

Levi J Irwin

Leanne Beer

Sebastien Hamel

Shilpa A Worlikar

David Samuel Ginley

Calvin J Curtis

Scott Ryan Hammond

Alexander Miedaner

Robert Dean Sanner

Matthew O Reese

Benjamin W Sturm

Dana C Olson

Wayne L Gellett

Richard Hoft

Lithium oxide argyrodites having the formula LiPSOXwhere X is a halide anion and y is a number between 0 and 0.8, inclusive, are provided herein. Also provided are methods of synthesizing the lithium oxide argyrodites and composites including the lithium oxide argyrodites, as well as other alkali metal oxide argyrodites and related methods and composites.

Lithium oxide argyrodites

Provided herein are ionically conductive solid-state compositions that include ionically conductive inorganic particles in a matrix of an organic material. The resulting composite material has high ionic conductivity and mechanical properties that facilitate processing. In particular embodiments, the ionically conductive solid-state compositions are compliant and may be cast as films. In some embodiments of the present invention, solid-state electrolytes including the ionically conductive solid-state compositions are provided. In some embodiments of the present invention, electrodes including the ionically conductive solid-state compositions are provided. The present invention further includes embodiments that are directed to methods of manufacturing the ionically conductive solid-state compositions and batteries incorporating the ionically conductive solid-state compositions.

Compliant solid-state ionically conductive composite materials and method for making same

Provided herein are solid materials that are ionically conductive and electrochemically stable. Embodiments of the solid materials are argyrodite-type compositions that have high ionic conductivity. The compositions include small amounts of thiophilic metals, whose binary sulfides do not react with water to hydrogen sulfide (HS). As such, HS release is minimized or eliminated. Also provided are methods of fabricating the materials and batteries and battery components containing the materials.

Argyrodites doped with thiophilic metals

Provided herein are methods of forming solid-state ionically conductive composite materials that include particles of an inorganic phase in a matrix of an organic phase. The methods involve forming the composite materials from a precursor that is polymerized in-situ after being mixed with the particles. The polymerization occurs under applied pressure that causes particle-to-particle contact. In some embodiments, once polymerized, the applied pressure may be removed with the particles immobilized by the polymer matrix. In some implementations, the organic phase includes a cross-linked polymer network. Also provided are solid-state ionically conductive composite materials and batteries and other devices that incorporate them. In some embodiments, solid-state electrolytes including the ionically conductive solid-state composites are provided. In some embodiments, electrodes including the ionically conductive solid-state composites are provided.

Polymerized in-situ hybrid solid ion-conductive compositions

Provided herein are methods of forming solid-state ionically conductive composite materials that include particles of an inorganic phase in a matrix of an organic phase. The organic phase includes a cross-linked polyurethane network. The methods involve forming the composite materials from a precursor that is cross-linked in-situ after being mixed with the particles. The cross-linking occurs under applied pressure that causes particle-to-particle contact. Once cross-linked, the applied pressure may be removed with the particles immobilized by the polymer matrix. The polyurethane network is configured for easy processability of uniform films and may be characterized by a hard phase content of at least 20%.

Polyurethane hybrid solid ion-conductive compositions

Methods of synthesizing particles and the resulting particles are disclosed. The methods include synthesizing the particles in the presence of one or more additives. The resulting particles are smaller and easier to disperse in solution. Also described are methods of processing particles and the resulting particles. In particular embodiments, the particles are suited for incorporation into films.

Additives for particle size control

Provided herein are functionally substituted fluoropolymers suitable for use in liquid and solid non-flammable electrolyte compositions. The functionally substituted fluoropolymers include perfluoropolyethers (PFPEs) having high ionic conductivity. Also provided are non-flammable electrolyte compositions including functionally substituted PFPEs and alkali-metal ion batteries including the non-flammable electrolyte compositions.

Functionalized fluoropolymers and electrolyte compositions

In one embodiment, a scintillator material includes a polymer matrix; and a primary dye in the polymer matrix, the primary dye being a fluorescent dye, the primary dye being present in an amount of 5 wt % or more; wherein the scintillator material exhibits an optical response signature for neutrons that is different than an optical response signature for gamma rays. In another embodiment, a scintillator material includes a polymer matrix comprising at least one of: polyvinyl xylene (PVX); polyvinyl diphenyl; and polyvinyl tetrahydronaphthalene; and a primary dye in the polymer matrix, the primary dye being a fluorescent dye, the primary dye being present in an amount greater than 10 wt %. A total loading of dye in the scintillator material is sufficient to cause the scintillator material to exhibit a pulse-shape discrimination (PSD) figure of merit (FOM) of about at least 2.0.

Plastic scintillator with effective pulse shape discrimination for neutron and gamma detection

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Berkeley, CA, United States of America

Benjamin Rupert