Avantium Knowledge Centre B.v.

Synvina C.v.

Furanix Technologies B.v.

Avantium International B.v.

Benjamin McKay

Gerardus Johannes Maria Gruter

Jan Cornelis Van Der Waal

Ana Sofia Vagueiro De Sousa Dias

Jagdeep Singh

Johannes Maria Franciscus Sijben

Robert-Jan Van Putten

Paula Dekker

Victor Peter Charles Vreeken

Martijn Kersbulck

David L Sikkenga

Matheus Adrianus Dam

Bing Wang

Etienne Mazoyer

Wei Zhao

Hendrikus Jacob Baars

Emilio René Bodenstaff

Mimoun Lamkadmi

Alan Arthur Smith

Danny Dirk Pieter Willem Stam

Lisa Lynn Agocs

Francois Gilardoni

Anna Louise Jongerius

Scott Henry Russell

Johannes Hendrick Vleeming

Kay Jochem Damen

Sarwat Iqbal

Processed lignin comprising the elements carbon (C), hydrogen (H) and oxygen (O) in the following amounts: A process to prepare the processed lignin comprising subjecting particles comprising lignin and cellulose and optionally hemicellulose to acidic hydrolysis using hydrochloric acid of at least 35%, subjecting the obtained residue to a high temperature treatment of between 300 and 500° C. under inert gaseous atmosphere to a total CI level of below 0.1% by weight, after drying.

Processed lignin and process to prepare such

A process includes the following steps: a) converting a solid material containing hemicellulose, cellulose and lignin, by: (i) hydrolyzing at least part of the hemicellulose of the solid material with a first aqueous hydrochloric acid solution, yielding a remaining solid material and a hydrochloric acid-containing, aqueous, first hydrolysate product solution; (ii) hydrolyzing at least part of the cellulose of the remaining solid material with a second aqueous hydrochloric acid solution, yielding a residue and a hydrochloric acid-containing, aqueous, second hydrolysate product solution; (b) forwarding to step (c) a, hydrochloric acid-containing, aqueous intermediate product solution comprising: a part of or the whole of the hydrochloric acid-containing, aqueous first and/or second hydrolysate product solution of step (a); and (c) heating at least part of the hydrochloric acid-containing, aqueous intermediate product solution to yield a product solution containing 5-(chloromethyl)furfural, and extracting the 5-(chloromethyl)furfural from the product solution into an extraction solvent.

Process for the conversion of a solid lignocellulosic material

A process for obtaining aqueous hydrolysates from solid material containing hemicellulose, cellulose and lignin. The process comprises hydrolysing at least part of the hemicellulose of the solid material with a first aqueous hydrochloric acid solution at a concentration of 15-40 wt %, yielding a remaining solid material and an aqueous first hydrolysate product solution. The aqueous first hydrolysate is displaced from the remaining solid material with a non-aqueous displacement fluid having a density of less than 1000 kg/m. Thereafter, at least part of the cellulose of the remaining solid material is hydrolysed with a second aqueous hydrochloric acid solution at a concentration of 40-51 wt %, yielding a residue and an aqueous second hydrolysate product solution. This process is carried out in vertical cylindrical reactors, and the displacement fluid is supplied to a reactor in a downward fashion.

Process for the conversion of a solid material containing hemicellulose, cellulose and lignin

A process for obtaining aqueous hydrolysates from solid material containing hemicellulose, cellulose and lignin, which process comprises hydrolysing at least part of the hemicellulose of the solid material with a first aqueous hydrochloric acid solution at a concentration of 15-40 wt %, yielding a remaining solid material and an aqueous first hydrolysate product solution. The aqueous first hydrolysate is displaced from the remaining solid material with a non-aqueous displacement fluid. Thereafter, at least part of the cellulose of the remaining solid material is hydrolysed with a second aqueous hydrochloric acid solution at a concentration of 40-51 wt %, yielding a residue and an aqueous second hydrolysate product solution.

The invention relates to a process for the production of ethylene glycol including the steps of: The invention further relates to a regenerated heterogeneous catalyst composition obtainable therein.

Process for the production of ethylene glycol and heterogeneous catalyst composition

A purified hydrochloric acid composition is prepared from a stream of a contaminated hydrochloric acid composition by a process comprising a distillation treatment, wherein at least a first distillation column is operated at a first pressure and a second distillation column is operated at a second pressure, which second pressure is lower than the first pressure; wherein the contaminated hydrochloric acid composition comprises water, contaminants and hydrochloric acid in a first hydrochloric acid concentration of above the azeotropic composition of hydrochloric acid and water at the first pressure; wherein a part of the stream of the contaminated hydrochloric acid composition is fed into the first distillation column to yield a first bottom product comprising water and hydrochloric acid with a hydrochloric acid concentration below the first hydrochloric acid concentration and a first top product comprising hydrochloric acid in a concentration above the azeotropic hydrochloric acid composition at the first pressure; wherein at least a portion of the first bottom product is passed to the second distillation column; wherein another part of the stream of the contaminated hydrochloric acid composition is fed into the second distillation column to yield a second top product comprising contaminants and water, and a second bottom product comprising water and hydrochloric acid; wherein at least a part of the second bottom product is recycled into the first distillation column; and wherein the first top product is recovered as purified hydrochloric acid composition.

Process for purifying a contaminated hydrochloric acid composition

A process for the conversion of solid lignocellulosic material containing hemicellulose, cellulose and lignin, includes (a) hydrolyzing, at a temperature equal to or less than 40&#xb0; C. at least part of the hemicellulose and at least part of the cellulose of the solid lignocellulosic material with an aqueous hydrochloric acid solution, containing in the range from equal to or more than 40.0 wt. % to equal to or less than 51.0 wt. % hydrochloric acid, based on the combined weight amount of water and hydrochloric acid in the aqueous hydrochloric acid solution; yielding a hydrochloric acid-containing, aqueous hydrolysate solution; (b) separating the hydrochloric acid-containing, aqueous hydrolysate solution from the lignin; and (c) heating at least part of the hydrochloric acid-containing, aqueous hydrolysate solution to a temperature equal to or more than 60&#xb0; C., yielding a product solution containing 5-(chloromethyl)furfural, and extracting the 5-(chloromethyl)furfural from the product solution into an extraction solvent.

A continuous or semi-continuous process for the preparation of ethylene glycol from a carbohydrate source including: reacting, in a reactor, at a temperature in the range from equal to or more than 170&#xb0; C. to equal to or less than 270&#xb0; C., at least a portion of a carbohydrate source in the presence of hydrogen, a solvent, and a catalyst system, to yield ethylene glycol; wherein the catalyst system includes: a homogeneous catalyst, which homogeneous catalyst contains tungsten; and a heterogeneous catalyst, which heterogeneous catalyst contains one or more transition metals from groups 8, 9 and 10 of the Periodic Table of the Elements supported on a carrier; and wherein continuously or periodically additional heterogeneous catalyst is added to the reactor. Further described is a catalyst system that can be used in such a process.

Continuous or semi-continuous process for the preparation of ethylene glycol and catalyst system for use therein

A process for the production of ethylene glycol including the steps of:

Process for the production of ethylene glycol

Solid saccharides are produced from an aqueous saccharide solution in a process, where the aqueous saccharide solution is admixed with a carrier liquid in which the saccharides are insoluble and that has a boiling point higher than that of water to obtain an aqueous admixture, and where the aqueous admixture is subjected to an evaporation step. The heat for the evaporation is at least partially supplied by a heated surface area to yield a vapor fraction including water and a residue fraction including solid saccharides and carrier liquid.

Process for the production of solid saccharides from an aqueous saccharide solution

An ester composition including at least 90% wt of the dialkyi ester of 2,5-furandicarboxylic acid as starting dialkyi ester concentration and up to 5% wt of the monoalkyi ester of 2,5-furandicarboxylic acid as starting monoalkyi ester concentration, the percentages being based on the weight of the ester composition, is purified in a process which includes subjecting the ester composition to melt crystallization to yield a purified dialkyi ester composition containing a dialkyi ester concentration higher than the starting dialkyi ester concentration and a melt residue containing a monoalkyi ester concentration higher than the starting monoalkyi ester concentration. From the melt residue a purified monoalkyi ester composition and a contaminants-rich residue can be prepared via melt crystallization. The purified dialkyi ester composition and/or the purified monoalkyi ester composition can be hydrolyzed to yield purified 2,5-furandicarboxylic acid.

Process for purifying a crude composition of dialkyl ester of 2,5-furandicarboxylic acid

Dialkyil esters of 2,5-furandicarboxylic acid are prepared in a process including: contacting an acid starting composition having 2,5-furandicarboxylic acid with an excess of alkanol to form an esterification product having the dialkyil ester of 2,5-furan dicarboxylic acid, water and unreacted alkanol; separating at least part of the unreacted alkanol and water from the esterification product to yield a solid crude product composition having the dialkyil ester of 2,5-furandicarboxylic acid; and subjecting at least part of the solid crude product composition to an evaporation step, where the dialkyil ester of 2,5-furandicarboxylic acid is evaporated and subsequently condensed to yield purified dialkyil ester of 2,5-furandicarboxylic acid.

Preparation of dialkyl esters of 2,5-furandicarboxylic acid

Dialkyl esters of 2,5-furandicarboxylic acid are prepared from a 2,5-furandicarboxylic acid-containing starting material in a process, which includes: contacting a vaporous stream of an alkanol countercurrently with the at least partially liquid starting material having the 2,5-furandicarboxylic acid, in a reaction zone to conduct an esterification reaction to yield the dialkyl ester of 2,5-furandicarboxylic acid and water; withdrawing a reaction vapor comprising the alkanol and water from the reaction zone; and discharging a liquid phase having at least the dialkyl ester of 2,5-furandicarboxylic acid, from the bottom part of the reaction zone, to obtain the dialkyl ester of 2,5-furandicarboxylic acid.

A fructoside-containing product is manufactured from a glucose-rich feedstock, in a process where glucose to fructose is isomerized by contacting the glucose-rich feedstock with a basic isomerization catalyst in an alcoholic medium at a temperature of at least 75&#xb0; C., to yield a fructose-containing product; and where at least part of the fructose-containing product obtained therefrom is reacted with an alcohol in the presence of an acid catalyst to yield a fructoside-containing product.

Process for producing a fructoside-containing product

An acid composition comprising 2-formyl-furan-5-carboxylic acid and 2,5-furandicarboxylic acid is purified in a process which comprises; contacting the acid composition with an alcohol to obtain an esterified composition; and separating the ester of 2-formyl-furan-5-carboxylic acid from the esterified composition to obtain a purified esterified product; and contacting the purified esterified composition with water for saponification or hydrolysis, to obtain a product composition, comprising 2,5-furandicarboxylic acid and a reduced amount of 2-formyl-furan-5-carboxylic acid.

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Amsterdam, Netherlands

Benjamin McKay