3m Innovative Properties Company

Benjamin G Sonnek

Gregg A Ambur

Jo Anne Etter

Thomas P Klun

Richard John Pokorny

Zhisheng Yun

Timothy L Wong

Robert M Jennings

Benjamin R Coonce

Chunjie Zhang

Jung-Sheng Wu

Douglas Scott Dunn

John R Jacobson

Henry A Kostalik, Iv

Christopher S DeGraw

Christopher Bland Walker, Jr

Mary M Caruso Dailey

Abdullahi A Mohamud

Daniel J Richter

A curved reflective has at least one location having a radius of curvature in a range from about 6 mm to about 1000 mm. Each location on the reflective polarizer has a maximum reflectance greater than about 70% for a block polarization state, a maximum transmittance greater than about 70% for an orthogonal pass polarization state, and a minimum transmittance for the block polarization state. For a continuous first portion of the reflective polarizer extending between different first and second edges of the reflective polarizer and defining disjoint second and third portions of the reflective polarizer, the minimum transmittance of the reflective polarizer for the block polarization state is higher at each location in at least 70% of the first portion than at each location in at least 70% of the second portion and at each location in at least 70% of the third portion.

Curved reflective polarizer

A method of making a shaped abrasion-resistant multilayer optical film includes providing a curable composition comprising, based on the total weight of components a) to d) components: a) 87 to 96 weight percent of urethane (meth)acrylate compound having an average (meth)acrylate functionality of 2 to 4.8; b) 2 to 12.5 weight percent of (meth)acrylate monomer having a (meth)acrylate functionality of 1 to 2, wherein the (meth)acrylate monomer does not comprise a urethane (meth)acrylate compound; optionally c) 0.5 to 2 weight percent of silicone (meth)acrylate; and d) optional effective amount of photoinitiator. The curable composition is coated onto an MOF. Optionally, the curable composition to is at least partially dried. Next, the curable composition or the at least partially dried curable composition is at least partially cured to provide an abrasion-resistant multilayer optical film. Lastly, the abrasion-resistant multilayer optical film is thermoformed using a female mold having a mold surface. At least a portion of the mold surface has a radius of curvature of 58 to 76 mm and a maximum depth of 13 to 20 mm.

Thermoformed abrasion-resistant multilayer optical film and method of making the same

An optical assembly including an optical element insert molded directly onto an optical stack is provided. The optical stack includes an optical film and may include a liner with the optical film being disposed between the optical element and the liner. The liner, if included, is removable from the optical film without substantial damage to the optical film. An outermost layer of the optical film may be diffusion bonded to a major surface of the optical element. The optical film includes a protective coating having an average thickness of no more than 30 micrometers. The protective coating includes an at least partially cured composition. The composition includes 70 to 96 weight percent of urethane (meth)acrylate compound having an average (meth)acrylate functionality of 2 to 9.5, and 2 to 20 weight percent of (meth)acrylate monomer having a (meth)acrylate functionality of 1 to 2.

Optical assembly with protective coating

An optical assembly including an optical element insert molded directly onto an optical stack is provided. The optical stack includes an optical film and may include a liner with the optical film being disposed between the optical element and the liner. The liner, if included, is removable from the optical film without substantial damage to the optical film. An outermost layer of the optical film may be diffusion bonded to a major surface of the optical element.

Optical assembly

A method of fabricating an optical assembly includes providing a first mold having a first curved mold surface; placing a substantially flat reflective polarizer; on the first curved mold surface and applying at least one of pressure and heat to at least partially conform the reflective polarizer to the first curved mold surface; providing a second mold comprising a second mold surface, the first and second mold surfaces defining a mold cavity therebetween; substantially filling the mold cavity with a flowable material having a temperature greater than a glass transition temperature of the reflective polarizer; and solidifying the flowable material to form a solid optical element bonded to the reflective polarizer. A maximum variation of an orientation of a pass polarization state across the bonded reflective polarizer is within about 3 degrees of a maximum variation of the orientation of the pass polarization state across the substantially flat reflective polarizer.

Method of fabricating an optical assembly

Shaped optical films and methods of shaping optical films are described. The method includes securing at least portions of a perimeter of the optical film in a first plane so that the secured portions do not move relative to one another; and stretching the optical film by displacing a portion of the optical film along at least a first direction perpendicular to the first plane such that one of a radial and circumferential stretching of the optical film is substantially constant from a center to the perimeter of the optical film, and the other one of the radial and circumferential stretching of the optical film substantially changes from the center to the perimeter of the optical film. The optical film is a reflective polarizer including a plurality of alternating polymeric layers.

Curved reflective polariser films and methods of shaping

A curable composition comprises: a) 91 to 98.2 weight percent of: (i) at least one polymerizable compound containing at least one carbamylene group; or (ii) at least one polyurethane precursor system; and b) 0.2 to 9 weight percent of alpha alumina particles having a particle size distribution with a Dv50 of from 0.1 to 1 micron, wherein the weight percentages of a) and b) are based upon the total amount of a) and b). Cured compositions and their use in thermoforming are also disclosed.

Compositions including alpha-alumina particles and methods of their use

Optical systems for displaying an image are described. The optical systems include spaced apart first and second optical lenses. A partial reflector is disposed on and conforms to a major surface of the first optical lens where the major surface can have a best-fit spherical radius of curvature in a range from 20 mm to 200 mm. A reflective polarizer is disposed on and conforms to a major surface of the second optical lens where the major surface can have a best-fit spherical radius of curvature in a range from 14 mm to 250 mm. A retarder layer is disposed between the reflective polarizer and the partial reflector. The first optical lens can have an optical birefringence of less than 15 nm/cm and the second optical lens can have an optical birefringence of greater than 15 nm/cm. A method of fabricating an optical assembly is described.

Optical system

There is provided an article having at least a first surface having: a binder resin layer comprising an actinic radiation reactive polyurethane dispersion, where the binder resin layer has a first major surface opposite a second major surface; and a plurality of microspheres partially embedded and adhered to the first major surface of the binder resin layer. There is also provided a thermoset article derived from such thermoformable articles.

Growing community of inventors

Mahtomedi, MN, United States of America

Benjamin G Sonnek