Fuel Tech, Inc.

Platinum Plus, Inc.

Clean Diesel Technologies, Inc.

Nalco Fuel Tech

Clean Diesel Technologies Inc. (cdti)

Technol Fuel Conditioners, Inc.

Barry N Sprague

William R Epperly

James C Sullivan

W Robert Epperly

Jeremy D Peter-Hoblyn

James M Valentine

Wayne E Bowers

John H O'Leary

Leonard Dubin

Thure Von Harpe

George F Shulof, Jr

Danny T Kelso

William H Sun

John E Hofmann

Steve Beal

Disclosed here are systems and methods including one or more FBCs and one or more suitable aftertreatment devices, including DOCs, DPFs, and suitable combinations thereof. The systems and methods disclosed may include selecting a suitable FBC for use with a fuel with a specified sulfur content. Systems and methods disclosed here may also include using one or more ECUs to control one or more FBC dosing/metering devices to supply FBCs from one or more FBC reservoirs in the presence of a specified event.

Diesel exhaust treatment systems and methods

Heavy oil emulsions, comprising decant oils and No. 6, No. 5 and No. 4 oils, and water are stabilized by adding certain saccharide-based esters. Preferably, the saccharide-based esters are naturally-occurring saccharide esters such as gallotannins, saponin, red gum, and the like.

Heavy oil emulsion stabilizers containing saccharide based emulsion stabilizer

A low-emissions diesel fuel comprises fungible aviation kerosene grade 55, 50&#x2013;300 ppm detergent, 25&#x2013;500 ppm lubricity additive and a bimetallic, fuel soluble platinum and cerium fuel borne catalyst (e.g., 0.1&#x2013;2.0 ppm platinum COD and 5&#x2013;20 ppm cerium oleate). The fuel can be used as is or in the form of an emulsion. A method of reducing the emissions of pollutants from a diesel engine, comprising running the engine on a fuel as defined. Retarding engine timing can further reduce NOand the use of a diesel particulate filter and/or diesel oxidation catalyst can provide further reductions in carbon monoxide, unburned hydrocarbons and particulates.

Low-emissions diesel fuel

Residual fuels, as well as lighter distillate fuels, are combusted with greater efficiency by utilizing low concentrations of specific bimetallic or trimetallic fuel-borne catalysts. The catalysts reduce fouling of heat transfer surfaces by unburned carbon while limiting the amount of secondary additive ash which may itself cause overloading of particulate collector devices or emissions of toxic ultra fine particles when used in forms and quantities typically employed. By utilizing a fuel containing a fuel-soluble catalyst comprised of platinum and at least one additional metal comprising cerium and/or iron, production of pollutants of the type generated by incomplete combustion is reduced. Ultra low levels of nontoxic metal combustion catalysts are able to be employed for improved heat recovery and lower emissions of regulated pollutants.

Reduced-emissions combustion utilizing multiple-component metallic combustion catalyst

Emissions of pollutants from diesel engines are reduced by a combination of mechanical devices and fuel additives. In one series of embodiments, diesel emissions of NO.sub.x and particulates are reduced, simultaneously with gaseous hydrocarbons and carbon monoxide, by the combined use of exhaust gas recirculation or engine timing modification, with a particulate trap and a platinum group metal catalyst composition. In another embodiment, a multi-metal catalyst composition, comprising a combination of a platinum metal catalyst composition and at least one auxiliary catalyst metal composition, especially cerium or copper, is employed to provide catalyst metal to the exhaust system including a diesel trap to lower the balance point of the particulate trap (the temperature at which the rate of trap loading equals the rate of regeneration) while also lowering the emissions of carbon monoxide and unburned hydrocarbons. Data for platinum, copper and cerium catalysts establishes effective amounts. Tests also show selective maintenance of low oxidation of SO.sub.2 to SO.sub.3.

Methods for reducing harmful emissions from a diesel engine

The invention presented involves a method for reducing emissions from or increasing the utilizable energy of fuel for powering diesel, gasoline or gasohol internal combustion engines, the method comprising admixing with the fuel an additive which comprises a fuel-soluble, nonionic, organometallic platinum group metal coordination composition which is a) resistant to breakdown under ambient temperatures; b) does not contain a disadvantageous amount of phosphorus, arsenic, antimony or halides; and c) has a partition ratio sufficient to maintain preferential solubility in the fuel.

Method for reducing emissions from or increasing the utilizable energy

Platinum group metal fuel additives are effective in fuel environments which make the exclusion of water impractical. The fuels additives comprise a platinum group metal compound and a water-functional composition selected from the group consisting of lipophilic emulsifiers, lipophilic organic compounds in which water is miscible and mixtures of these. The additives are preferably effective in fuel compositions having water contents of at least about 0.01% water by weight.

Platinum metal fuel additive for water-containing fuels

The tendency of aqueous solutions of urea and other NH-containing compositions to force instability of hardness factors has been found to be detrimental to processes and apparatus employing them. The reliability of these processes and apparatus is improved by the inclusion of hardness-suppressing compositions, which preferably include both a water-soluble polymer and a phosphonate. In particular, agricultural and NO.sub.x -reducing applications are improved, especially for solutions containing urea hydrolysis products and the salts of them.

Hardness suppression in urea solutions

The invention presented relates to a method for reducing the emission of nitrogen oxides from a diesel engine without significant loss of fuel efficiency and without significant increases in carbon monoxide and hydrocarbon emissions. The method involves preparing a diesel engine such that the injection timing thereof is set at a point sufficient to obtain reductions in the nitrogen oxides emissions from the engine; and firing the diesel engine with a diesel fuel having admixed therein an additive which comprises a fuel soluble organometallic platinum group metal coordination composition.

Method for reducing pollution emissions from a diesel engine

The invention presented involves a method for regenerating, replacing or treating the catalyst in a hydroprocessing reactor, the method comprising admixing with the feedstock, recycle stream or hydrogen stream of the reactor an additive which comprises a nonionic, organometallic platinum group metal coordination composition which is a) resistant to breakdown under ambient temperatures; b) capable of breakdown at temperatures existing in the vicinity of the catalyst; and c) does not contain a disadvantageous amount of phosphorus, arsenic, sulfur, antimony or halides.

Method for regenerating, replacing or treating the catalyst in a

A method and composition for reducing ammonia emissions from non-acidic residue from the combustion of a carbonaceous fuel, such residue containing ammonium salts or absorbed ammonia, is presented, the method comprising applying to the residue either a physical barrier composition, a chemical barrier composition, or both, under conditions effective to reduce the emission of ammonia from the residue.

Method and composition for the reduction of ammonia emissions from

A process is presented for reducing the concentration of pollutants in an effluent from the combustion of a carbonaceous fuel. The process comprises introducing a first treatment agent into the effluent at a first temperature zone to reduce the concentration of a first pollutant and introducing a second treatment agent into the effluent at a second temperature zone to reduce the concentration of either the first pollutant or a second pollutant, wherein the first and second treatment agents are introduced under conditions effective to reduce the effluent pollution index.

Multi-stage process for reducing the concentration of pollutants in an

The invention presented is a process for reducing the nitrogen oxides concentration in the effluent from the combustion of a carbonaceous fuel. The inventive process comprises introducing into the effluent an oxygenated treatment agent which includes an oxygenated hydrocarbon under conditions effective to oxidize nitric oxide in the effluent to nitrogen dioxide and to produce ammonia; and contacting the effluent with an aqueous absorbing solution having a component capable of causing nitrogen dioxide to be absorbed into the solution.

Hybrid process for nitrogen oxides reduction

The invention presented is a method for catalyzing fuel for powering internal combustion engines. The method comprises admixing with fuel an additive composition comprising at least one fuel-soluble platinum group metal compound in an amount effective to supply from 0.01 to 1.0 parts per million of platinum group metal per part of fuel.

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Bethlehem, CT, United States of America

Barry N Sprague