Ciba-geigy Corporation

Standard Fireworks Ltd.

Barry Cook

John G Dingwall

Norman Richardson

Alan Marshall

Alexander Michael Chalmers

Joseph Tames

Donald Richard Randell

James Jack

Brian Martin Thomas

A pyrotechnic composition, particularly for fireworks, which contains an organic compound having at least one aromatic group as a binder. The compound preferably has a weight ratio of carbon:hydrogen of at least 10:1 and is substantially free of groups of the formulae COOH or COO.sup.-M.sup.+, wherein M.sup.+ is the equivalent of a metal ion. Also, pyrotechnic devices containing such composition.

Pryotechnic composition and device containing such composition

Compounds having the formula I: ##STR1## wherein M.sub.1, M.sub.2, M.sub.3 , independently, are hydrogen, C.sub.1 -C.sub.4 alkkyl, phenyl, a monovalent or an equivalent of a polyvalent metal atom, ammonium or a substituted ammonium ion; R.sub.1 is C.sub.1 -C.sub.4 alkyl substituted by one or more hydroxy or carboxyl groups; and p is an integer. The new compounds are useful in the treatment of aqueous systems, in particular to inhibit scale deposition from aqueous systems.

Telomeric compound

A method is shown of treating an aqueous system comprising adding to the system a water-soluble tri-copolymer having the formula I:

Treatment of aqueous systems

Aqueous or partly aqueous systems are treated against the corrosion of metals, especially ferrous metals, in contact therewith, and/or against scale deposition therefrom, by adding to these systems from 0.1 to 50 000 ppm of 2-hydroxyphosphonoacetic acid having the formula I ##STR1## or a water-soluble salt thereof.

Systems inhibited against corrosion and/or scale deposition

Process for conditioning metal surfaces to inhibit their corrosion and/or to inhibit scale deposition thereon by treating said surfaces:

Process of inhibiting corrosion of metal surfaces and/or deposition of

A compound or mixture of compounds of the general formula: ##STR1## in which m and n may be 0 or 1 but both cannot be 1, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are independently H or CH.sub.3, X.sup.1, X.sup.2, Z.sup.1 and Z.sup.2 are independently hydrogen or straight or branched chain C.sub.1 -C.sub.4 alkyl; and the water-soluble inorganic or organic salts thereof, with the proviso that at least one of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 must be CH.sub.3, and when m and n are both 0, R.sup.2 and R.sup.3 are each methyl and R.sup.4 and R.sup.5 have their previous significance, when added to an aqueous system imparts one or more of the following beneficial effects to be treated system:

Method of treating aqueous systems with phosphonoadipic acids

A compound or mixture of compounds of the general formula: ##STR1## in which m and n may be 0 or 1 but both cannot be 1, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are independently H or CH.sub.3, X.sup.1, X.sup.2, Z.sup.1 and Z.sup.2 are independently hydrogen or straight or branched chain C.sub.1 -C.sub.4 alkyl; and the water-soluble inorganic or organic salts thereof, with the proviso that at least one of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 must be CH.sub.3, and when m and n are both 0, R.sup.2 and R.sup.3 are each methyl and R.sup.4 and R.sup.5 have their previous significance, when added to an aqueous system imparts one or more of the following beneficial effects to be treated system: (a) the corrosion of ferrous metals in contact with the system is inhibited; (b) the precipitation of scale-forming salts of calcium, magnesium, barium and strontium from the treated aqueous system is inhibited; and (c) inorganic materials present in the treated aqueous system are dispersed.

Phosphonoadipic acid additives to aqueous systems

New piperidine derivatives and in particular esters and amides of substituted (piperidinylidene-4) acetic acid are used as stabilizers for polymers, especially for polyolefines.

Piperidine derivatives

A composition comprising an organic material and, as stabiliser, a compound having the formula ##STR1## and salts thereof, wherein R.sub.1 and R.sub.2 are the same or different and each is an alkyl residue having from 1 to 12 carbon atoms or R.sub.1 and R.sub.2, together with the carbon atom to which they are bound, form a cycloalkyl residue having from 5 to 12 carbon atoms in the ring, Y is 0, hydrogen, a straight-or branched alkyl residue having from 1 to 20 carbon atoms, an alkenyl or alkynyl residue having from 3 to 12 carbon atoms, an aralkyl residue having from 7 to 12 carbon atoms or a group having the formula ##STR2## wherein R is hydrogen, or a methyl or phenyl residue and R.sub.3 is hydrogen or a straight- or branched chain alkyl residue having from 1 to 12 carbon atoms.

Polymers stabilized with substituted 2-(piperidinyl-4')-ethyl alcohol

A method of treating an aqueous system to inhibit the corrosion of metals in contact therewith and/or inhibit the deposition of scale therefrom comprising adding to the aqueous system a minor proportion of a compound of the formula: ##STR1## wherein n is 0 or 1 and when n is O, R.sub.3 and R.sub.4 are the same or different and each is hydrogen, an alkyl group having from 1 to 4 carbon atoms, a benzyl, allyl, --CH.sub.2 PO.sub.3 H.sub.2 -- or --CHCOOH.CH.sub.2 COOH group or a group of formula ##STR2## wherein R.sub.5 is hydrogen, a methyl, --CH.sub.2 COOH or --CH.sub.2 CH.sub.2 COOH group and Z is a group --COOH or --PO.sub.3 H.sub.2, with the proviso that when Z is a PO.sub.3 H.sub.2 group then R.sub.5 is hydrogen or methyl, and when n is 1, R.sub.1 and R.sub.2 are the same or different and each is hydrogen, or a methyl or phenyl residue and R.sub.3 is hydrogen and R.sub.4 is hydrogen, an alkyl group having from 1 to 4 carbon atoms or a --CH.sub.2 CH.sub.2 COOH group, or R.sub.3 and R.sub.4 together may form a methylene group .dbd.CH.sub.2.

Corrosion inhibitors

Epoxy resins stabilized by at least one sterically hindered cyclic amine of the formula I ##STR1## AND SALTS THEREOF IN WHICH Q IS 1 OR 2, X represents an organic grouping which complements the nitrogen-containing ring to give a 5-membered, 6-membered or 7-membered ring, R.sub.1 and R.sub.2 represent methyl or together represent --(CH.sub.2).sub.5 --, R.sub.3 represents methyl, R.sub.4 represents alkyl with 1-5 carbon atoms or together with R.sub.3 represents the radicals --(CH.sub.2).sub.4 --, --(CH.sub.2).sub.5 --, --CH.sub.2 --C(CH.sub.3).sub.2 --NH--C(CH.sub.3).sub.2 --CH.sub.2 -- or --CH.sub.2 --C(CH.sub.3).sub.2 --N(O.sup..)--C(CH.sub.3).sub.2 --CH.sub.2 -- and, if q is 1, Y denotes hydrogen, --O.sup.., hydroxyl, alkyl, substituted alkyl, alkenyl, alkynyl, aralkyl, substituted aralkyl or acyl or, if q is 2, Y denotes alkylene, alkenylene, alkynylene, cycloalkylene or aralkylene.

Stabilized epoxy resins

New piperidine derivatives of 1,3-pyrimidine and 1,3,5-triazine are used as stabilizers for organic materials, especially for polymers.

A composition comprising an organic material and, as stabiliser, a compound having the formula ##SPC1## And salts thereof, wherein R.sub.1 and R.sub.2 are the same or different and each is an alkyl residue having from 1 to 12 carbon atoms or R.sub.1 and R.sub.2, together with the carbon atom to which they are bound, form a cycloalkyl residue having from 5 to 12 carbon atoms in the ring, Y is O, hydrogen, a straight or branched alkyl residue having from 1 to 20 carbon atoms, an alkenyl or alkynyl residue having from 3 to 12 carbon atoms, an aralkyl residue having from 7 to 12 carbon atoms or a group having the formula ##EQU1## wherein R is hydrogen, or a methyl or phenyl residue and R.sub.3 is hydrogen or a straight- or branched chain alkyl residue having from 1 to 12 carbon atoms.

Growing community of inventors

Manchester, United Kingdom

Barry Cook