Servomex Group Limited

Bahram Alizadeh

Martin Lopez

James D Hobby

Ian C Gaskin

Richard P Kovacich

Gary Robert Aylward

Michael Anthony Ratcliffe

Nicky Jay Batson

Michael Lawson

James David Hobby

Martin Picton Lopez

Provided are methods, apparatus and systems for stabilization of a glow discharge from a plasma. Also provided are methods, apparatus and systems for processing optical signals from a stabilised glow plasma with enhanced signal to noise recovery. A first method comprises: generating an electric field within a plasma cell using an alternating excitation voltage to excite particles within the cell, to produce a glow discharge from a plasma in the plasma cell in a resonant condition; monitoring, in each excitation cycle of the alternating excitation voltage, one or more signals that correlate with glow discharge optical emissions from the plasma in the plasma cell; and, in response to said monitoring, controlling one or more operating conditions for the plasma cell to maintain the glow discharge emissions from the plasma within a desired operating range in each excitation cycle of the alternating excitation voltage. A relatively stable glow discharge optical emission is maintained via dynamic resonant feedback control of operating conditions such as the electric field that is used to excite particles within the plasma cell. The stabilization of the glow plasma can be used in glow discharge optical emission spectroscopy (GD-OES) for gas analysis and in other applications.

Glow plasma stabilization

A method and system for the suppression and/or modulation of absorption spectrum artifacts for the purpose of gas detection and concentration measurements using at least one magnetic, electric or electromagnetic field. A field applied selectively to at least one section of the system modulates absorption by influencing quantum energy state transitions of gas species.

Electromagnetic control of absorption and suppression of spectral artifacts

Methods and apparatus for determination of the gas composition of a sample gas using glow discharge optical emission spectroscopy, in which the method comprises: generating one or more oscillating electromagnetic fields within a plasma cell to excite particles within the cell, to produce a glow discharge plasma in the plasma cell, and controlling the operating conditions for the plasma cell while flowing a gas mixture through the plasma cell to maintain glow discharge optical emissions from the plasma within a desired operating range; and monitoring one or more glow discharge optical emissions from the plasma in the plasma cell by measuring the optical emissions, or measuring a signal that correlates with the optical emissions, at twice the plasma excitation frequency; and processing the signal during each excitation cycle of the electromagnetic excitation, to determine the concentration of a gas within a gas mixture flowing through the plasma cell.

Glow plasma gas measurement signal processing

A method and system for reducing the effect of distortions on the baseline signal in an absorption spectroscopy system used for the detection or measurement of chemical species in a medium, whereby one or more correlations or convolutions are performed on the signal using a kernel function. The shape of the kernel function is chosen to reduce the influence of the baseline distortions on the processed measurand determination. The kernel function may also be chosen to enhance the absorption signal.

Method and system for reduction of influence of baseline distortion in absorption spectroscopy measurements

A method and system for correcting the effect of intensity fluctuations of the transmitted light in an absorption spectroscopy system used for the detection or measurement of chemical species in a medium, whereby one or more modulation bursts are imposed onto a light beam that passes through the medium. This burst signal may be obtained by modulating the bias current of a tunable diode laser, and the modulation burst signal may be optimally at the second harmonic of the modulation frequency of a wavelength modulated beam to allow usage of the same signal path processing used for the spectroscopic detection of the measurand for a second harmonic detection system. The burst signal can be controlled using a smooth window function to minimise the effects of non-linear perturbations that are inherent in tunable diode laser wavelength modulation spectroscopy systems, of optical interference fringes (etalons) and of the residual light absorption by background chemical species or the measurand at the wavelength coinciding with the modulation burst.

Method and system for correcting incident light fluctuations in absorption spectroscopy

Provided is a compact apparatus for measuring the flow rate of a fluid. The apparatus includes a heated measure element and a heated reference element which are in substantially the same thermal environment within a measure cell, except that the measure element is situated in the path of the cooling fluid flow and the reference element is sheltered from this direct fluid flow. These elements are arranged as parallel and concentric planar elements that are essentially identical to each other with matching thermal characteristics. The elements are electrically connected in a Wheatstone bridge arrangement. Thermal exchange between the reference and measure elements is used to optimise noise rejection due to common mode background thermal effects. Measured parameters from the bridge can be used to derive the fluid flow rate.

Apparatus for measuring the flow rate of a fluid

A sensor for determining the thermal conductivity of a fluid comprising a sensing module located within a housing having inlet and outlet ports for a fluid under test, the sensing module comprising a reference base surface and a sensing element spaced therefrom and having measure and reference sections, and there being provided electrical power monitoring means for monitoring the power through the measure and reference sections in order to generate a signal indicative of the power difference due to thermal conductivity through the fluid. The sensing element is a thick film printed disc with measure and reference resistors printed on it. All changes in the fluid are common to both the measure and reference sections except for the thermal conductivity of the fluid itself.

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Maidstone, United Kingdom

Bahram Alizadeh