Saudi Arabian Oil Company

King Fahd University of Petroleum and Minerals

Bader Ghazi Al-Harbi

Norah Abdullah Aljeaban

Wengang Li

Sameeh Issa Batarseh

Fawaz M Al-Otaibi

Muhammad Nawaz Tahir

Mohammed H Al-Khaldi

Majad Khan

Tawfik Abdo Saleh

Edreese Alsharaeh

Ayman Mohammed Almohsin

Tao Chen

Qiwei Wang

Ime Bassey Obot

Jin Huang

Mohammed Abudullah Bataweel

Ahmad A Sorour

Abeer Ateeq Alarawi

Mumtaz Ahmad Quraishi

Abdullah Abbas Alrustum

Mohammed H Alkhaldi

Ahmad S Busaleh

Mohammed N Aldahlan

Haneen Omar

Tamim Hassan Alshehri

A foamed composition includes a base fluid, a graphene particle, one or more surfactants, a gas, and an inorganic acid. The foamed composition has a foam quality in a range from 50 to 90 vol/vol % at a temperature in a range from 120° C. to 165° C. A method of stimulating a hydrocarbon-bearing formation includes introducing the foaming composition into the hydrocarbon-bearing formation under a pressure greater than fracturing pressure of the hydrocarbon-bearing formation to generate fractures in the hydrocarbon-bearing formation and generating a foam from the foaming composition inside the hydrocarbon-bearing formation using a gas. The foam has a half-life of 130 to 260 min at 200° F.

Foamed acid system stabilized by two dimensional-graphene and surfactant composite for fracturing application

A method includes preparing an alkyl-modified graphene oxide, injecting the modified graphene oxide into a well, and inhibiting acid-induced corrosion of a steel surface in the well with the modified graphene oxide. A composition includes an alkyl-modified graphene oxide having one or more alkyl functional group covalently bonded to a graphene core through an oxygen-containing linking group. A method of preparing modified graphene oxide includes mixing graphite powder with an oxidant to provide a mixture, adding the mixture to an acid solution including HSO, HPO, or a combination thereof to provide graphene oxide, and reacting the graphene oxide with an alkyl halide by nucleophilic substitution to provide the alkyl-modified graphene oxide.

Graphene based material for corrosion inhibition

The disclosure relates to compositions that include a substrate having attached thereto functional molecules capable of interacting with ions, and related methods. Examples of the substrate include graphene, boron nitride and a graphene-boron nitride hybrid. The compositions can reduce (e.g., prevent) scale formation and/or dissolve scale formations in oil and gas production, transportation, storage, and processing systems, such as scales caused by calcium, barium and/or strontium ions.

Compositions including a substrate and a functional molecule and related methods

Hydraulic fracturing fluids include an aqueous fluid, an acrylamide-based polymer, and a crosslinker that crosslinks the acrylamide-based polymer to form a crosslinked gel. The crosslinker includes a cellulose backbone functionalized with branch structures. The branch structures comprise oxiranylalkanol branches or polyoxiranylalkanol branches. Methods for preparing the hydraulic fracturing fluids and methods for treating subterranean formations with the hydraulic fracturing fluids are disclosed.

Branched cellulose-based hydraulic fracturing fluid crosslinker

This disclosure relates to acidizing retarder compositions and methods of reducing the rate of carbonate dissolution in carbonate acidizing treatments of carbonate formations using the acidizing retarder compositions. The methods may include dissolving one or more retarder compounds in a solution comprising a strong acid to form acidizing retarder compositions, and introducing the acidizing retarder compositions to carbonate formations. The acidizing retarder compositions may include one or more retarder compounds and a strong acid. At least one of the one or more retarder compounds may be a poloxamer. A concentration of the strong acid in the acidizing retarder composition may be 5 weight percent or greater.

Acidizing retarder compositions and methods of reducing a rate of carbonate dissolution using the same

A composition for inhibiting corrosion in gas wells includes a pyrazolopyridine derivative. The pyrazolopyridine derivative includes a pyridyl moiety, a first pyrazole moiety, a second pyrazole moiety, and a phenyl moiety. The first pyrazole moiety is bound to the pyridyl moiety. The second pyrazole moiety is bound to the pyridyl moiety. The phenyl moiety is bound to the pyridyl moiety. The composition can be flowed into a wellbore formed in a subterranean formation, thereby inhibiting corrosion in the wellbore.

Inhibiting corrosion in gas wells

Hydraulic fracturing fluids include an aqueous fluid, an acrylamide-based polymers, and a hyperbranched crosslinker that crosslinks the acrylamide-based polymer to form a crosslinked gel. The hyperbranched crosslinker includes a hyperbranched polyethyleneimine polyoxiranylalkanol having a weight-average molecular weight from 10 kDa to 1500 kDa. The hyperbranched crosslinker may be a product of reacting a hyperbranched polyethyleneimine with an oxiranylalkanol to obtain the hyperbranched polyethyleneimine polyoxiranylalkanol. In examples, the oxiranylalkanol is glycidol. Methods for preparing the hydraulic fracturing fluids and methods for treating subterranean formations with the hydraulic fracturing fluids are disclosed.

Hyperbranched polymer-based hydraulic fracturing fluid crosslinker

Compositions and methods for acid stimulation of a subterranean sandstone formation.

Sandstone stimulation formulations

This application relates to systems and methods for stimulating hydrocarbon bearing rock formations using a downhole hybrid tool for discharging a fracturing solution to a wellbore in the formation and for delivering an output laser beams to the rock formation.

Hybrid stimulation tool and related methods

Systems and methods for delivering an injection fluid into a subterranean well include an injection tool having an injection tool body with an internal cavity. A fluid chamber is located within the internal cavity. A heating chamber includes a pipe segment arranged parallel to the central axis. A one way valve provides a fluid flow path for the injection fluids to travel in a downhole direction through the one way valve, and prevents the flow of fluids through the one way valve in an uphole direction. A fiber optic cable extends to the pipe segment, the fiber optic cable operable to deliver a laser radiation to the pipe segment, heating the pipe segment. The injection tool body provides a fluid flow path from the one way valve to an outside of the injection tool.

Laser and chemical system and methods for well stimulation and scale removal

Systems and methods for delivering inhibitor fluid downhole within a subterranean well include an injection tool. The injection tool has an injection tool body that is an elongated member with an interior storage space. An injector valve is moveable between a closed position where the inhibitor fluid located within the interior storage space is prevented from exiting the interior storage space past the injector valve, and an open position where the injector valve provides a fluid flow path for the inhibitor fluid located within the interior storage space to exit the interior storage space through the injector valve. A water sensor is in signal communication with the injector valve. A refill line extends from an inhibitor fluid storage tank to the interior storage space. A support member suspends the injection tool within the subterranean well.

Downhole scale and corrosion mitigation

A methods and compositions for inhibiting iron sulfide scale in an oil production system having a well in a hydrocarbon-bearing formation. The method includes the steps of: supplying an aqueous scale-inhibiting solution comprising a water-soluble metal compound and a scale inhibitor, the water-soluble metal compound comprising a metal selected from the group consisting of lead, zinc, and combinations of the same; and wherein the scale inhibitor comprises a compound selected from the group consisting of phosphino polymers, inorganic polyphosphinates, organic phosphate esters, organic phosphonates, organic aminophosphates, polyphosphonates, polycarboxylates, and combinations of the same; and injecting the aqueous scale-inhibiting solution through the well such that iron sulfide scale is inhibited in the oil production system.

Iron sulfide scale inhibition in an oil production system

One aspect of an emulsion includes an internal phase including acid, an external phase including supercritical carbon dioxide, and multiple nanoparticles to stabilize the internal phase and the external phase. The acid can include hydrochloric acid. The hydrochloric acid can include 15% hydrochloric acid. The nanoparticles can include hydrophobic nanoparticles. A concentration of nanoparticles in the emulsion can be at least 0.1% by weight. The emulsion can include a corrosion inhibitor. A concentration of the corrosion inhibitor can be in a range of between 0.25% and 0.6% by volume. A ratio of a concentration of the acid to a concentration of the supercritical carbon dioxide can be in a range between 30% and 70%.

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Dammam, Saudi Arabia

Bader Ghazi Al-Harbi