Mitsui Chemicals, Inc.

Aya Nakagawa

Satoshi Yamasaki

Shinji Kiyono

Toshihiko Nakagawa

Hirokazu Morita

Shinya Aoki

Takashi Miura

Takaomi Hayashi

Tetsuya Hamada

Shigeru Mio

Naritoshi Yoshimura

Kengo Goto

Takashi Kanno

Tatsuya Yamashita

Ayako Bando

Hideo Kitagawa

Susumu Saito

Kazuki Sakata

Junya Kiyosu

Jingjing Yang

The application discloses a composition for hard tissue repair comprising a monomer (A), a polymer powder (B) and a polymerization initiator (C), wherein the polymer powder (B) comprises a polymer powder (B-x) having an aspect ratio of 1.10 or more, and the cumulative ratio of powder particles having aspect ratios of 1.00 or more and less than 1.10 in all of the powder particles contained in the composition for hard tissue repair is 75 cumulative % or less, as well as, a kit for hard tissue repair comprising three or more members, in which each of the components of the monomer (A), the polymer powder (B) and the polymerization initiator (C) contained in this composition for hard tissue repair are divided and contained in the members in an optional combination.

Composition for hard tissue repair and kit for hard tissue repair

A polyisocyanate composition contains a modified product of xylylene diisocyanate and a modified product of pentamethylene diisocyanate, and/or a modified product of the xylylene diisocyanate and the pentamethylene diisocyanate. The ratio of the pentamethylene diisocyanate with respect to the total amount of the xylylene diisocyanate and the pentamethylene diisocyanate is 30 mol % or more and 80 mol % or less.

Polyisocyanate composition, polyurethane resin, two-component curable polyurethane composition, coating material, and adhesive material

A polyisocyanate composition contains a modified product of xylylene diisocyanate and a modified product of pentamethylene diisocyanate, and/or a modified product of the xylylene diisocyanate and the pentamethylene diisocyanate. The ratio of the pentamethylene diisocyanate with respect to the total amount of the xylylene diisocyanate and the pentamethylene diisocyanate is 5 mol % or more and 40 mol % or less.

Polyisocyanate composition, polyurethane resin, two-component curable polyurethane composition, and coating material

A polyisocyanate composition contains a modified product of xylylene diisocyanate and a modified product of pentamethylene diisocyanate, and/or a modified product of the xylylene diisocyanate and the pentamethylene diisocyanate. The ratio of the pentamethylene diisocyanate with respect to the total amount of the xylylene diisocyanate and the pentamethylene diisocyanate is 60 mol % or more and 95 mol % or less.

A polyisocyanate composition includes at least a pentamethylenediisocyanate derivative. The polyisocyanate composition contains 5 mass % or more and 95 mass % or less of a uretdione derivative composed of an isocyanate bimolecular-product of pentamethylenediisocyanate.

Polyisocyanate composition, polyurethane resin, and coating

The method for producing trans-rich-1,4-bis(aminomethyl)cyclohexane includes blending 1,4-bis(aminomethyl)cyclohexane with an alkali metal compound and XDA and heating the mixture to isomerize 1,4-bis(aminomethyl)cyclohexane so that the trans isomer content relative to the cis/trans isomers in total is more than 70 mass %, and purifying the isomerized 1,4-bis(aminomethyl)cyclohexane by distillation after the isomerization step. The alkali metal compound is at least one compound selected from the group consisting of alkali metal hydride, alkali metal amide, and alkyl alkali metal. In the isomerization step, 0.01 mol or more and less than 4 mol of XDA is blended relative to 100 mol of 1,4-bis(aminomethyl)cyclohexane, a dimer produced from one molecular of 1,4-bis(aminomethyl)cyclohexane and one molecular of XDA, and a trimer produced from two molecules of 1,4-bis(aminomethyl)cyclohexane and one molecular of XDA are produced, and the dimer content is 5 mass % or more and less than 75 mass % relative to the dimer and trimer in total.

Method for producing trans-rich-1,4-bis(aminomethyl)cyclohexane

A polycarbodiimide composition is a reaction product of polyisocyanate having a primary isocyanate group and alcohols, wherein in an infrared absorption spectrum, the intensity ratio (IR/IR) of absorbance IRat or near 2120 cmdue to stretching vibration of the carbodiimide group relative to absorbance IRat or near 1720 cmdue to stretching vibration of the uretonimine group and urethane group is 1.5 or more and 4.5 or less.

Polycarbodiimide composition, method for producing polycarbodiimide composition, aqueous dispersion composition, solution composition, resin composition, and cured resin

The present invention is a method for producing a polyhydric phenol, including the following steps (a) to (d): (a) a first step of producing (4S,5R,6S)-4,5,6-trihydroxy-2-cyclohexcene-1-one from 2-deoxy-scyllo-inosose by a dehydration reaction; (b) a second step of producing 1,2,4-trihydroxybenzene from the (4S,5R,6S)-4,5,6-trihydroxy-2-cyclohexene-1-one obtained in the first step by a dehydration reaction; (c) a third step of producing 4-hydroxycyclohexane-1,3-dione from the 1,2,4-trihydroxybenzene by a catalytic hydrogenation reaction with the use of a metal catalyst; and (d) a fourth step of producing hydroquinone by heating the 4-hydroxycyclohexane-1,3-dione.

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Sodegaura, Japan

Aya Nakagawa