Covestro Deutschland Ag

Bayer Intellectual Property Gmbh

Bayer Materialscience Ag

Bayer Technology Services Gmbh

Covestro Intellectual Property Gmbh & Co. Kg

Bayer Aktiengesellschaft

Lanxess Deutschland Gmbh

Futurecarbon Gmbh

Aurel Wolf

Jörg Hofmann

Christoph Gürtler

Leslaw Mleczko

Kai Laemmerhold

Stefan Grasser

Volker Michele

Christoph Guertler

Jens Langanke

Hartmut Nefzger

Thomas Ernst Müller

Sigurd Buchholz

Reiner Rudolf

Matthias Wohak

Ilja Peckermann

Stefanie Braun

Christian Münnich

Walter Leitner

Michael Traving

Carsten Koopmans

Stefan Westhues

Burkhard Köhler

Bert Klesczewski

Daniel Gordon Duff

Claudine Rangheard

Werner Obrecht

Pieter Ooms

Jan Weikard

Johann Rechner

Rainer Weber

Dieter Mager

Michael Bierdel

Urs Rauwald

Sohajl Movahhed

Muhammad Afzal Subhani

Hans-Georg Pirkl

Rolf Bachmann

Jürgen Kintrup

Heiko Hocke

Thomas Früh

Stephan Schubert

Torsten Ziser

Markus Dugal

Stefan Grabowski

Ralph Weber

Friedhelm Risse

Michael R Buchmeiser

Helmut Meyer

Horst Zwick

Giulio Lolli

Elena Frick-Delaittre

Daniel Thiel

Oliver Felix-Karl Schlüter

Jens Assmann

Markus Meuresch

Yvonne Dienes

Nicole Welsch

Ralph Schellen

Stefan Naumann

Timo Breuer

Lars Krueger

Mike Schuetze

Persefoni Hilken

Annika Stute

Julien Barruet

Anthony Kermagoret

Angelina Prokofieva

Franco Doro

Joachim Simon

Volker Marker

Reinhard Schomaecker

Reinhard Schomäcker

Karolina Walker

Jens Stefan Roggan

Konstantinos Metaxas

Jochen Norwig

Monika Heinz

Elmar Bramer-Weger

Thoams Ernst Mueller

Maziar Kakhi

Jens Aβmann

Alexandra Groβe Böwing

Kilian Tellmann

Martin Schmid

Matthias Voetz

Leslaw Mileczko

Philipp Nicholas Wagner

Min Wang

Olga Linker

Florian Kessler

Yvonne Reimann

Ralf Schellen

Alexander Karpenko

Martin Machat

Waldemar Schlundt

Mathias Glassner

Hagen Altmann

Michelle Tupinamba Lima

Michael Gradzielski

A process for producing a thermoplastic polyoxazolidinone comprising copolymerizing a diisocyanate compound (A) with a bisepoxide compound (B) in the presence of a specific a quaternary ammonium, quaternary phoshonium and/or quaternary stibonium-based catalyst (C), a compound (D), a compound (F) wherein compound (D) and compound (F) independently comprises at least one of a monofunctional isocyanate, a monofunctional epoxide, a cyclic carbonate, a monofunctional alcohol, a monofunctional amine optionally in a solvent (E), and wherein the process is in the absence of a solvent (G) with a boiling point higher than 200° C., preferably higher than 190° C. and more preferably higher than 180° C. at 1 bar (absolute). The invention is also related to the resulting thermoplastic polyoxazolidinone.

Method for the production of a thermoplastic polyoxazolidinone

The present invention relates to a process of preparing a poly(anthranilamide) comprising the steps: (A) providing an anthranilate, and (B) reacting the anthranilate by polycondensation and separation of the alcohol on which the anthranilate is based in the presence of a catalyst to poly(anthranilamide), the poly(anthranilamides) obtained in this way and their use in the production of fibers of composite materials.

Process of preparing a poly(anthranilide), poly(anthranilide) and its use

A process for producing a thermoplastic polyoxazolidinone comprising copolymerizing a diisocyanate compound (A) with a bisepoxide compound (B) in the presence of a specific a quaternary ammonium, quaternary phoshonium and/or quaternary stibonium-based catalyst (C), a compound (D), a compound (F) wherein compound (D) and compound (F) independently comprises at least one of a monofunctional isocyanate, a monofunctional epoxide, a cyclic carbonate, a monofunctional alcohol, a monofunctional amine optionally in a solvent (E), and wherein the catalyst (C) is added in at least two portions (C-1) and (C-2). The invention is also related to the resulting thermoplastic polyoxazolidinone.

The invention relates to a method for producing a polyoxymethylene polyoxyalkylene block copolymer, said method including the process of reacting a polymer formaldehyde compound with alkylene oxide in the presence of a double metal cyanide (DMC) catalyst and an H-functional starter substance, wherein the theoretical molar mass of the polymer formaldehyde compound is lower than the theoretical molar mass of the H-functional starter substance, and the polymer formaldehyde compound has at least one terminal hydroxyl group, the theoretical molar mass of the H-functional starter substance being at least 500 g/mol. In the method according to the invention, a mixture i) is provided comprising the DMC catalyst and the H-functional starter substance in step (i); the polymer formaldehyde compound is then added to the mixture (i) in step (ii), thereby forming a mixture (ii); and the alkylene oxide is added in step (iii), step (ii) being carried out at the same time as or prior to step (iii).

Method for producing polyoxymethylene polyoxyalkylene block copolymers

A process for producing thermoplastic polyoxazolidinone, comprising the following steps: (i) Reaction of a diisocyanate compound (A) with a bisepoxide compound (B) in the presence of a catalyst (C) and a compound (D) in a solvent (E) forming an intermediate compound (F) and (ii) Reaction of a compound (G) with the intermediate (F) formed in step (i), wherein the bisepoxide compound (B) comprises isosorbide diglycidylether, wherein compound (D) is one or more compounds selected from the group consisting of monofunctional isocyanate and monofunctional epoxide, and wherein compound (G) is an alkylene oxide. The invention is also related to the resulting thermoplastic polyoxazolidinone.

Method for the production of thermoplastic polyoxazolidinone polymers

A process for producing thermoplastic polyoxazolidinone, comprising the following steps: (i) Reaction of a diisocyanate compound (A) with a bisepoxide compound (B) in the presence of a catalyst (C) and a compound (D) in a solvent (E) forming an intermediate compound (F) and (ii) Reaction of a compound (G) with the intermediate (F) formed in step (i), wherein compound (D) is one or more compounds selected from the group consisting of monofunctional isocyanate and monofunctional epoxide, and wherein compound (G) is an alkylene oxide. The invention is also related to the resulting thermoplastic polyoxazolidinone.

Method for the production of thermoplastic polyoxazolidone polymers

A process for producing rigid PUR/PIR foams comprising A1 an isocyanate-reactive component, A2 a flame retardant, A3 a blowing agent, A4 a catalyst, A5 optionally auxiliaries and additives, and B an organic polyisocyanate component. Component A1 comprises a triurethane triol A1.1 and a compound A1.2 selected from the group consisting of polyether polyol, polyester polyol, polyether carbonate polyol, and polyether ester polyol. Also disclosed is a rigid PUR/PIR foam, an insulating material, a composite element, and a mixture.

Flame-retarded rigid polyurethane foams

The present invention describes a process for producing an elastomer, preferably a polyurethane-containing elastomer, by reacting a polyol component (A) comprising at least one polyether carbonate polyol (A-1) containing carbon-carbon double bonds with a component (B) which is reactive with OH groups and contains at least one compound reactive toward OH groups, preferably an isocyanate component (B-1) containing NCO groups, in the presence of a free-radical initiator (C), preferably at least one peroxide (C-1), and optionally a catalyst (D), where the molar ratio of the OH-reactive groups of component (B) reactive with groups, to the OH groups of the polyol component (A) containing carbon-carbon double bonds, is greater than 1.0. It further relates to elastomers obtainable by such a process, preferably polyurethane elastomers, the use thereof, and two-component systems for production of elastomers, preferably polyurethane elastomers.

Process for producing elastomers

A process for producing thermoplastic polyoxazolidinone comprising copolymerization of a diisocyanate compound (A) with a bisepoxide compound (B) in the presence of a catalyst (C) and a compound (D) in a solvent (E), wherein the catalyst (C) is selected from the group consisting of alkali halogenides and earth alkali halogenides, and transition metal halogenides, compound (D) is selected from the group consisting of monofunctional isocyanate, monofunctional epoxide, and wherein the process comprises step (&#x3b1;) of placing the solvent (E) and the catalyst (C) in a reactor to provide a mixture, and adding the diisocyanate compound (A), the bisepoxide compound (B) and the compound (D) in step (&#x3b2;) to the mixture resulting from the step (&#x3b1;). The invention is also related to the resulting thermoplastic polyoxazolidinone.

The invention relates to a method for producing polyether carbonate polyols by adding alkylene oxides and carbon dioxide to an H-functional starter substance in the presence of a double metal cyanide (DMC) catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, wherein (&#x3b3;) alkylene oxide and carbon dioxide are added to an H-functional starter substance in a reactor with a total pressure (absolute) of 5 to 120 bar in the presence of a double metal cyanide catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, and a reaction mixture containing the polyether carbonate polyol is obtained, (&#x3b4;) the reaction mixture obtained in step (&#x3b3;) remains in the reactor or is optionally continuously transferred to a downstream reactor at a starting total pressure (absolute) of 5 to 120 bar, the content of free alkylene oxide in the reaction mixture being reduced in the course of a downstream reaction in each case, and the total pressure (absolute) can be reduced by up to 50% during the step (&#x3b4;), and (&#x3b6;) the content of highly volatile components of the obtained reaction mixture is thermally reduced at a temperature of 80&#xb0; C. to 200&#xb0; C. The invention is characterized in that (&#x3b5;) the reaction mixture resulting from step (&#x3b4;) is brought to a total pressure (absolute) of &#x2264;2.0 bar, preferably 0.5 bar to 2.0 bar, particularly preferably 0.9 bar to 1.1 bar, prior to step (&#x3b6;) and then left at a temperature of 80 to 180&#xb0; C. for a dwell time of at least 0.5 h. After the dwell time has expired, 5 to 100 ppm of component K is added to the resulting mixture, component K being selected from at least one compound which contains a phosphorus-oxygen-hydrogen group.

Method for producing polyether carbonate polyols

The invention relates to a process for producing polyoxymethylene block copolymers, comprising the step of activating the DMC catalyst in the presence of an OH-terminated polymeric formaldehyde starter compound by means of a defined amount of alkylene oxide, optionally followed by polymerization with alkylene oxides, if necessary in the presence of other comonomers. The invention further relates to polyoxymethylene block copolymers that can be obtained by means of such a process and to the use of these for producing polyurethane polymers.

Process for the production of polyoxymethylene block copolymers

The present invention relates to a method for producing polyether carbonate polyols by attaching alkyloxides and carbon dioxide to H-functional starter compounds, characterized in that at least one alcohol containing at least two urethane groups is used as the H-functional starter compound. The invention further relates to polyether carbonate polyols containing a structural unit of the formula (IV), wherein: Rdenotes a linear or branched Cto C-alkylene, which optionally can be interrupted by heteroatoms of O, S or N and can be substituted, preferably by CH&#x2014;CHor CH&#x2014;CH(CH); Rdenotes a linear or branched Cto C-alkylene, Cto C-cycloalkylene, Cto C-alkylene, Cto C-aralkylene, Cto C-alkenylene, Cto C-alkynylene, each of which can optionally be interrupted by heteroatoms such as O, S or N and/or can be substituted with alkyl, aryl and/or hydroxyl groups, preferably Cto C-alkyls; Rdenotes H, linear or branched Cto C-alkyl, Cto C-cycloalkyl, Cto C-aryl, Cto C-aralkyl, Cto C-alkenyl, Cto C-alkynyl, each of which can optionally be interrupted by heteroatoms such as O, S or N and/or can each be substituted with alkyl, aryl and/or hydroxyl groups, preferably H; Rdenotes H, a linear of branched Cto C-alkyl, Cto C-cycloalkyl, Cto C-aryl, Cto C-aralkyl, Cto C24-alkenyl, C2 to C-alkynyl, each of which can optionally be interrupted by heteroatoms such as O, S or N and/or can each be substituted with alkyl, aryl and/or hydroxyl groups, preferably H; Rdenotes a linear or branched Cto C-alkylene, which can optionally be interrupted by heteroatoms such as O, S or N and can be substituted, preferably by CH&#x2014;CHor CH&#x2014;CH(CH); and wherein R1 to R5 can be identical or different to each other.

Use of alcohols which contain at least two urethane groups for producing polyether carbonate polyols

The present invention relates to a method for producing polyether carbonate polyols by addition of one or more alkylene oxides and carbon dioxide to one or more H-functional starter substances in the presence of at least one DMC catalyst, in which the reaction is conducted in a main reactor () and a tubular reactor () connected as a post reactor downstream thereof, wherein the method is characterized in that at the outlet () of the tubular reactor () a temperature is set that is at least 10&#xb0; C. above the temperature in the inside of the main reactor (). The invention further relates to a device for carrying out said method.

Method for the production of polyether carbonate polyols and device therefor

The invention relates to a process for producing polyether carbonate polyols through an addition reaction of alkylene oxides and carbon dioxide onto one or more H-functional starter substances in the presence of a double metal cyanide catalyst or in the presence of a metal complex catalyst based on the metals zinc and/or cobalt, characterized in that one or more H-functional starter substances containing at least 1000 ppm of component (K) is/are continuously metered into the reactor during the reaction, where component (K) is selected from at least one compound containing a phosphorus-oxygen bond and a phosphorus compound that can form one or more P&#x2014;O bonds through reaction with OH-functional compounds.

The invention relates to a method particularly for reacting phosgene with compounds that contain hydroxyl, thiol, amino and/or formamide groups, comprising the steps of: (I) providing a reactor which has a first reaction chamber () and a second reaction chamber (), the first and the second reaction chambers being separated from one another by means of a porous carbon membrane (); (II) providing carbon monoxide and chlorine in the first reaction chamber; and simultaneously (III) providing a compound containing hydroxyl, thiol, amino and/or formamide groups in the second reaction chamber. The porous carbon membrane is configured to catalyze the reaction of carbon monoxide and chlorine to obtain phosgene, and to allow this formed phosgene to pass into the second reaction chamber. The invention also relates to a reactor that is suitable for carrying out the claimed method.

Method for phosgenating compounds containing hydroxyl, thiol, amino and/or formamide groups

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Wülfrath, Germany

Aurel Wolf