Kyushu University

Sumitomo Riko Company Limited

Japan Science and Technology Agency

Sumitomo Rubber Industries Limited

Adeka Corporation

Atsushi Takahara

Hitoshi Yoshikawa

Hideyuki Otsuka

Shigeaki Takamatsu

Yota Kokubo

Motoyasu Kobayashi

Ryosuke Matsuno

Kazunobu Hashimoto

Yasuhisa Minagawa

Tetsuo Mizoguchi

Yasuhiko Kondo

Jin Nishida

Shingi Kumagai

Tetsuo Kamimoto

Yutaro Taguchi

Masaharu Tsuji

Hideaki Yukutake

Ryousuke Matsuno

Yuji Higaki

Hirohmi Watanabe

Hidetsugu Torihara

Yuki Norizoe

Daiki Murakami

Hiroshi Jinnai

The object of the present invention is to provide a novel adhesive. The characteristics of the present invention is an adhesive comprising an organic polymer having a main chain formed by a water-soluble polymer unit, and a hydrophilic organic group and a self-assembling group bonded to the water-soluble polymer unit; and a curing agent.

Adhesive

The object of the present invention is to provide a polymer brush which forms phase-separated structure in a gas phase. The polymer brush according to the present invention comprises a substrate and a polymer layer wherein the polymer layer comprises polymer chains each of which has one end fixed on the substrate and other end free-ended, and wherein a state of phase-separation between a polymer dense part and a polymer thin part reversibly changes in the polymer layer.

Polymer brush

A reactive ionic liquid to be used as an ionic component that is contained in an ion-containing layer in a transducer arranged in contact with a high-resistance layer as a dielectric layer of the transducer, and is restrained from migrating from the ion-containing layer to the high-resistance layer on application of a voltage is provided. The reactive ionic liquid comprises an ion pair that consists of an anion and a cation. (a) The cation (a1) is an imidazolium or quaternary ammonium cation, and (a2) comprises a reactive group that consists of an alkoxysilyl or phosphonate group. (b) The anion (b1) is a sulfonate, sulfonylimide, or nitrobenzoate anion.

Reactive ionic liquid, and ion-immobilized metal oxide particle, ion-immobilized elastomer, and transducer using same

A conductive material includes metal nanowires and an extensible copolymer having an N&#x2014;C&#x2550;O structure and combined with the metal nanowires. The conductive material has excellent elongation properties and has an electrical resistance that is unlikely to increase even when the conductive material is extended. A method for producing a conductive material includes: a copolymer production step of polymerizing a plurality of monomers including a growth direction control monomer that has an N&#x2014;C&#x2550;O structure and controls a growth direction of metal nanowires to produce an extensible copolymer; a reaction step of reacting a metal compound in a solvent containing the copolymer to grow metal nanowires in a longitudinal direction; and an extraction step of extracting a product from the solution after the reaction.

Conductive material, method for producing the conductive material, and transducer including the conductive material

A novel material is provided herein which is suitable for use in a precursor of a polymer coating material that coats a polymer on a surface of a base material to provide the base material with surface modification and/or functionality assignment. A composite material characterized in that a compound having a polymerization initiation site containing a halogen group is incorporated in a crosslinked structure comprising a catechol derivative or a phenol derivative represented by the following formula (I). In the formula (I), R may be interrupted by an oxygen molecule and represents a hydrocarbon group with 2 to 20 carbons that has at least one double bond site, and A represents a hydrogen atom, a hydroxyl group, or an alkoxy group with 1 to 20 carbons. 

Composite material, and polymer coating material precursor produced using same

A dielectric film includes an elastomer and nanoparticles dispersed in the elastomer while chemically bound to the elastomer. The nanoparticles have cyano groups and are manufactured by a sol-gel process using an organometallic compound. A method for manufacturing a dielectric film includes: producing a chelate compound of an organometallic compound; producing a sol of metallic oxide particles having cyano groups by adding a silane coupling agent having a cyano group, an organic solvent, and water to the chelate compound; preparing a mixed solution by mixing the sol of the metallic oxide particles having cyano groups and a polymer solution containing a rubber polymer having a functional group capable of reacting with a hydroxy group; and forming a dielectric film by applying the mixed solution to a substrate and by curing a coating film.

Dielectric film, method for manufacturing the same, and transducer including the same

An ion-immobilized metal oxide particle includes a metal oxide particle and an anion that itself includes a) a reactive group that consists of an alkoxysilyl group and b) an anionic group consisting of a carboxylate (&#x2014;COO) group or a sulfonate (&#x2014;SO) group, the anion being immobilized to the metal oxide particle via a silanol group derived from the reactive group. An elastomer includes the ion-immobilized metal oxide particle, and a transducer includes the elastomer.

Provided are: surface modification method for imparting slidability to surface of elastic body such as vulcanized rubber or thermoplastic elastomer without using expensive self-lubricating resin; surface-modified elastic body with polymer brush formed on its surface; and gasket for injector and injector formed of surface-modified elastic body. The surface modification method applies to surface of thermoplastic elastomer or vulcanized rubber. The surface modification method comprises the step of forming hydroxyl group on surface of to-be-modified object such as rubber so that water contact angle of the surface becomes 8 to 50 degrees smaller than original water contact angle in unmodified condition, the step of forming polymerization initiation site by subjecting the hydroxyl group to action of secondary or tertiary organic halide, and the step of growing polymer brush on the surface of to-be-modified object by subjecting monomer to radical polymerization at the polymerization initiation site acting as a point of initiation.

Surface modification method, surface-modified elastic body, gasket for injector, injector, and tire

A reactive ionic liquid to be used as an ionic component that is contained in an ion-containing layer in a transducer arranged in contact with a high-resistance layer as a dielectric layer of the transducer, and is restrained from migrating from the ion-containing layer to the high-resistance layer on application of a voltage is provided. The reactive ionic liquid comprises an ion pair that consists of an anion and a cation. In the reactive ionic liquid, (a) the anion comprises (a1) a reactive group that consists of an alkoxysilyl group and (a2) an anionic group consisting of a carboxylate (&#x2014;COO) group or a sulfonate (&#x2014;SO) group. (b) The cation (b1) consists of an imidazolium, ammonium, pyrrolidinium, morpholinium, or phosphonium cation, and (b2) does not comprise an N&#x2014;H group or a P&#x2014;H group.

A method for producing a polymer nanocomposite, includes: after expanding an interlayer space of a layered inorganic compound using an organic onium salt, immobilizing a radical polymerization initiator having a group represented by formula (1) on an interlayer surface of the layered inorganic compound via a covalent bond; and carrying out surface-initiated radical polymerization in a monomer from the immobilized radical polymerization initiator. Preferably, in the radical polymerization initiator having the group represented by the general formula (1), at least one of X1 to X3 in the formula is a chlorine atom, or R1 in the formula is a C1-25 alkylene group or a C2-25 alkenylene group optionally interrupted by an oxygen atom or an ester group and optionally substituted by a phenyl group: R1 represents a C1-25 alkylene group, a C2-25 alkenylene group, a C5-8 cycloalkylene group, or a C6-12 arylene group.

Growing community of inventors

Fukuoka, Japan

Atsushi Takahara