Mitsubishi Gas Chemical Company, Inc.

Atsushi Sakai

Yuuki Sato

Nobuhiko Matsumoto

Naoki Kaneko

Jin Nakamura

Fumihiro Fukuda

A flame-retardant polyimide molding material containing a semi-aromatic polyimide resin (A) and further containing 15 to 80 mass % of either of the following component (B1) or component (B2): (B1) graphite (B2) a combination of two or more selected from the group consisting of graphite, a fluorine resin, and carbon fiber; and a molded article including the same.

Flame-retardant polyimide shaping material and shaped body

To provide a multilayered body with high adhesion between a resin layer containing a nanofiber or the like and a metal layer, and a method for manufacturing a multilayered body. The multilayered body contains: a metal layer having an uneven region with an average length (RSm) of a contour curve element from 0.5 to 10 μm; and a resin layer in contact with the uneven region of the metal layer, the resin layer containing a thermoplastic resin and a fibrous filler, the fibrous filler having a number average fiber diameter (F) of less than 1 μm, and a ratio (RSm/F) of the average length (RSm) of the contour curve element of the uneven region to the number average fiber diameter (F) from 1 to 20000.

Multilayered body and method for manufacturing same

A polyimide resin composition containing a polyimide resin (A) and a polyetherimide sulfone resin (B), wherein the polyimide resin (A) contains a repeating structural unit represented by the following formula (1) and a repeating structural unit represented by the following formula (2), and a content ratio of the repeating structural unit of the formula (1) with respect to the total of the repeating structural unit of the formula (1) and the repeating structural unit of the formula (2) is 20 to 70 mol %; and a molded article containing the same. (Rrepresents a divalent group having from 6 to 22 carbon atoms containing at least one alicyclic hydrocarbon structure; Rrepresents a divalent chain aliphatic group having from 5 to 16 carbon atoms; and Xand Xeach independently represent a tetravalent group having from 6 to 22 carbon atoms containing at least one aromatic ring.)

Polyimide resin composition and molded body

A polyimide resin composition containing a polyimide resin (A) and a nanocarbon material (B), wherein the polyimide resin (A) contains a repeating structural unit represented by the following formula (1) and a repeating structural unit represented by the following formula (2), and a content ratio of the repeating structural unit of the formula (1) with respect to the total of the repeating structural unit of the formula (1) and the repeating structural unit of the formula (2) is 20 to 70 mol %: wherein Rrepresents a divalent group having from 6 to 22 carbon atoms containing at least one alicyclic hydrocarbon structure; Rrepresents a divalent chain aliphatic group having from 5 to 16 carbon atoms; and Xand Xeach independently represent a tetravalent group having from 6 to 22 carbon atoms containing at least one aromatic group.

Polyimide resin composition

A polyimide resin composition containing a polyimide resin (A) and a fluororesin (B), wherein the polyimide resin (A) contains a repeating structural unit represented by the following formula (1) and a repeating structural unit represented by the following formula (2), a content ratio of the repeating structural unit of the formula (1) with respect to the total of the repeating structural unit of the formula (1) and the repeating structural unit of the formula (2) is 20 to 70 mol %, and the fluororesin (B) has a weight loss percentage measured using a differential scanning calorimeter after heating from 100° C. to 450° C. at a heating rate of 10° C./min in an air atmosphere of 1% or less: wherein Rrepresents a divalent group having from 6 to 22 carbon atoms containing at least one alicyclic hydrocarbon structure; Rrepresents a divalent chain aliphatic group having from 5 to 16 carbon atoms; and Xand Xeach independently represent a tetravalent group having from 6 to 22 carbon atoms containing at least one aromatic ring; and a molded article thereof.

A polyimide resin composition includes a polyimide resin (A) including a repeating structural units of formulas (1) and (2). The content ratio of the repeating structural unit of the formula (1) with respect to the total of the repeating structural units of the formulas (1) and (2) is 20 to 70 mol %. The polyimide resin composition further includes a fatty acid metal salt (B) including a fatty acid having 12 to 36 carbon atoms and optionally having a hydroxy group and at least one of an alkali metal, an alkaline earth metal, and a transition metal: wherein Rrepresents a divalent group having 6 to 22 carbon atoms containing at least one alicyclic hydrocarbon structure; Rrepresents a divalent chain aliphatic group having 5 to 16 carbon atoms; and Xand Xeach independently represent a tetravalent group having 6 to 22 carbon atoms containing at least one aromatic ring.

A polyimide resin composition containing a polyimide resin (A) and a phosphinic acid metal salt-based flame retardant (B), the polyimide resin (A) containing repeating structural units of formulae (1) and (2):

A flame-retardant polyimide molding material and a molded article including the flame-retardant polyimide molding material, where the flame-retardant polyimide molding material includes a semi-aromatic polyimide resin (A) and carbon fiber (B), and the flame-retardant polyimide molding material includes 15 to 80 mass % of the carbon fiber (B).

Flame-retardant polyimide molding material and molded object

A resin molded article having a microphase-separated structure, the resin molded article containing a polyimide resin (A) and a polyether ketone resin (B), the polyimide resin (A) containing repeating structural units of formulae (1) and (2):

Resin molding

Provided is a polyimide powder composition containing a thermoplastic polyimide resin powder (A) and silica particles (B) having a volume average particle size D50 of 90 nm or less.

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Kanagawa, Japan

Atsushi Sakai