Samsung Sdi Co., Inc.

Samsung Electronics Co., Ltd.

Sanyo Electric Co., Ltd.

Kabushiki Kaisha Toshiba

Atsuo Sonai

Kunihiro Nakato

Hiroyuki Nishide

Takahiro Tago

Shuji Yamada

Motoya Kanda

Hiroko Endo

Hiroyasu Yoshizawa

Kazuo Saito

Atsushi Ohma

Kenji Murata

Yasuji Ogami

Michio Hori

Soichiro Shimotori

Makoto Harada

Teruyuki Okayasu

Toshihiko Matsuda

A solid polymer fuel cell stack has a layered product comprised of a plurality of cells stacked, and is so structured that the layered product is fastened by end plates on both sides thereof via a current collector and an insulating plate on each side. Each cell is structured such that an MEA is sandwiched between an anode-side plate, which is provided with a fuel path disposed counter to an anode of the MEA, and a cathode-side plate, which is provided with an oxidizing agent path disposed counter to a cathode of the MEA. An MEA is comprised of a solid polymer electrolyte membrane, an anode and a cathode. The solid polymer electrolyte membrane is composed of powder of basic polymer such as polybenzimidazole, strong acid such as phosphoric acid impregnated with the basic polymer, and binder such as fluorocarbon resin.

Electrolyte for fuel cell, membrane electrode assembly, fuel cell stack and fuel cell system

A membrane electrode assembly (MEA) is structured such that an anode is joined, via a carbon layer, to one surface of a solid polymer electrolyte membrane containing PBI and phosphoric acid and a cathode is joined to the other surface. The carbon layer is constituted by carbon powder and a first binder. Carbon black, carbon nanotube and the like may be used as carbon powder. The thickness of the carbon layer is preferably greater than that of the solid polymer electrolyte membrane.

Membrane electrode assembly, fuel cell stack and fuel cell system

A proton conductive polymer electrolyte includes an acidic functional group-containing aromatic hydrocarbon polymer and an electron donor functional group-containing compound. When used in a fuel cell, the proton conductive polymer electrolyte provides a long-term stable power generating performance at an operating temperature from 100&#xb0; C. to 200&#xb0; C. in non-humidified conditions or a relative humidity of 50% or less.

Proton conductive polymer electrolyte and fuel cell including the same

A fuel cell electrolyte according to one aspect of the invention contains a basic polymer and a phosphate compound expressed by the following general formula (1): where R represents an alkyl or alkoxyalkyl group, and n is 1 or 2.

Fuel cell electrolyte, membrane electrode assembly, and method of manufacturing fuel cell electrolyte

Aspects of the present invention provide a proton conductive electrolyte suitable for a fuel cell material and a fuel cell including the proton conductive electrolyte. More particularly, aspects of the present invention provide a proton conductive electrolyte that has good proton conductivity and can be used to form a membrane having good flexibility. As a result, the proton conductive electrolyte can be used in a fuel cell, the electrolyte membrane of a fuel cell or the electrodes thereof, and can provide a solid polymer fuel cell having high current density, high power and long life-time in a dry environment (relative humidity of 50% or less) at an operating temperature of 100 to 200&#xb0; C.

Proton conductive electrolyte and fuel cell comprising the same

An electrolyte for a fuel cell comprising a proton conducting resin comprising a backbone comprising a polyurea resin and side chains that comprise an active hydrogen group at a terminal and a fuel cell employing the same are provided. The electrolyte has improved proton conductivity, heat resistance, and mechanical strength.

Electrolyte for fuel cell and fuel cell employing the same

Dimensional change occurring in a fuel cell electrolyte including a basic polymer after the electrolyte is doped with acid is regulated and the occurrence of wrinkles and the like is reduced. A fuel cell electrolyte comprises a basic polymer and an organic phosphonic acid expressed by the following general formula (1): where R represents an alkyl, aryl, acyl, amino, phosphonic group or a derivative of the functional group, and n is 1 or 2.

A fuel cell electrolyte comprises: a basic polymer; an organic phosphonic acid expressed by the following general formula (1); and a hydrolyzable phosphate compound expressed by the following general formula (2): where R represents an alkyl, aryl, acyl, amino, phosphonic group or a derivative of the functional group, and n is 1 or 2, and R represents an alkyl or alkoxyalkyl group, and n is 1 or 2.

The invention provides a proton-conducting electrolyte that has excellent proton-conducting properties, heat resistance, and chemical stability without containing any fluorine. The proton-conducting electrolyte contains polyamide sulfamidic acid in which a polyamide backbone has side chains of sulfamidic acid groups. The polyamide sulfamidic acid may be represented by the formula: where Arand Arare each an aromatic ring or a group containing an aromatic ring and n is the average degree of polymerization and is an integer between 100-300,000.

Proton-conducting electrolyte and fuel cell using the same

A fuel cell system comprising a fuel cell stack and a fuel reformer for reforming a fuel and supplying a reformed fuel to the fuel cell stack, further comprising a total enthalpy heat exchanger for exchanging heat and moisture between a reacted gas and an unreacted gas from the fuel cell stack, a separator for separating moisture from the fuel gas fed from the fuel cell stack or from an oxidant gas, and a mixer for mixing part of the moisture separated by the separator with a medium having a freezing point of 0&deg; C. or less.

Polymer electrolyte fuel cell system

To generate electric energy to a load such as an electric car or the like, a fuel cell power generation system includes a fuel cell composed of a fuel electrode and an oxygen electrode with an electrolytic layer interposed therebetween so as to continuously supply electric power to the load, a secondary cell for supplying a required quantity of electric energy to the load at least during the initial time until the generation of electric energy is started with the fuel cell and a shifting unit serving to shift the power source of electric energy to the load from the fuel cell main body to the secondary cell or from the secondary cell to the fuel cell. An electrolytic layer constituting the fuel cell is composed of a film of high molecular material having ionic conductivity, and the secondary cell is a secondary lithium cell consisting of a nonaqueous solution based material or a solid electrolyte based material as an electrolyte.

Fuel cell power generation system

A fuel cell proper is constructed by superposing a plurality of unit cells having a solid polymer electrolyte membrane held between an anode and a cathode. This fuel cell proper is cooled with a liquid having a boiling point closely approximating the working temperature of the fuel cell. Water and a liquid fuel as liquid raw materials are gasified with a liquid raw material gasifying mechanism. This liquid raw material gasifying mechanism uses, as at least part of the heat source for gasification of water, the waste heat from the reformer and the heat possessed by the reformed gas. The gasified water and liquid fuel are reformed by the reformer into a hydrogen rich gas. The gas thus produced is supplied to the anode in the fuel cell proper. The cathodes are supplied with air to effect a reaction for power generation.

Growing community of inventors

Kanagawa, Japan

Atsuo Sonai