Toyota Shatai Kabushiki Kaisha

Kurashiki Boseki Kabushiki Kaisha

Asuka Akihama

Minoru Sugiyama

A molding material mixture contains cellulose nanofibers (CNFs) and at least one base material selected from the group consisting of a resin and fibers. A hydrophobic polymer is chemically bonded to at least some of the &#x2014;OH groups of the cellulose nanofibers. The base material and the cellulose nanofibers are ground or pelletized. A method for producing the molding material mixture includes the following: a pre-irradiation step of applying an aqueous dispersion of CNFs to a base material sheet or immersing a base material sheet in the CNF aqueous dispersion, irradiating the base material sheet with an electron beam, and bringing the base material sheet into contact with an aqueous solution or an aqueous dispersion containing a hydrophobic monomer so that the hydrophobic monomer is graft-polymerized onto the CNFs, or a simultaneous irradiation step of mixing an aqueous dispersion of CNFs with a hydrophobic monomer to form a solution, applying the mixed solution to a base material sheet or immersing a base material sheet in the mixed solution, and irradiating the base material sheet with an electron beam so that the hydrophobic monomer is graft-polymerized onto the CNFs; a drying step; and a grinding or pelletizing step. The present invention provides a molding material mixture that contains cellulose nanofibers and at least one base material selected from the group consisting of a resin and fibers, and that can be handled as a ground product or pellets, and also provides a method for producing the molding material mixture.

Molding material mixture and method for producing the same

A flame retardant resin composition includes a thermoplastic resin, flame retardant reinforced fibers, and a flame retardant. The flame retardant reinforced fibers include cellulosic fibers, a phosphorus compound that is grafted to the surface of the cellulosic fibers, and a polyamine compound that is bound to the phosphorus compound. The flame retardant is a phosphorus-based flame retardant. A method for producing the flame retardant resin composition includes the following: grafting a vinyl phosphate compound to cellulosic fibers by bringing the vinyl phosphate compound into contact with the cellulosic fibers after the cellulosic fibers have been irradiated with an electron beam, optionally followed by electron beam irradiation; binding a polyamine compound to the vinyl phosphate compound, which is grafted to the cellulosic fibers, to form flame retardant reinforced fibers; grinding the flame retardant reinforced fibers; and melt-kneading and pelletizing a thermoplastic resin, the flame retardant reinforced fibers, and a component containing a phosphorus-based flame retardant. This can provide a non-halogen flame retardant resin composition with sufficient flame resistance.

Growing community of inventors

Aichi, Japan

Asuka Akihama