Kemira Oyj

Basf Se Corporation

Basf Se Ludwigshafen

Raisio Chemicals Oy

Ciba Specialty Chemicals Holding, Inc.

Chemigate Oy

Asko Karppi

Matti Hietaniemi

Kimmo Strengell

Jaakko Ekman

Rosa Carceller

Marko Kolari

Vladimir A Grigoriev

Mikko Virtanen

Kari Vanhatalo

Veli-Matti Vuorenpalo

Joonas Likander

Kari Parviainen

Olli Dahl

Leif Robertsen

Vladimir Grigoriev

Michael Lennartz

Anneli Lepo

Jukka Rautiainen

Perttu Heiska

Marco Polverari

Sacha Legrand

Esko Tirronen

Jonas Konn

Charles Hunger

Jan-Luiken Hemmes

Lenita Lindberg

Holger Reinicke

Antti Likitalo

Hannu Ketola

Sauli Laakso

Jyri Välimäki

Mika Suvanto

Timo Valkealaakso

Bengt-Erik Knubb

Simo-Pekka Vanninen

Maarit Latvanen

Elsa Olmos

Tuija Andersson

Leif Robertsén

Erkki Iikka Sakari Rasanen

Martina Halinen

Salla Timperi

Jyri Valimaki

Erkki Iikka Rasanen

Erkki Iikka Sakari RÄSÄNEN

Disclosed is method for on-site glyoxylation of polyacrylamide in a paper or board mill, where a discontinuous batch glyoxylation reaction of aqueous reaction mixture is performed in reactor vessel having driven agitator to form aqueous polymer composition comprising glyoxylated polyacrylamide. The method comprises forming or obtaining the aqueous reaction mixture comprising polyacrylamide base polymer and glyoxal, determining alkali consumption of the mixture, and adding to the mixture, based on determined alkali consumption, pre-determined amount of alkali for adjusting pH to 8-10. The temperature is optionally adjusted to 15-40° C. and the on-site glyoxylation reaction of polyacrylamide base polymer is allowed to proceed. Viscosity of the mixture and/or a variable related to the viscosity is measured, acid is added to the mixture for lowering pH to <8, when a predetermined end viscosity value is attained, and the aqueous polymer composition comprising glyoxylated polyacrylamide is removed from the reaction vessel.

Method for on-site glyoxylation of polyacrylamide

The invention relates to a composition and method for manufacture of paper, board, tissue or the like. The composition comprises an amphoteric polymer component, which has a weight average molecular weight of at least 600 000 g/mol, preferably at least 1 000 000 g/mol, more preferably at least 2 000 000 g/mol, and at least one synthetic cationic polymer component, which is a copolymer of a polyamidoamine and has a weight average molecular weight ≤550 000 g/mol, preferably ≤500 000 g/mol, more preferably ≤400 000 g/mol and dispersity index more than 15, preferably more than 20, more preferably more than 25.

Composition and method for manufacture of paper, board or the like

The invention relates to a composition for use in a manufacture of paper, board or the like. The composition comprises a mixture of cationic starch having amylopectin content of at least 85%, and an amphoteric polymeric structure comprising structural units originating from non-ionic monomers, preferably (meth)acrylamide, anionic groups and cationic groups, the polymeric structure comprising cationic groups at least 0.2 mol-%.

Composition and its use for use in manufacture of paper, board or the like

The present invention relates to a method and an arrangement for dissolving starch. Specifically, the present invention relates to a method for dissolving starch by introducing mechanical force to at least partially gelatinized aqueous starch.

Method for dissolving starch

A method for manufacturing a multi-layered fibrous web is disclosed, which includes at least two fibrous layers, where each layer is formed from one or more fibre stocks. The fibrous layers are combined prior to subjecting the multilayered fibrous web to wet-pressing and drying. At least one layer of the multi-layered fibrous web is formed from a fibre stock including at least 50 weight-% of a chemi-thermomechanical pulp (CTMP), a hardwood kraft pulp and/or a recycled fibre material calculated from a thick stock applied to a particular layer approach system. A first strength component and a second strength component are added to the fibre stock. The first strength component includes a cationic strength agent and the second strength component includes a synthetic amphoteric polymer composition having a net charge from &#x2212;3 to +1 meq/g (dry), at a pH of 7.

Method for manufacturing multi-layered fibrous web and multi-layered fibrous web

A method for producing an aqueous copolymer solution, which comprises dissolving a copolymer of (meth)acrylamide and at least 1 mol-% cationic monomers, calculated from total amount of monomers in the dissolving water having calcium hardness of at least mg/l, expressed as Ca, and adding acid comprising monoprotic organic acid and/or mineral acid to the dissolving water and/or the aqueous solution of the copolymer in an amount sufficient to provide the aqueous solution of the copolymer with a pH of equal to or less than 4.5. The invention also relates to uses of the obtained polymer solutions in manufacturing of paper, board or the like or in treatment of sludge or water.

Method for producing polymer solutions

The invention relates to a water-soluble polymer composition obtained by polymerizing in an aqueous polymerisation medium, which comprises degraded starch, at least following monomers: acrylamide and/or methacrylamide, and &#x3e;2 mol-% of at least one unsaturated mono- or dicarboxylic acid(s) or salts thereof. The polymer composition has an anionic net charge at pH 7 and a dry solids content of &#x3e;5 weight-%. The invention relates also to the use of the polymer composition for surface sizing of paper, board or the like as well as to a surface size composition comprising it.

Polymer composition, its use and a surface size

The invention relates to a use of a water-soluble polymer product comprising amphoteric polyacrylamide, which has neutral or cationic net charge at pH 7, a weight-average molecular weight of 2,500,000-18,000,000 g/mol and a total ionicity of 4-28 mol-%. The polymer product is used for controlling deposit formation caused by hydrophobic substances in manufacture of paper or board, where a fibre web is formed from an aqueous suspension of fibres. The invention relates also to a method for controlling deposit formation caused by hydrophobic substances in manufacture of paper or board, where a fibre web is formed from an aqueous suspension of fibres, as well as to produced paper or board.

Use of a polymer product for deposit formation control in manufacture of paper or board

A dry strength composition for manufacture of paper, board or the like is disclosed. The dry strength composition includes, as a mixture, at least one anionically derivatized polysaccharide, and cationic starch having an amylopectin content &#x2265;80 weight-%. The anionically derivatized polysaccharide and the cationic starch provide the composition with a charge density in a range of 0.1-1.5 meq/g, when measured at pH 2.8, and &#x2212;0.1-&#x2212;3 meq/g, preferably &#x2212;0.3-&#x2212;2.5 meq/g, more preferably &#x2212;0.5-&#x2212;2.0 meq/g, when measured as an aqueous solution, at pH 7.0. Further disclosed are a use of the composition and a method for manufacturing paper, board or the like.

Dry strength composition, its use and method for making of paper, board or the like

A method for manufacturing paper or board is disclosed and further disclosed is an internal sizing system for providing improved retention of hydrophobic internal sizing agents. The internal sizing system includes a hydrophobic internal sizing agent as a first component selected from a group consisting of alkenyl succinic anhydride (ASA), alkyl ketene dimer (AKD), rosin sizes and any combination thereof, and a water-soluble polymer product including amphoteric polyacrylamide as a second component, which amphoteric polyacrylamide has neutral or cationic net charge at pH 7, a weight-average molecular weight of 700,000-18,000,000 g/mol and a total ionicity of 4-28 mol-%, where the first component and the second component are provided as separate components or as a combination of the first component and the second component.

Polymer product for improving retention of hydrophobic internal sizing agents in manufacture of paper or board

A cationic glyoxylated polyacrylamide polymer composition having improved storage stability for use in manufacture of paper, board or the like, which aqueous composition includes a glyoxylated polyacrylamide polymer having a cationic charge density in a range of 0.8-1.8 meq/g of dry polymer in dry content of 5-15% and a buffering acid. The aqueous composition has pH in a range of 2.2-4.0 and a viscosity of less than 80 mPas measured at 25&#xb0; C. by using a Brookfield viscometer after 30 days storage at 35&#xb0; C. or after 60 days storage at 23&#xb0; C.

Glyoxylated polyacrylamide polymer composition, its use and method for increasing the strength properties of paper, board or the like

A method is disclosed for dewatering of sludge from a pulp, paper or board making process, such as deinking sludge, including obtaining of an aqueous sludge including an aqueous phase and a fibre material suspended in the aqueous phase. The sludge is subjected to a pre-thickening step, where a first part of the aqueous phase is removed from the sludge and to a pressing step, where a second part of the aqueous phase is removed from the sludge, thereby obtaining a dry pressed sludge. Before or at the pre-thickening step a polymer composition having a charge density of at the most 1.7 meq/g, preferably at most 1.5 meq/g, more preferably at most 1.1 meq/g, is added to the sludge.

Method for dewatering of sludge from a pulp, paper or board making process

A polymer composition includes a first host polymer, which is a copolymer of (meth)acrylamide and at least one cationic first monomer, and a second polymer, which is a copolymer of (meth)acrylamide and at least one cationic second monomer. The second polymer is polymerised in presence of the first host polymer, and the first host polymer has a higher cationicity than the second polymer, the difference in cationicity of the first host polymer and the second polymer being at least 3 mol-%, at least 5 mol-%, more preferably at least 7 mol-%. The polymer composition has a standard viscosity of &#x3e;2.0 mPas, measured at 0.1 weight-% solids content in an aqueous NaCl solution (1 M), at 25&#xb0; C., using Brookfield VII T viscometer with UL adapter. The invention relates also to uses of said polymer composition.

Polymer composition and its uses

A method for manufacture of paper, board or the like, comprising the step of dissolving a composition into aqueous solution, whereby an aqueous treatment solution is obtained for adding the obtained treatment solution to the pulp. The composition comprising a copolymer of acrylamide and at least one cationic monomer, the copolymer comprising cationic monomers at least 15 mol-%, calculated from total amount of monomers, and an ionic crosslinker agent comprising at least two carboxyl groups, wherein the equivalent ratio of carboxyl groups:cationic monomer is between 1:20 and 1:0.5.

Method for manufacture of paper, board or the like and use of the composition

The invention relates to an aqueous dry strength composition suitable for use in manufacture of paper, board or the like. The composition includes a mixture of a synthetic polymer component, which is a copolymer of acrylamide and at least one anionic monomer, and a cationic starch component. The polymer component has an anionicity of 1-60 mol-%. The synthetic polymer component and cationic starch component provide the composition with a charge density in the range of 0.05-1 meq/g, when measured at pH 2.8, and 0.2-&#x2212;3 meq/g, when measured at pH 7.0. The invention also relates to a method for making of paper, board or the like, where the dry strength composition is diluted with water, and the solution of the dry strength composition is added to the fibre stock before or after the addition of a cationic strength agent.

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Turku, Finland

Asko Karppi