Kuraray Co., Ltd.

Asako Minamide

Hiromichi Nakata

Yosuke Jogo

Yasuhiro Shirotani

Mikio Masuda

Masahiro Suzuki

Shigenao Kuwahara

Masanori Tomoi

The present invention is a thermoplastic polymer composition which contains 10-120 parts by mass of a polar group-containing polypropylene resin (B) per 100 parts by mass of a thermoplastic elastomer (A) that is a block copolymer having a polymer block containing an aromatic vinyl compound unit and a polymer block composed of a conjugated diene unit having 40% by mole or more of 1,2-bonds and 3,4-bonds in total, or a hydrogenated product of the block copolymer (provided that a thermoplastic polymer composition containing 1 part by mass or more of a polyvinyl acetal resin is excluded). This thermoplastic polymer composition is able to be bonded with a ceramic, a metal or a synthetic resin without requiring a primer treatment, and has excellent flexibility, mechanical characteristics, moldability, heat resistance and storage stability.

Thermoplastic polymer composition and molded article

A thermoplastic polymer composition which is excellent in flexibility, mechanical properties, moldability, and particularly in heat resistance and is capable of adhering to ceramics, metals, and synthetic resins even at low temperature (for example, 190&#xb0; C. or lower) without the treatment with a primer, and a molded product produced by using the thermoplastic polymer composition are described. The thermoplastic polymer composition includes 100 parts by mass of a thermoplastic elastomer (A), 1 to 100 parts by mass of a polyvinyl acetal resin (B), and 5 to 100 parts by mass of a polar group-containing polypropylene resin (C). The thermoplastic elastomer (A) is a block copolymer which is constituted by a polymer block including aromatic vinyl compound units and a polymer block including isoprene units, butadiene units, or isoprene/butadiene units wherein the total of a content of 1,2-bonding and a content of 3,4-bonding is 40 mol % or more, or the thermoplastic elastomer (A) is a hydrogenated product of the block copolymer.

A thermoplastic polymer composition which is excellent in flexibility, mechanical properties, and moldability and is capable of adhering to ceramics, metals, and synthetic resins even by heat treatment at a low temperature (for example, 190&#xb0; C. or lower) without the treatment with a primer, and a molded product obtained by using the thermoplastic polymer composition. The thermoplastic polymer composition includes 100 parts by mass of a thermoplastic elastomer (A), 1 to 100 parts by mass of a polyvinyl acetal resin (B), 5 to 100 parts by mass of a polar group-containing olefin-based copolymer (C), and 0.1 to 300 parts by mass of a softener (D). The thermoplastic elastomer (A) is a block copolymer which has a polymer block constituted by aromatic vinyl compound units and a polymer block constituted by conjugated diene units or a hydrogenated product of the block copolymer.

The invention provides a thermoplastic polymer composition containing a hydrogenated block copolymer mixture (a), a polyvinyl acetal (b), and a thermoplastic elastomer (c), wherein the hydrogenated block copolymer mixture (a) contains a hydrogenated block copolymer (a1) containing hydrogenated polymer blocks (A1) containing aromatic vinyl units and hydrogenated polymer blocks (B1) containing conjugated diene units and a hydrogenated block copolymer (a2) containing hydrogenated polymer blocks (A2) containing aromatic vinyl units and hydrogenated polymer blocks (B2) containing conjugated diene units; (A1) content is 5 mass % or higher and lower than 40 mass % in (a1); (A2) content is 40 mass % to 70 mass % in (a2); the polyvinyl acetal (b) has been produced through acetalization of a polyvinyl alcohol; and the thermoplastic elastomer (c) contains hydrogenated polymer blocks (A3) containing aromatic vinyl units, hydrogenated polymer blocks (B3) containing conjugated diene units, and polymer blocks having a polar functional group (C).

Growing community of inventors

Ibaraki, Japan

Asako Minamide