Exxon Chemical Patents, Inc.

Infineum International Limited

Arunas T Lapinas

Ricardo A Bloch

Malcolm Waddoups

David J Martella

John V Redpath

Albert Rossi

William M Davis

Andrew James Ritchie

Edward Francis Outten

James M Gardiner

Steven W McKeown

Ariel Alvarino

Process for the copolymerization of free radical polymerizable comonomers such as vinyl acetate with an unsaturated diester such as diakyl fumarate which is carried out in the presence of water to produce copolymers such as fumarate vinyl acetate copolymers useful as lubricating oil and fuel oil additives, for example, as wax crystal modifiers and flow improvers.

Process for producing free radical polymerized copolymers

A lubricating oil having an ashless nitrogenous TBN source together with ash containing detergent having a TBN in excess of 100, a source of magnesium, and metal dihydrocarbyl dithiophosphate with predominantly or exclusively secondary hydrocarbyl groups is described. It comprises a major amount of an oil of lubricating viscosity having a sulfated ash content between 0.35 and 2 mass percent and A) a nitrogenous TBN source selected from the group consisting of ashless nitrogen containing dispersants, ashless nitrogen containing dispersant viscosity modifiers, oil soluble aliphatic, oxyalkyl, or arylalkyl amines and mixtures thereof; B) a metal salt of an oil soluble acid having a TBN in excess of 100; C) at least 500 ppm (mass) magnesium; and D) at least one metal dihydrocarbyl dithiophosphate. The nitrogenous TBN source provides at least about 1.5 TBN to the finished lubricant. The metal salt of an oil soluble acid provides at least about 40% of the total TBN of the composition. At least 50 mole per cent of the hydrocarbyl groups on the dithiophosphate are secondary. Overbased magnesium sulfonate may be used as the metal salt of an oil soluble sulfonic acid having a TBN in excess of 100 and the additive providing at least 500 ppm (mass) magnesium. The lubricant may be free of aromatic amines having at least two aromatic groups attached directly to the nitrogen. It may have at least 100 ppm (mass) boron and at least 1000 ppm (mass) phosphorous. The boron-to-nitrogen ratio is at least 0.1.

Crankcase lubricant for modern heavy duty diesel and gasoline fueled

A lubricant which comprises: a mineral oil basestock which has been dewaxed via catalytic cracking and/or catalytic isomerization; an alkylene-alkylene copolymer; and a lubricating oil flow improver formed from the reaction product of: (a) an unsaturated carboxy ester formed via the esterification of an unsaturated carboxylic acid or its corresponding anhydride with a monohydric aliphatic alcohol having an average carbon number of between about 10 to 18, the unsaturated carboxy ester having the formula: ##STR1## wherein R' is selected from the group consisting of hydrogen and COOR and wherein R is a C.sub.6 to C.sub.22 alkyl group; and (b) a monomer selected from the group consisting of

Lubricant with a higher molecular weight copolymer lube oil flow improver

A method for testing a sample for soot-related viscosity increase comprising: (a) preparing the sample which comprises a major amount of an oil of lubricating viscosity, (b) measuring the viscosity of the sample (c) preparing a stable sample/paste dispersion of the sample and a carbon black paste, (d) equilibrating the sample/paste dispersion, and (e) measuring the viscosity of the sample/paste dispersion, and a method for predicting physical effects of soot-loading on a sample in a test which measures viscosity increase comprising: (1) measuring viscosity increase for a series of reference fluids in the test, (2) measuring viscosity increase for the series of reference fluids in a method having steps (a) to (e), (3) developing a curve, (4) evaluating the sample using the method having steps (a) to (e), and (5) interpolating a viscometric effect for the sample using the curve.

Method for testing soot-related viscosity increase

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Pittstown, NJ, United States of America

Arunas T Lapinas