USA As Represented by Secretary of the Navy

Arthur A Morrish

Paul M Natishan

John W Glesener

Brian Rhys Stoner

Pehr E Pehrsson

Patrick L Hagans

Benji Maruyama

William E O'Grady

William A Carrington

An electrode for electrochemical uses is made of a conductive metal mesh coated with boron-doped diamond. The electrode may be used in electrochemical reactions either as a cathode or as an anode, or can be used with an alternating current.

Fabrication of a high surface area boron-doped diamond coated metal mesh for electrochemical applications

In a system containing an electron field emitter array characterized by aying diamond powder to a substrate and affixing the powder thereto, the diamond powder being composed of particles having sharp tips which are adapted to emit electrons in a vacuum and in an electric field, which electrons impact a phosphor layer disposed on an anode spaced above the tips of the diamond powder particles.

Electron field emission

Filamentous substrates are coated with diamond by a chemical vapor deposin process. The substrate may then be etched away to form a diamond filament. In a preferred embodiment, the substrate is copper-coated graphite. The copper initially passivates the graphite, permitting diamond nucleation thereon. As deposition continues, the copper-coated graphite is etched away by the active hydrogen used in the deposition process. As a result a substrateless diamond tubule is formed. Diamond-coated and diamond filaments are useful as reinforcement materials for composites, as filtration media in chemical and purification processes, in biomedical applications as probes and medicinal dispensers, and in such esoteric areas as chaff media for jamming RF frequencies.

Self-supporting diamond filaments

The deposition of diamond on a substrate is enhanced by coating the subste surface with a thin layer of carbon before deposition. Preferably, the substrate is scratched before being coated with diamond. The carbon layer may be formed by applying an oil coating to the substrate and then heating the substrate to carbonize the coating, or by the evaporative deposition of carbon.

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LaPlata, MD, United States of America

Arthur A Morrish