Bruker Analytische Messtechnik Gmbh

Bruker Optik Gmbh

Bruker Analytik Gmbh

Bruker Analytisch Mebtechnik Gmbh

Bruker Analtik Gmbh

Arno Simon

Jurgen Gast

Norbert Rapp

Reiner Schubel

Axel Keens

Wilfried Hartmann

Matthias Boese

Gunter Zachmann

Werner Jaross

Eckhard Reh

Jean-Francois Blavier

Jean-Michel Weil

The present invention relates to an FTIR spectrometer comprising a single-element detector to analyze a detector light beam emitted by a sample, with a unit to digitize the voltage available at the detector output and with a unit to process the digitized voltage. The single-element detector and the dedicated unit to digitize the detector voltage are located immediately adjacent to each other.

Digital FTIR spectrometer

A method for taking a spatially resolved spectrum, in particular an infrared (IR) spectrum, of a sample by means of a Fourier-transform (FT)-spectrometer, is described wherein light emitted by a light source is fed to an interferometer, directed onto the sample and detected by an array-detector, wherein a movable reflector of the interferometer is displaced over a distance s and the array-detector is read out at a number n of predetermined discrete way points s, . . . , sof the distance s, respectively. When the movable reflector is displaced over the distance s, the array-detector is first read out at respective non-adjacent way points sseparated by at least one respective intermediate way point s, and that the movable reflector is displaced over the distance s at least twice, wherein the array-detector is read out at the way points supon a second or further repeated displacement over the distance s.

Method for taking a spatially resolved spectrum by means of a fourier-transform (FT)-spectrometer and such spectrometer

A device for the optical spectroscopic examination of interior surfaces ( &prime;) of a body, e.g. of blood vessels ( ), comprising an optical spectrometer and an endoscope ( ) with a light guide for illuminating the surfaces, wherein at the proximal end of the light guide it is supplied with light and at the distal of the light guide the light can be launched to the surfaces to be examined, wherein at the distal end of this endoscope there is provided a device for receiving the light reflected by the surfaces to be examined, is characterized in that the distal end of the light guide is arranged within an inflatable balloon ( ) with an elastic exterior, and that the light decoupled from the light guide and the light reflected by the surfaces to be examined to the receiving device penetrates in each case the exterior of the balloon. In this way, the light launched by the light guide and also the light directed to the surface to be examined and the light scattered by them, if e.g. interior walls of the vessels in the human body are to be examined, does not pass twice a layer of blood or body fluid, and the distal end of the endoscope is fixed such that during measurements, shaking and change of relative distances can be largely avoided, whereby the quality at the received optical spectra is considerably improved.

IR spectroscopic endoscope with inflatable balloon

The invention concerns a method and a device for process control of reaction processes using Fourier transform infrared spectroscopy. In accordance with the invention, an interferogram is generated before or after interaction with the compositions. Subsequent thereto, the interferogram is inspected in segments for externally introduced intensity fluctuations. The intensity fluctuations are subjected to an analysis procedure involving integration, differentiation, or the like, and on the basis of this evaluation, a decision is made as to whether or not the interferogram has an acceptable degree of interfering signals. The interferogram is labeled with this evaluation result and the procedure is repeated a plurality of times. After a sufficient number of acceptable interferograms have been collected, the acceptable interferograms are summed and subjected to a Fourier transform process to extract the frequency dependence. In this manner, Fourier transformation infrared spectroscopy techniques can be applied for process control of processes which would otherwise be impossible due to unacceptably large degrees of interference caused primarily by bubble formation.

Method and apparatus for process control using fourier transform infrared spectroscopy

A device for infrared (IR) spectroscopic investigation of internal surfaces of a body, for example of blood vessels, comprising an endoscope (10) with light guide means to illuminate the surfaces is characterized in that at the distal end of the light guide means there is arranged a detector (12) for detecting IR light scattered from the illuminated surface and transforming it into electric signals. For otherwise identical conditions, compared to comparable known devices, the device according to the invention offers a higher signal strength and thereby the possibility to shorten the measuring time for equal signal quality.

Device for infrared (IR) spectroscopic investigations of internal

The invention relates to a grazing angle microscope for spectroscopic applications. A novel light path having two shifting planar mirrors permits spectroscopic investigation of a sample area off the optical microscope axis at grazing angles as well as visual viewing at steeper angles of incidence of the light.

Grazing angle microscope

An optical spectrometer (1) with an interferometer having a means for varying the optical path difference comprising a drive (8), and with a detector (6) for recording optical signals from the interferometer and converting them into electrical analog signals, wherein an analog-to-digital converter (ADC) (9) is connected to the detector (6) digitizing the electrical analog signals in a time-equidistant manner, is characterized in that the data acquisition electronics (17) are supplied by a switched power supply (14), the clock of which is derived from the same reference oscillator (16) as the clock of the signal digitization by the ADC (9). In contrast to known spectrometers with spatially equidistant sampling of the detector signal, the design of the spectrometer according to the invention is considerably cheaper and more compact with respect to its voltage supply elements. Galvanic separation of the data acquisition electronics and the electronic control unit of the linear drive is no longer required.

Optical spectrometer and method of implementing optical spectroscopy

In a self-supporting beam-splitter (1), in particular for use in an FTIR-spectrometer for the far-infrared region, with an optical thickness on the order of the interesting wavelength region, the foil beam-splitter (1) consists of an undoped semi-conducter material or carbon which is transparent in the far-infrared, and is preferentially made from thin silicon sheets or diamond foil in the thickness region between 2 .mu.m and 125 .mu.m. In this fashion, an extremely high efficiency for the beam-splitter is achieved, whereby little or no resonant absorption takes place due to the beam-splitter in the interesting wavelength region.

Semiconductor foil beam-splitter for an infrared spectrometer

In an analytic spectrometer (50) having a central computer (9), permanently installed and exchangeable components (5), such as a radiation source, a detector, a beam splitter, a filter, external measurement probes and the like, each of which exhibiting a readable data carrier (7) with encoded data of parameters characterizing the respective component (5), the data media (7) can be written to and contains changeable time dependent data concerning the history and/or the actual properties of the corresponding component (5) for example length of operation, performance deterioration parameters or calibration curves of the component (5). These data can be continuously adjusted by the central computer (9) to the current state of the component (5) so that the data medium (7) connected to the component (5) can immediately supply information concerning the current actual properties of the component (5) when installing the component (5) in another spectrometer.

Spectrometer with dynamically coded components

A method for routine identification of materials of plastic components with the assistance of infrared spectroscopy with which an infrared reflection spectrum is taken from the surface of a plastic component to be investigated and compared to a set of reference spectra, whereby the material of the plastic component under investigation is correlated to a class of plastic materials represented by one of the reference spectrum, is characterized in that the plastic component under investigation is positioned with the assistance of a video device (25, 26) and in that the infrared reflection spectrum is recorded in the range of the mid-infrared (MIR) in a wave length region between 400 and 4,000 cm.sup.-1. In this fashion even plastics which, for example, are filled with carbon can be routinely identified. It is preferred when the first derivative of the recorded IR spectrum with respect to wave number is taken and compared to the first derivative of the IR spectra of the reference spectra.

Method for the routine identification of plastics

The invention concerns an optical or infrared Fourier spectrometer with a plurality of entrances and exits for the coupling on of external sources or samples. The entrances can also be used as exits and vice versa.

Fourier spectrometer with exchangeable entrance and exit ports allowing

In a Raman microscope, in particular for a Fourier transform (FT) spectrometer with a lens for magnified imaging of a point-shaped region (1) on a surface of a measuring sample (2) and with a laser for irradiating laser radiation onto the point-shaped region (1), the laser radiation is in the infrared (IR), preferentially in the near-infrared (NIR) region and the lens is a Cassegrain mirror-lens (3, 4) with a convex mirror (3) arranged rotationally symmetrically to an optical axis (5) and with a concave mirror (4) which is likewise rotationally symmetric to the optical axis (5) of the lens, whereby the focal point of the concave mirror (4), lying on the optical axis (5), coincides with the point-shaped region (1) on the surface of the measuring sample (2). In this fashion distortion-free NIR Raman spectra can be taken with simple optical elements.

Lens for a FT-raman microscope

An apparatus and a method for the exchange of an optical component 20 is proposed in which a storage housing 1 exhibits a lower opening with a first gate means 21 adapted for sealing the lower opening. A second stopping means 6 attached to a driving means 5 and a first stop attached to the storage housing 1 are adapted to assume two states, a first state in which a optical component 20 is completely within the storage housing 1, and a second state in which an optical component 20 is completely removed from the storage housing 1. A pivoted mounting 4 of a lifting means 2 onto the driving means 5 in combination with a rotation of said driving means 5 allows for the force of gravity to guide the removal and introduction of the optical component 20 out of and into a spectrometer housing 24.

Optical component exchanger and method

An optical or Fourier infrared Fourier spectrometer with a two-beam interferometer with which the mirror drive is effected via two retroreflectors which are located on two 180.degree. displaced arms of a double pendulum. Deflecting mirrors are arranged between the beam splitter and the retroreflectors. The otherwise usual retroreflecting mirrors are not present. The beam splitter is displaced with respect to the plane of the pendulum. Thereby, a stable, easily aligned, and compact configuration is effected.

Fourier spectrometer

An infrared Fourier transformation spectrometer comprising a non-linear analog-to-digital converter device having at least one amplifier and one sample and hold circuit connected downstream thereof, as well as an an analog-to-digital converter following the latter, wherein an input signal to be converted is to be supplied to one input of the amplifier and the gain of the input signal is a function of the magnitude fo the input signal, and wherein the output signal of the analog-to-digital converter is evaluated giving regard to the respective gain, is characterized by the fact that at least two analog-to-digital converters are provided whose outputs are connected to a first controllable switching arrangement for supplying selectively the output signals of one of the said analog-to-digital converters to another evaulation means and that the input signal is supplied to each of the said analog-to-digital converters amplified by a different amplification factor. This allows to achieve high resolution by simple means.

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Karlsruhe, Germany

Arno Simon