Borealis Technology Oy

Borealis A/s

Evonik Degussa Gmbh

Borealis Ag

Evonik Oxeno Gmbh

Norner as

Arild Follestad

Ivar Martin Dahl

Richard Blom

Siw Bodil Fredriksen

Hannu Salminen

Vidar Almquist

Klaus Joachim Jens

Klaus-Joachim Jens

Michael Grass

Kauno Alastalo

Erling Rytter

Bo Malm

Espen Ommundsen

Markku Vahteri

Bill Gustafsson

Jarmo Lindroos

Harri Hokkanen

Ulf Palmqvist

Stefan Buchholz

Tore Dreng

Petri Rekonen

Mika Harkonen

Merete Skar

Katrin Nord-Varhaug

Ted M Pettijohn

Merja Poikela

Jari Hatonen

Svein Staal Eggen

Erik Eriksson

Gerhard Ellermann

Arild Geir Andersen

Karl Isak Skau

Vidar Almqvist

Ketil Strand Andersen

Jari Hätönen

Knut Fosse

Morten Lundquist

Arno Johansen

Hans Georg Daviksnes

Ted Pettijohn

Anne Brit Bjaland

Jari Hätonen

Hans Jorg Fell

Bala Kona

A film containing an interpolymer of ethylene and a 3-substituted Calkene is prepared using a catalyst system comprising a Ziegler Natta or chromium oxide catalyst.

Polyethylene/3-substituted alkene film made with Ziegler-Natta or chromium oxide catalyst

The present inventions relates to a process for producing polyethylene compositions comprising polymerizing polyethylene resins in a cascaded multi-stage reaction in which the reaction steps are performed in at least two slurry phase reactors (A) and (B) and at least one gas phase reactor (C) which are arranged in series in any order wherein in reactor (A) a low molecular weight ethylene homo- or copolymer fraction having a MFRof 100 to 2000 g/10 min, in reactor (B) a low molecular weight ethylene homo- or copolymer fraction having an MFRof 100 to 2000 g/10 min, and in reactor (C) a high molecular weight ethylene copolymer fraction are polymerized, and further comprising a compounding step after polymerization, wherein the final polyethylene composition has a MFRof 3 to 50 g/10 min, the melt flow rates being determined according to ISO 1133.

Multi-stage process for producing polyethylene with lowered gel formation

A polymer composition suitable for rotomoulding comprising I) An ethylene homopolymer or copolymer with at least one other C3-10 ? olefin, having a melt flow rate of 0.5 to 30, a molecular weight distribution (Mw/Mn) of less than 4, an Mw of 50,000 to 110,000, a density of 0.940 g/cm3 to 0.970 g/cm3 and a melting point of 100 to 145&#xb0; C.; or I) a propylene homopolymer or copolymer with at least one other C2-10 ? olefin, having a melt flow rate of 0.5 to 30, a molecular weight distribution (Mw/Mn) of less than 4, an Mw of 150,000 to 300,000, and a melting point of 100 to 170&#xb0; C.; and II) an ethylene homo or copolymer with at least one other C3-10 ?-olefin, having a melt flow rate of within 40% of the melt flow rate of component (I), a molecular weight distribution of (Mw/Mn) of less than 4, an Mw of within 30% of the Mw of component (I), a density of 0.880 g/cm3 to 0.940 g/cm3 said density being at least 0.010 g/cm3 less than the density of component (I) and a melting point of at least 5&#xb0; C. less than that of component (I); or II) a propylene homo or copolymer with at least one other C2-10 ?-olefin having a melt flow rate of within 40% of the melt flow rate of component (I), a molecular weight distribution of (Mw/Mn) of less than 4, an Mw of within 30% of the Mw of component (I), and a melting point of at least 10&#xb0; C. less than that of component (I).

Polyolefin composition for rotomolding

The invention relates to a process for the preparation of a multimodal A-olefin polymer comprising polymerizing in a polymerization stage at least one A-olefin in the presence of a multisite catalyst and an adjuvant so as to produce a polymer having a relatively lower molecular weight component and a relatively higher molecular weight component, said adjuvant being selected from the group consisting of phosphines, phosphites, acetylenes, dienes, thiophenes and aluminium alkyls and said adjuvant being capable of altering the ratio of the fraction of higher molecular weight component to the fraction of the lower molecular weight component by at least 10%.

Olefin polymerization process

The invention provides a supported chromium catalyst system comprising a chromium catalyst precursor bound via at least one heteroatom to a functionalised support, said heteroatom being connected to said support via an organic group.

Supported catalyst

The invention relates to a process for the preparation of an olefin polymer comprising at least two polymerization stage in the presence of an olefin polymerization catalyst material, an olefin polymer produced by such process, and the use of such polymers for the production of fibres, pipes, films, moulded products and products for wire and cable applications.

A supported titanium catalyst system comprising a titanium catalyst bound via at least one heteroatom, a functionalized support, said heteroatom being connected to said support via an organic group.

Supported titanium catalyst system

A catalyst system for the polymerization of ethylene, comprising a particulate inorganic oxide supporting a chromium oxide being in a reduced oxidation state and a metallocene compound having the formula Cp ZrR&prime;R&Prime;, wherein each Cp, being equal or different, is an unsubstituted or substituted cyclopentadienyl compound, and R&prime; and R&prime;, independent of each other, are selected from the group comprising alkyls having 1 to 6 carbon atoms, unsubstituted or substituted benzyl, and phenoxy substituted with alkyls having 1 to 6 carbon atoms; or R&prime; or R&Prime; may be a halide. The catalyst system is prepared by a method comprising the steps of calcining the support, joining onto the surface of the support a chronium-organic compound, subjecting the obtained catalyst precursor to oxidizing conditions to obtain the chromium in an oxidized state, reducing the oxidized chromium to obtain a main part thereof in a bivalent oxidation state, and contacting the reduced catalyst with the metallocene compound.

Catalyst system for ethylene polymerizations

A particulate, modified chromium oxide catalyst for the polymerisation of ethylene or ethylene with &agr;-olefins, comprising: a) a chromium-oxide catalyst, b) a transition metal compound, and c) a catalyst activator. A method for the preparation of the catalyst comprises the steps of: a) subjecting a chromium oxide catalyst precursor, which comprises a chromium oxide compound combined with an inorganic support, to a temperature in the range of from 400 to 950&deg; C. under oxidising conditions, and b) impregnating the obtained chromium catalyst with a catalyst activator and with a transition metal compound which comprises at least one cyclopentadienylic ring bonded to said transition metal and at least ligand selected from the group comprising alkoxy, amido and hydrocarbyl radicals, halogen and hybride bonded to said transition metal, which cyclopentadienylic ring may contain hetero atoms, be unsubstituted or substituted, be bonded to said transition metal through a bridge, and optionally annealed to other substituted or unsubstituted ring structures, and if two cyclopentadienyl rings are present they may be bonded to each other through a bridge, and c) subjecting the thus obtained particulate catalyst to drying conditions. This catalyst is suitable for producing polyethylenes under conditions of continuous feeding of all reactants.

Catalyst for the (co)polymerization of ethylene and a method for the preparation thereof

A process for the production of a propylene based polymer, the process comprising the following steps: (a) a first polymerization stage comprising homopolymerizing propylene or copolymerizing propylene and at least one alpha-olefin in the presence of an alpha-olefin polymerization catalyst whereby to produce a polypropylene component; (b) a second polymerization stage comprising copolymerizing ethylene and at least one alpha-olefin in the presence of an alpha-olefin polymerization catalyst whereby to produce an ethylene/alpha-olefin copolymer component; and (c) blending the polymer components produced in steps (a) and (b) whereby to produce a polymer blend, wherein the first and second polymerization stages are effected in separate polymerization reactors connected in parallel. Also provided are polymer compositions comprising: (i) 30 to 97% by weight, based on the total weight of the polymer composition, of a propylene based polymer; and (ii) 3 to 70% by weight, preferably 5 to 20% by weight, based on the total weight of the polymer composition, of an ethylene copolymer plastomer (e.g., an ethylene-propylene plastomer) containing at least 60% by weight ethylene.

Process for producing propylene based polymer compositions

This invention relates to a process for the preparation of olefin polymers, preferably a multi-stage process, in which hydrogen is used to control the molecular weight of the olefin polymer produced in a continuous reactor, in particular a process wherein a metallocene or other single site catalyst is present in the polymerization reaction mixture, as well as to olefin polymers produced thereby.

A process for olefin polymerization in a reaction vessel, said process comprising polymerizing at least one &agr;-olefin in a polymerization stage employing a catalyst feed comprising 1) a first catalyst composition having at least two active catalytic sites capable of producing a first set of polymer components; 2) a second catalyst composition having at least two active catalytic sites capable of giving essentially the same set of polymer components as produced by the catalyst in feed (1) under the same polymerization conditions but these components in a different ratio to those produced by the catalyst composition of feed (1); wherein the amounts of catalyst compositions (1 and 2) fed into the reaction vessel are independently controlled.

Olefin polymers are prepared in a plurality of polymerization stages, optionally in a plurality of polymerization reactors, in the presence of hydrogen and an olefin polymerization multisite catalyst, preferably a dualsite catalyst, having at least catalytic sites A and B, site A capable of yielding polymers of different molecular weights and differing MFR or MFR depending on the concentration of hydrogen in the polymerization reactor and site B capable of yielding polymers of certain molecular weight and MFR or MFR depending on the concentration of hydrogen in the polymerization reactor where the ratio between MFR or MFR of polymers produced by site B at two different selected hydrogen concentrations is less than ten and the ratio between MFR or MFR of polymers produced by site A at the same hydrogen concentrations is more than 50.

Multistep process for preparing polyolefins having high melt strength

A polyethylene produced by the homopolymerisation of ethylene or copolymerisation of ethylene with &agr;-olefins in the presence of a catalyst, characterized in that the fraction of low molecular weight polymers having MW<5000 g/mole is lower than 12% by weight of the produced polymer, and that the produced polyethylene has a measured melt strength expressed by a haul-off (HO) value satisfying the expression: HO>K &middot;&eegr;0.05&plus;K , wherein K is 9.10 and K is 0.4.

Polyethylenes obtained by use of dual site catalyst

A process for the polymerization of ethylene and optionally &agr;-olefins to form ethylene homopolymer or copolymers having a broad molecular weight distribution, comprising polymerization of 100-80 wt. % of ethylene and 0-20 wt. % of comonomer in the presence of two independent, simultaneously present catalysts A and B, wherein catalyst A, deposited on an inorganic support, comprises chromium in a predominantly oxidant state of 2 and catalyst B comprises a bis-cyclopentadienyl chromium compound reacted with an inorganic support.

Process for producing polyethylenes having a broad molecular weight distribution, and a catalyst system used thereby

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Stathelle, Norway

Arild Follestad