Conopco, Inc.

Arash Mojaher Moghadam

Joseph Muscat

Pierre Starck

Robert George Riley

Robert Machen

An aqueous, sulphate free shampoo composition for hair and scalp comprising:—a. a pre-formed emulsified silicone; b. a cationic deposition polymer; c. a hair substantive cationic conditioning polymer which is an APTAC polymer having a molecular weight of less than 1 million Daltons, preferably selected from a homopolymer of (3-acrylamidopropyl) trimethyl ammonium chloride and a (3-acrylamidopropyl) trimethyl ammonium chloride/acrylamide copolymer; d. a total amount of anionic surfactant, amphoteric surfactant and zwitterionic surfactant consisting of: (i) from 3 wt % to 13 wt %, by weight of the total composition at 100% activity, of an alpha olefin sulfonate anionic surfactant of general formula (I): R—CH═CH—CH—SO(I) in which Ris selected from linear or branched alkyl groups having from 11 to 13 carbon atoms and mixtures thereof; and M is a solubilizing cation; (ii) from 1 to 6%, by weight of an amphoteric or zwitterionic surfactant, selected from an alkyl betaine of general formula (II) R—N(CH)—CH—COOM(II) wherein R=C12 (Lauryl) or Coco derived; an alkyl hydroxy sultaine of general formula (III), R—N(CH)—CH—CH(OH)—CH—SOM(III) wherein R=C12 (Lauryl) or Coco derived; an alkyl aminopropyl hydroxy sultaine of general formula (IV), R—CO—NH—(CH)—N(CH)—CH—CH(OH)—CH—SOM(IV) wherein R=C12 (Lauryl) or Coco derived; an alkyl amphoacetate of general formula (V), R—CO—NH—(CH)—N(CH—CH—OH)(CH—COOM) (V) wherein R=C12 (Lauryl) or Coco derived; and mixtures thereof; and e. a suspending agent in which the weight ratio of (i) to (ii) ranges from 1:1 to 6:1 and the pH of the composition is from 3 to 6.5; and wherein the composition has a viscosity from 3,500 to 15,000 mPa·s, preferably from 4,000 to 12,000 mPa·s when measured using a Brookfield V2 viscometer using a spindle RTV5, for 1 minute at 20 rpm at 30° C. results in superior deposition and retention of silicone on hair.

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Wirral, United Kingdom

Arash Mojaher Moghadam