Clemson University

University of Kentucky Research Foundation

Apparao M Rao

Bevan Craig Elliott

Ramakrishna Podila

Jay Gaillard

Doyl E Dickel

Yongchang Dong

Gayatri D Keskar

Malcolm J Skove

Robert Cort Haddon

Goutam Koley

Francesco Stellacci

Wei Wang

Mark E Roberts

Robert Ryan Vallance

Srikanth Pilla

Saurabh Chopra

Mark Mattson

M Pinar Menguc

Razvan Marian Ciocan

Robert K Emmett

Morteza Sabet

Jay B Gaillard

M Pinar Mengüc

Herbert W Behlow

Pu-Chun Ke

Rahul Rao

Amod A Ogale

Nancy Chen

Jason B Reppert

Sai Sunil Kumar Mallineni

Herbert W Behlow, Jr

Dan D Edie

Nicholas W Gothard

Soaram Kim

Methods for synthesis of high surface area porous silicon-based materials and structures that can be formed according to the methods are described. Methods are scalable and capable of producing large quantities of the high surface area materials with high efficiency. The high surface area products can be in the form of a 3D network of interconnected arms or quills with multimodal porosity including high level pores between and among arms, hollow cores of the arms of the network, and pores through the walls of the arms of the network.

Hollow porous silicon-containing structures and method of formation

Pressure/strain piezoresistive are described that include a poled piezoelectric polymer such as PVDF or P(VDF-TrFE) and graphene. The poled piezoelectric polymer and the graphene are electronically coupled to form a heterojunction and provide an ultra-high sensitivity pressure/strain sensor. The sensors can be carried on a flexible supporting substrate such as PDMS or PET to exhibit high flexibility. The materials of formation can be biocompatible and the sensors can be wearable or implantable.

Graphene/polymer heterostructure-based flexible and biocompatible pressure/strain sensor

Devices and methods relate to a portable self-powered wireless sensor and transmitter providing a tactile driven electric generator, using a 3D printed nano carbon and polymer electrodes. The device has two electrodes capable of producing greater than 2000 V, which when connected to a metal conductor is sufficient to create an electric field that can be used to wirelessly communicate a signal over a range of a few tens of meters. The sensor is completely self-powered and requires no motors or additional power such as active power supplies, batteries, or capacitors. The sensor generated waveform can be modulated by mechanical action such as hand tapping in a given sequence, which is preserved in the wireless signal (akin to Morse coding) and can be detected by existing compatible commercial electronic receivers. Resulting devices are suitable for security applications requiring wireless transmission of codes.

Self powered wireless sensor

Embodiments of the present disclosure, in one aspect, relate to composites including a carbon nanomaterial having a redox-active material, such as a polymer containing redox groups, disposed on the carbon nanomaterial, methods of making the composite, methods of storing energy, and the like.

Polymer-nanocarbon composites, methods of making composites, and energy storage devices including the composite

A method and system is disclosed to detect and analyze an electric signal based on movement between an element and a counter electrode influenced by a nonlinear electric field produced by an electrical signal impressed between the element and counter electrode. Through detection of changes in the distance between the element and the counter electrode characteristics of the element and/or the environment of the element may be ascertained. Changes in the distance between the element and the counter electrode may be monitored based on changes in the value of capacitance between the element and counter electrode. The disclosed devices and methods may be employed to detect, for instance, presence of chemical/biological species in a sample or measure physical parameters of a sample such as pressure/acceleration, density, viscosity, magnetic force, temperature, and/or extremely small masses.

Non-linear electrical actuation and detection

Disclosed are methods and devices for patterning micro- and/or nano-sized pattern elements on a substrate using field emitted electrons from an element. Disclosed methods and devices can also be utilized to form nano- and micron-sized depressions in a substrate according to a more economical process than as has been utilized in the past. Methods include single-step methods by which structures can be simultaneously created and located at desired locations on a substrate. Methods include the application of a bias voltage between a probe tip and a substrate held at a relatively close gap distance. The applied voltage can promote current flow between the probe and the substrate via field emissions. During a voltage pulse, and within predetermined energy levels and tip-to-surface gap distances, three dimensional formations can be developed on the substrate surface.

Substrate patterning by electron emission-induced displacement

The present invention discloses a relatively simple CVD method for forming specifically tailored carbon-based nanostructures. In general, the method is a chemical vapor deposition method in which at least a portion of the precursor materials are provided as a liquid at atmospheric conditions. The precursor materials include at least one carbon source and at least one catalyst source. Optionally, the precursor materials can also include one or more dopant sources. The carbon source and the optional dopant source can be injected as liquids into the system, and the liquid catalyst source can be either injected into the system or located on a substrate in the reactor prior to the process. Very high yield of nanostructures exhibiting particular characteristics can be attained by the process. Control of electrical characteristics as well as structural characteristics of the products are possible via control of process parameters including the particular precursors used as well as the relative amounts of the precursors used.

Process for preparing carbon nanostructures with tailored properties and products utilizing same

A method and system is disclosed that can be used to directly detect and analyze an electric signal electrostatically induced a semi-conductive or conductive element at resonance. Through detection of the changes in the characteristics of the signal from the element, the disclosed devices can detect, for instance, presence of chemical/biological species in a sample or measure physical parameters of a sample such as pressure/acceleration, magnetic force, temperature, and/or extremely small masses. The disclosed systems include one or more micro- or nano-sized elements. Through modulation of an electric charge on a counter-electrode that is located at a pre-determined distance from the element, a modulating charge can be induced upon the element. Resonance can be directly detected via electronic monitoring of the induced signal for the higher harmonics of the natural resonant frequency.

Method and apparatus for detecting resonance in electrostatically driven elements

Disclosed are optical devices including one or more carbon nanotubes that can function as plasmon waveguides. The presently disclosed devices advantageously utilize the existence of surface plasmons on carbon nanotubes through the generation and transport of surface plasmon polaritons across the nanotubes. Also disclosed are methods for tuning the devices through particular formation parameters for the nanotubes and/or selection of particular substrate materials. Systems of the present invention can provide optical data concerning a sample, for instance via construction of an NSOM image, as well as topological date concerning a sample via construction of an AFM image. In one embodiment, the disclosed systems can provide simultaneous acquisition of optical images and topological images.

Surface plasmon induction in multiwalled carbon nanotube arrays

The present invention is generally directed to a novel process for the production of nanowires and nanobelts and the novel nanostructures which can be produced according to the disclosed processes. The process can be carried out at ambient pressure and includes locating a metal in a reaction chamber, heating the chamber to a temperature at which the metal becomes molten, and flowing a vapor-phase reactant through the chamber. The vapor-phase reactant and the molten metal can react through a thermal CVD process, and nanostructures can form on the surface of the molten metal. Dimensions of the nanostructures can be controlled by reaction temperature.

Thermal CVD synthesis of nanostructures

A modified, mesophase pitch-based carbon fiber is disclosed which includes carbon nanotube reinforcements in an amount ranging from about 0.01 percent to about 1.0 percent by weight. Although the reinforcements actually decrease the excellent tensile modulus of the unmodified fiber, they provide a random microstructure, which can decrease brittle failure of the fiber caused by propagation of a flaw.

Mesophase pitch-based carbon fibers with carbon nanotube reinforcements

The present invention discloses a relatively simple CVD method for forming branched carbon nanotubes. In general, the method includes adding a dopant to the precursor materials. The dopant can be a material that has a thermodynamically more favorable carbide-forming reaction at the reactor conditions than does the catalyst that is provided to the reactor by a second precursor material. The doped nanoparticles formed in the reactor can adhere to the walls of the developing nanotubes and provide a nucleation site for the development of one or more branches on the nanotube. The nanotubes formed according to the invention can be recognized as such due to the presence of the doped nanoparticles adhered along the walls of the branched nanotubes.

Synthesis of branched carbon nanotubes

Disclosed are resonant gas sensors and methods for forming and using the disclosed sensors. The sensors include a resonator including a layer comprising adsorptive nanostructures, for example carbon nanotubes, activated carbon fibers, or adsorptive nanowires. The dielectric of the resonator is in electrical communication with the layer comprising adsorptive nanostructures such that the effective resonant frequency of the resonator depends on both the dielectric constant of the dielectric as well as the dielectric constant of the adsorptive layer. In some embodiments, the nanostructures can be degassed. The sensors can detect the presence of polar gases, non-polar gases, organic vapors, and mixtures of materials with both high sensitivity and high selectivity.

Carbon nanotube based resonant-circuit sensor

A cell and substrate system and nerve regeneration implant are disclosed including a carbon nanotube and a neuron growing on the carbon nanotube. Both unfunctionalized carbon nanotubes and carbon nanotubes functionalized with a neuronal growth promoting agent may be utilized in the invention. A method is also disclosed for promoting neuronal growth.

Molecular functionalization of carbon nanotubes and use as substrates for neuronal growth

Novel methods and devices for nanomachining a desired pattern on a surface of a conductive workpiece are disclosed. In one aspect, the method comprises using an electron beam emitted from one or more nanotubes to evaporate nanoscale quantities of material from the workpiece surface. The surface of the workpiece to be machined may be excited to a threshold energy to reduce the amount of power required to be emitted by the nanotube. In another aspect, a device is described for nanomachining a desired pattern on a surface of a conductive workpiece, comprising a vessel capable of sustaining a vacuum, a leveling support, a nanopositioning stage, and a laser for heating the workpiece. A nanotool is provided comprising at least one nanotube supported on an electrically conductive base, adapted to emit an electron beam for evaporating material from an electrically conductive workpiece.

Growing community of inventors

Anderson, SC, United States of America

Apparao M Rao