Enichem Elastomeri S.p.a.

Enoxy Chimica S.p.a.

Enichem S.p.a

Agip Petroli

Montedipe S.r.l.

Antonio Carbonaro

Silvano Gordini

Domenico Ferraro

Salvatore Cucinella

Francesco Masi

Renzo Invernizzi

Lorenzo Costa

Angelo Moalli

Margherita Corbellini

Cesare Ferrero

Mario Bruzzone

Luciano Ripani

Stanislao Spina

A supported catalyst for the polymerization and copolymerization of olefinically unsaturated compounds is described, comprising an organometallic compound of aluminium and a second component obtained by bringing a titanium, vanadium or chromium compound, at least one compound of a second metal chosen from V, Al, Zr, Hf, Mo and Nd and optionally a magnesium compound into contact with a porous support consisting of microbeads of aerogels of one or more inorganic oxides distinguished by low density, high porosity and the fact that at least 90% of the pores have a diameter lying within a very narrow range of values. The process for the polymerization or copolymerization of olefinically unsaturated compounds based on the use of said catalyst is also described.

Supported catalyst for the polymerization and copolymerization of

This invention concerns the production of 1,4-cis polybutadiene, or copolymers of butadiene with other related diolefins, through the catalytic polymerization or copolymerization of butadiene monomer by a continuous or discontinuous process carried out in the absence or substantial absence of solvents or diluents and operating in the presence of solid bodies.

Process for the polymerization or copolymerization of butadiene in the

This invention concerns the production of 1,4-cis polybutadiene or copolymers of butadiene with other related diolefins through the catalytic polymerization or copolymerization of butadiene monomer by a continuous or discontinuous process carried out in the absence or substantial absence of solvents or diluents, operating in two successive phases (the first at a T&lt;30.degree. C. and the second at a T=or&gt;30.degree. C.) by control of the molecular weights.

Process for the polymerization or copolymerization of butadiene

The present invention relates to the production of 1,4-cis-polybutadiene and of copolymers of butadiene with other conjugated diolefins, by means of the catalytic polymerization or copolymerization of monomer butadiene, by an either continuous or batch process, operating in the presence or in the absence of diluents, and carrying out a portionwise addition, during the polymerization, of a portion of the organometallic compound of aluminum (or of the related hydride derivative), constituiting also one of catalytic components.

Isoprene polymers and copolymers are prepared by a polymerization process carried out in the absence of solvents and in the presence of a catalytic system comprising (a) at least one element or compound of an element pertaining to Group IIIB of the Periodic Table, (b) at least one aluminium alkyl derivative, (c) at least one organic halogen derivative or at least one halide of an element able to exist in at least two valency states with the halide corresponding to a higher state than the minimum, or at least one halogen or at least one hydrogen halide acid, (d) at least one compound containing one or more hydroxyl groups of which the hydrogen can be substituted, the ratio of component (b) to component (a) being equal to or less than 20.

Isoprene polymerization process

A new process is described for polymerizing and copolymerizing conjugate diolefins characterized by the use of a catalytic system comprising at least one compound of Group III B of the periodic system, at least one non-halogenated aluminium alkyl, at least one compound containing one or more hydroxyls of acid or neutral type, and possibly an inorganic compound containing Cl or Br in ionizable form or an organic halogen derivative. The new process allows the preparation, both in the absence and in the presence of an inert diluent, of polydiolefins of essentially entirely 1,4-cis structure which even in the absence of a purification stage contain a very small quantity of catalytic residues.

Process for preparing conjugate diolefins, and means suitable for this

A novel process is disclosed for polymerizing and copolymerizing alpha olefins (ethylene included) also in the presence of conjugated diolephins, and more particularly for copolymerizing ethylene with 1,3-butadiene, based on the use of a plural-component catalyst system, one of said components being a novel complex which contains titanium and magnesium. The process gives, in yields higher than 200,000 grams of polymer per g of elemental Ti, ethylene-butadiene copolymers having a distribution of monomeric units characterized by a particular novel .sup.13 C-NMR spectrum, a high apparent specific gravity and such a grit size as to impart flowability to the dry product, and a distribution in the presence of sulphur and accelerators such as to acquire a gel content (fraction insoluble in boiling xylenes) over 50%.

Polymerizing and copolymerizing olefinically unsaturated compounds and

An improved process is described for preparing conjugate diolefin polymers or copolymers having a high content of 1,4-cis units and high chain linearity, the process using a particular catalytic system prepared from a compound of a metal chosen from those of Group III B of the Periodic System which have an atomic number of between 21 and 103, preferably neodymium, an organic halogen derivative, and an aluminium alkylhydride or trialkyl.

Process for polymerizing conjugate diolefins, and means suitable for

A new process is described for polymerizing and copolymerizing conjugate diolefins, characterized by using a catalytic system formed from at least one metal pertaining to Group III B of the Periodic System, at least one non-halogenated aluminium alkyl, at least one organic halogen derivative or a halide of an element also able to exist in a lower valency state, and at least one compound containing one or more salifiable hydroxyl groups, i.e. of acid or neutral type. The new process allows the preparation, both in the absence and in the presence of inert diluents, of conjugate diolefin polymers of linear structure which are essentially entirely 1,4-cis. The method for preparing the new catalytic system is also described.

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Milan, Italy

Antonio Carbonaro