A123 Systems LLC

Markforged, Inc.

Massachusetts Institute of Technology

Telcordia Technologies, Inc.

Lithium Werks Technology Bv

Antoni S Gozdz

Gregory Thomas Mark

Yet-Ming Chiang

Gilbert N Riley, Jr

Andrew L Loxley

Richard K Holman

Michael S Viola

Andrew C Chu

William Douglas Moorehead

Ronnie Wilkins

Ricardo Fulop

Martin W Payne

Paul C Warren

Gilbert N Riley

Roger Lin

Anthony Edward Pullen

Leslie J Pinnell

C Michael Hoff

Caroline N Schmutz

Jeong Ju Cho

Hung-Chieh Shiao

Michele L Ostraat

Christopher Campion

Charles E Martin

Ric Fulop

Benjamin Nunes

Jean Marie Tarascon

Various embodiments related to three dimensional printers, and reinforced filaments, and their methods of use are described. In one embodiment, a void free reinforced filament is fed into a conduit nozzle. The reinforced filament includes a core, which may be continuous or semi-continuous, and a matrix material surrounding the core. The reinforced filament is heated to a temperature greater than a melting temperature of the matrix material and less than a melting temperature of the core prior to drag the filament from the conduit nozzle.

Three dimensional printing of composite reinforced structures

Various embodiments related to three dimensional printers, and reinforced filaments, and their methods of use are described. In one embodiment, a void free reinforced filament is fed into an extrusion nozzle. The reinforced filament includes a core, which may be continuous or semi-continuous, and a matrix material surrounding the core. The reinforced filament is heated to a temperature greater than a melting temperature of the matrix material and less than a melting temperature of the core prior to extruding the filament from the extrusion nozzle.

Three dimensional printing

Various embodiments related to three dimensional printers, and reinforced filaments, and their methods of use are described. In one embodiment, a void free reinforced filament is fed into an conduit nozzle. The reinforced filament includes a core, which may be continuous or semi-continuous, and a matrix material surrounding the core. The reinforced filament is heated to a temperature greater than a melting temperature of the matrix material and less than a melting temperature of the core prior to drag the filament from the conduit nozzle.

Impregnation system for composite filament fabrication in three dimensional printing

Methods for additive manufacturing using a three-dimensional printer including at least one linear feed mechanism and a print head positioned proximate a build platen are disclosed. The methods include a step of providing and/or feeding an unmelted fiber reinforced composite filament at a feed rate by the at least one linear feed mechanism. The methods include heating the filament to a temperature at which a matrix material therein flows within at least one rounded outlet of the print head. The methods include moving the print head and the build platen relative to one another at a printing rate. The methods include applying a spreading force to the filament between the at least one rounded outlet of the print head and the build platen. The methods include a step of controlling a differential in the feed rate and printing rate using the at least one linear feed mechanism so that the feed rate and the printing rate are substantially the same.

Apparatus for fiber reinforced additive manufacturing

Various embodiments related to three dimensional printers, and reinforced filaments, and their methods of use are described. In one embodiment, a void free reinforced filament is fed into an conduit nozzle. The reinforced filament includes a core, which may be continuous or semi-continuous, and a matrix material surrounding the core. The reinforced filament is heated to a temperature greater than a melting temperature of the matrix material and less than a melting temperature of the core prior to applying the filament from the conduit nozzle.

Methods for composite filament threading in three dimensional printing

Three dimensional printer with composite filament fabrication

According to one aspect, embodiments herein provide a 3-D printer comprising a composite filament supply, a build platen, a print head comprising a composite filament ironing tip and a heater, a plurality of actuators that move the print head and the build platen relative to one another in three degrees of freedom at a printing rate, at least one linear feed mechanism that advances the composite filament at a feed rate and drives the composite filament into the print head to deposit the composite filament, and a controller configured to operate the heater to heat the composite filament ironing tip to flow matrix material among axial fiber strands within the composite filament and operate the plurality of actuators to press the composite filament ironing tip against the composite filament and reshape the composite filament against one of the build platen and a composite filament previously deposited upon the build platen.

According to one aspect, embodiments of the invention provide an additively manufactured part, comprising a top portion, a bottom portion, and a plurality of compacted composite filaments arranged in layers between the top portion and the bottom portion, each compacted composite filament including one or more axial fiber strands, wherein the plurality of compacted composite filaments includes a first compacted composite filament located in a first layer and a second compacted composite filament located in a second layer, the first layer being located closer to the bottom portion than the second layer, and wherein the second compacted composite filament layer is compressed against the first compacted composite filament, forming a vertically bonded rank in which the one or more axial fiber strands of the second compacted composite filament intrudes into the first compacted composite filament.

Additively manufactured part including a compacted fiber reinforced composite filament

A rechargeable battery cell having a specific combination of anode, cathode and electrolyte formulation is provided. The electrolyte formulation includes an additive system and a salt system. The additive system includes a first additive containing a sulfonyl group, an anti-gassing agent, and a second additive. The salt system includes a lithium salt and a co-salt. The disclosed electrolyte formulation has reduced gassing and improved performance over a wide temperature range.

Electrolyte formulation for reduced gassing wide temperature range cycling

Methods for composite filament fabrication in three dimensional printing

Growing community of inventors

Acton, MA, United States of America

Antoni S Gozdz