Akzo Nobel N.v.

Teijin Aramid B.v.

Acordis Industrial Fibers Gmbh

Thijin Aramid B.v.

Anton Peter De Weijer

Sanjay Rastogi

Joris Eem Van Der

Hendrik Middeljans

Hendrik Van De Hee

Martinus Wilhelmus Maria Gemma Peters

Herman M Heuvel

Robert Jan Van Wijk

Johannes Bos

Gert Jan Jongerden

Bing Wang

Erik Swieringa

Christiaan J Van Den Heuvel

Christiaan J Maria

Dirk Albert Klarenberg

Roel De Jonge

Gerwin Elderman

Martinus Wilhelmis Maria Gemma Peters

An UHMWPE film having a tensile strength of at least 2.0 GPa, a tensile energy to break of at least 30 J/g, an Mw of at least 500 000 gram/mole, and a Mw/Mn ratio of at most 6, and a film width of at least 5 mm. The film may be manufactured via a process which comprises subjecting a starting UHMWPE with a weight average molecular weight of at least 500 000 gram/mole, an elastic shear modulus determined directly after melting at 160&#xb0; C. of at most 1.4 MPa, and a Mw/Mn ratio of at most 6 to a compacting step and a stretching step under such conditions that at no point during the processing of the polymer its temperature is raised to a value above its melting point. The film may be used as starting material in any applications where high tensile strength and high energy to break are important. Suitable applications include ballistic applications, ropes, cables, nets, fabrics, and protective applications.

Polyethylene film with high tensile strength and high tensile energy to break

The present invention pertains to a UHMWPE film having a tensile strength of at least 2.0 GPa, a tensile energy to break of at least 30 J/g, an Mw of at least 500 000 gram/mole, and a Mw/Mn ratio of at most 6. The film may be manufactured via a process which comprises subjecting a starting UHMWPE with a weight average molecular weight of at least 500 000 gram/mole, an elastic shear modulus determined directly after melting at 160&#xb0; C. of at most 0.9 MPa, and a Mw/Mn ratio of at most 6 to a compacting step and a stretching step under such conditions that at no point during the processing of the polymer its temperature is raised to a value above its melting point. The film may be used as starting material in any applications where high tensile strength and high energy to break are important. Suitable applications include ballistic applications, ropes, cables, nets, fabrics, and protective applications.

A process for manufacturing high molecular weight polyethylene fibers, including subjecting a polyethylene tape with a weight average molecular weight of at least 500,000 grams/mole, a Mw/Mn ratio of at most 6, and a 200/110 uniplanar orientation parameter of at least 3 to a force in the direction of the thickness of the tape over the entire width of the tape. A polyethylene fiber having a Mw of at least 500 000 gram/mole, a Mw/Mn ratio of at most 6, and a 020 uniplanar orientation value of at most 55&#xb0;.

Method for manufacturing high molecular weight polyethylene fibers

The present invention pertains to a polyethylene film and a process for manufacturing such film. The polyethylene film may have a ratio between the strength in a first direction in the film plane and the strength in a second direction in the film plane perpendicular to the first direction in the range of 0.1-10:1, the strength in at least one direction being at least 0.2 Gpa. The process for manufacturing a polyethylene film may have a starting UHMWPE polymer with an average molecular weight of at least 500,000 grams/mole, an elastic shear modulus determined directly after melting at 160&#xb0; C. of at most 1.4 MPa, and a Mw/Mn ratio of at most 6 to a solvent-free compacting process and a stretching process under such conditions that at no point during the process the temperature of the intermediate polymer film is raised to a value above its melting point.

Polyethylene film and method for the manufacture thereof

The invention pertains to a process for determining the dye uptake of polyethylene terephthalate fibers in which the fibers are irradiated with high-intensity monochromatic light. A light-sensitive sensor is used to measure the Raman scattering and compare it with that of an earlier established model on the basis of Raman spectra of polyethylene terephthalate fibers of known composition and structure. A model is used to calculate the density, which constitutes a quantitative measure of the dye uptake. In the calculation use is made of measurement points from a number of regions in the spectral measuring region of 598 to 1900 cm .

Process for determining the dye uptake of polyethylene terephthalate fibers

The invention pertains to a technique for determining the dye uptake or measuring one or more structural parameters or mechanical properties of polymeric fibres. This technique entails measuring the Raman spectrum of the fibres during or after a spinning process. After the Raman spectrum has been treated, a model is applied to it which is derived from the Raman spectra of fibres having the same chemical composition as the fibres to be examined.

Technique for measuring properties of polymeric fibres

Multifilament yarn, monofilament, or film, formed at least substantially of polyethylene naphthalate, has a strength of at least 400 MN/tex and a DSC melting point of at least 292.degree. C., where the DSC melting point is measured on a sample quantity of 2.5 mg at a heating rate of 20.degree. C. per min. For production, melted polyethylene naphthalate is extruded from a multi-hole spinneret, the filaments or film, solidified by cooling, are/is withdrawn at a rate of 500 to 10,000 m/min, where the filaments or film are/is subjected to a draw-down B of 40 to 25,000 from the spinneret output to the first withdrawal element. The polymer used may contain at least 85% by weight polyethylene naphthalate and have a melt flow index of 3 to 26.

Process of making multifilament yarn, monofilament or film of

Multifilament yarn, monofilament, or film, formed at least substantially of polyethylene naphthalate, has a strength of at least 400 mN/tex and a DSC melting point of at least 292.degree. C., where the DSC melting point is measured on a sample quantity of 2.5 mg at a heating rate of 20.degree. C. per min. For production, melted polyethylene naphthalate is extruded from a multi-hole spinneret, the filaments or film, solidified by cooling, are/is withdrawn at a rate of 500 to 10,000 m/min, where the filaments or film are/is subjected to a draw-down B of 40 to 25,000 from the spinneret output to the first withdrawal element. The polymer used may contain at least 85% by weight polyethylene naphthalate and have a melt flow index of 3 to 26.

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Nijmegen, Netherlands

Anton Peter De Weijer