Church Dwight & Co., Inc.

Anthony J Falotico

Louis R Mazzola

Charles D Carr

Steven A Bolkan

John Ip

Herman L Marder

Joseph G Becker

Bruce R Conley

Francis R Cala

This invention provides a powder carbonate-based laundry detergent which can be utilized in cold water fabric laundering with a minimized remainder of undissolved detergent residue in the wash water. An essential aspect of the laundry detergent formulation is a content of a partially sulfated and neutralized blend of ethoxylated alcohol surfactant constituents. A preferred type of surfactant ingredient is a Neodol 23-3 derived type of blend which is 60-65 percent sulfated and neutralized.

Powder laundry detergent product with improved cold water residue properties

This invention provides a high carbonate-low phosphate powder laundry detergent formulation which can be utilized in cold water fabric laundering with a minimized remainder of undissolved detergent residue in the wash water. An essential aspect of the laundry detergent formulation is a content of a partially sulfated and neutralized blend of ethoxylated alcohol surfactant constituents. A preferred type of surfactant ingredient is a Neodol 23-3 derived type of blend which is 50-65 percent sulfated and neutralized.

High carbonate-low phosphate powder laundry detergent product with improved cold water residue properties

A liquid aqueous, laundry detergent composition which has a pH in the range of about 7.0 to about 12.2 and comprises at least one active surfactant; an at least partially neutralized polymer of an .alpha.,.beta.-monoethylenically unsaturated carboxylic acid containing no more than nine carbon atoms which is either (1) a homopolymer of such an unsaturated carboxylic acid, (2) a copolymer of monomers consisting of at least two of such unsaturated carboxylic acids, or (3) a copolymer of monomers consisting of at least 50 mol % of at least one of such unsaturated carboxylic acids with at least one non-carboxylic acid .alpha.,.beta.-monoethylenically unsaturated comonomer containing no more than nine carbon atoms, said polymer having a number average molecular weight of up to about 10,000 and being present in an amount equivalent to at least about 0.025 wt. % of the corresponding unneutralized polymer; and about 30 to about 95 wt. % of water, based on the total weight of the composition. Articles washed with the liquid detergent composition of this invention exhibit unexpectedly less soil redeposition than articles washed with a similar composition but which does not contain such at least partially neutralized polymer.

Liquid laundry detergent composition containing a completely or

A process for preparing a free-flowing high bulk density granular laundry detergent product comprises pre-blending a powder admixture comprising (1) between about 40-90 weight percent of a water soluble detergent builder wherein at least 70 weight percent of the detergent builder is sodium carbonate, and (b) between about 0.5-10 weight percent of alkali metal chloride salt, (2) forming a builder-surfactant powder by blending the step (1) admixture with between about 5-40 weight percent of a detergent active ingredient which is a blend of sulfated ethoxylated alcohols and nonionic ethoxylated alcohols, (3) subjecting the builder-surfactant powder to treatment with water under agglomerating conditions, and (4) drying the detergent composition to provide a free-flowing granular laundry detergent product having a bulk density of at least 650 grams per liter, and in which the detergent granule surfaces are coated with a glossy shell of alkali metal salt crystallites.

Process for preparing a free-flowing high bulk density granular

A non-bleaching cleaning composition, e.g. laundry detergent, wherein the solids content comprises at least about 70 wt. % of sodium carbonate, and up to about 12 wt. % of elemental magnesium in the form of a water soluble salt, e.g., magnesium sulfate or magnesium chloride, based on the total weight of the solids composition. Preferably the composition also contains an active surfactant and, when used as a laundry detergent, a polymeric polycarboxylate, e.g., an acrylic acid polymer. Incorporation of magnesium ions in the foregoing cleaning composition containing carbonate ions is intended to minimize negative interactions that will occur between the precipitation of calcium carbonate and the substrate being cleaned, e.g., fabric encrustation when the composition is used as a laundry detergent.

Carbonate built cleaning composition containing added magnesium

This invention provides a liquid laundry detergent product with freeze/thaw and high/low temperature stability. The detergent product is an aqueous medium having a content of sodium carbonate detergent builder, and a surfactant blend of specific amounts of two anionic salt compounds and two nonionic compounds of specific chemical structure.

Clear, homogeneous and temperature-stable liquid laundry detergent

This invention provides a free-flowing high bulk density granular detergent product for heavy duty textile laundering utility. One essential aspect of an invention detergent product is a content of a partially sulfated and neutralized blend of ethoxylated alcohol surfactant constituents. Another essential aspect is a unique granule structure in which the surfaces are coated with a non-tacky glossy shell of alkali metal chloride salt crystallites. The said glossy coating facilitates free-flowing and tight-packing of the granules into a high bulk density compact mass.

Free-flowing high bulk density granular detergent product

A laundry detergent composition, wherein the solids content comprises an active surfactant, at least about 70 wt. % of a water soluble alkaline carbonate, e.g., sodium carbonate, and, a minor amount, for example, about 0.05 to 5 wt. % of a polymeric polycarboxylate, e.g., an acrylic acid polymer, based on the total weight of solids in the composition, the polymeric polycarboxylate being in a form such that its complete release into wash water is delayed to at least about 60 seconds after the complete dissolution of the alkaline carbonate. For example, the polymeric polycarboxylate may be present in slow dissolving granules which also contain a diluent salt such as sodium carbonate and a binder such as a low molecular weight polyethylene glycol. The delayed release of the polymeric polycarboxylate reduces fabric encrustation during washing, i.e., the precipitation of CaCO.sub.3 onto fabric surfaces due to the presence of soluble alkaline carbonate.

Carbonate built laundry detergent composition containing a delayed

A laundry detergent composition, wherein the solids content comprises an active surfactant, at least about 70 wt. % of a water soluble alkaline carbonate, e.g., sodium carbonate, up to about 12 wt. % of elemental magnesium in the form of a water soluble salt, e.g., magnesium sulfate or magnesium chloride, and about 0.05 to 5 wt. % of a polymeric polycarboxylate, e.g., an acrylic acid polymer, based on the total weight of solids in the composition. Incorporation of magnesium ions in the foregoing laundry detergent composition containing carbonate ions is intended to minimize negative interactions that will occur between the precipitation of calcium carbonate and the surfaces of the fabric being cleaned, e.g., fabric encrustation, with an enhancement of this effect due to the presence of the polymeric polycarboxylate.

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Doylestown, PA, United States of America

Anthony J Falotico