Ppg Industries, Inc.

Ashland Oil, Inc.

Anthony C Palermo

Rostyslaw Dowbenko

Karl F Schimmel

Jonathan T Martz

Thomas W Kelly

James A Meier

Suryya K Das

Roger M Christenson

James A Claar

Michael M Chau

Mary Ellen Rosenberger

Henry H Crum, Iii

Steven J Burks

Glenn L Mazza

Polyvinyl chloride plastisol composition suitable as a sealant

A stable emulsion polymer is prepared by the emulsion polymerization of a vinyl monomer component in the presence of a base neutralized copolymer having a peak molecular weight not exceeding 50,000 of an olefinically unsaturated material selected from the group consisting of 1-decene, 1-dodecene, undecenylic acid and mixtures thereof and an ethylenically unsaturated anhydride containing material. The emulsion polymer is particularly useful for preparing coating compositions which have excellent physical properties.

Emulsion polymers and coating compositions prepared therefrom

Disclosed is a liquid coating composition, useful for making a chip resistant coating, comprising a binder of: a first and a second urethane resin each containing terminal, reactive ethylenically unsaturated groups. Each urethane resin is prepared by reacting components comprising (A) an isocyanate-terminated prepolymer which is the product of reacting an organic polyisocyanate with an organic polyol with (B) an isocyanate reactive group-containing unsaturated monomer selected from hydroxyalkyl acrylates, hydroxyalkyl methacrylates and hydroxyalkyl acrylamides. The organic polyol for the first urethane resin has a hydroxyl functionality of 3 or more; the organic polyol for the second urethane resin has a hydroxyl functionality of less than three; and the average functionality of the polyols utilized for the first and second urethane resins is less than three. Also disclosed is a method of making a cured chip resistant, coating.

Chip resistant coatings and methods of application

A thickened composition which is cured by free-radical initiated polymerization is composed of a compound containing at least two ethylenically unsaturated double bonds per molecule; an active hydrogen-containing homopolymer or copolymer of a diene having a number average molecular weight of from 500 to 15,000; the active hydrogens being derived from hydroxyl, amino, or mercapto groups; and an organic polyisocyanate present in an amount sufficient to thicken said composition without gelation.

Compositions thickened through urethane reaction

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Gibsonia, PA, United States of America

Anthony C Palermo