Rohm and Haas Company

Montedison S.p.a.

S.r.l. Montedipe

Annick Du Vosel

Franco Francalanci

Paola Maggiorotti

Stefanio Bonsignore

Enrico Dal Canale

Polyaminoacid builders or co-builders having the general formula: ##STR1## that are useful in the formulations of detergents are disclosed. Preferred detergent formulations contain from 5 to 50 percent by weight of the polyaminoacid builder, preferably polyaspartic aicd or polyglutamic acid, together with surface-active agents, aluminosilicates and other detergent additives.

Polyaminoacids as builders for formulations of detergents

This invention relates to use of polyaminoacids as builders or co-builders in the formulation of detergents. These polyaminoacids, which are highly efficient as complexing agents, have good resistance to heat and stability to pH and are entirely biodegradable, have been chosen among those having the general formula: ##STR1## with substituents which are defined in the following description. The formulations of detergents contain, apart from the above builders, surface active agents, alumina-silicates and additives chosen from neutral salts, enzymes, bleaching agents, stabilizers, anti-foaming agents, perfumes, bactericides.

Octa-substituted derivatives of the macrocyclic tetramers obtained by condensation of resorcinol with an alkyl aldehyde, wherein the sutstituents are alkanoyl, p-alkylbenzoyl, and p-alkoxybenzoyl chains. These substituted tetramers show stable, tridimensional, columnar type mesophases wherein the crystalline lattice is formed with the central macrocyclic rings stacked one on another according to ordered columns, each ring being surrounded with alkyl chains in the melted state.

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Novara, Italy

Annick Du Vosel