Rolls-Royce Corporation

Praxair S.t. Technology, Inc.

Rolls-Royce North American Technologies Inc.

Praxair Technology, Inc.

Tosoh Smd, Inc.

Ann Bolcavage

Li Li

Stephanie Gong

Thomas Alan Taylor

Albert Feuerstein

Ngunjoh Lawrence Ndamka

Danny Lee Appleby

Neil Hitchman

Taylor K Blair

Sean E Landwehr

Matthew R Gold

Sunny Chang

Jun Shi

Adam Lee Chamberlain

Sungbo Shim

Randolph Clifford Helmink

Raymond John Sinatra

Jeff Hart

James Munroe

Thomas A Taylor

Raymond J Sinatra

Bruce Edward Varney

Kang N Lee

Hao Zhang

John Alan Weaver

Michael Cybulsky

Melissa Hughes

Kenneth A Green

Robert Golden

Taylor Keffer Blair

Randolph C Helmink

An example article includes a substrate and a barrier coating on the substrate. The barrier coating includes a matrix including a rare-earth disilicate extending from an inner interface facing the substrate to an outer surface opposite the inner interface. The barrier coating includes a graded volumetric distribution of rare-earth oxide rich (REO-rich) phase regions in the matrix along a direction from the inner interface to the outer surface. The graded volumetric distribution defines a first volumetric density of the REO-rich phase regions at a first region of the matrix adjacent the outer surface. The graded volumetric distribution defines a second volumetric density of the REO-rich phase regions at a second region of the matrix adjacent the inner surface. The second volumetric density is different from the first volumetric density. An example technique includes forming the barrier coating on the substrate of a component.

CMAS-resistant barrier coatings

An article may include a substrate including a ceramic matrix composite (CMC); a composite coating layer including a first coating material that includes a rare-earth disilicate and a second coating material that includes at least one of a rare-earth monosilicate, a CMAS-resistant material, or a high-temperature dislocating material, where the second coating material forms a substantially continuous phase in the composite coating layer.

Composite coating layer for ceramic matrix composite substrate

The disclosure describes articles and techniques that include an airfoil having a hybrid coating system to provide improved particle impact resistance and improve CMAS attack resistance on the pressure side of the airfoil and improved thermal load protection on the suction side of the airfoil. An example article for a gas turbine engine may include a substrate, and a hybrid environmental barrier coating (EBC) including a relatively dense EBC layer on a first portion of the substrate and a relatively porous EBC layer on a second portion of the substrate, where the first portion of the substrate is different from the second portion of the substrate, and wherein at least a portion of the relatively porous EBC layer overlaps at least a portion of the relatively dense EBC layer in an overlap region.

Hybrid airfoil coatings

A method includes predicting a composition of calcium-magnesium-aluminum-silicate (CMAS) to be encountered by a high temperature mechanical system during use of the high temperature mechanical system. The method further includes selecting a composition of a CMAS-resistant barrier coating layer based at least in part on the predicted composition of CMAS. The CMAS-resistant barrier coating layer includes a base composition and at least one secondary oxide selected based on the predicted composition of CMAS. The at least one secondary oxide includes at least one of an oxide of a divalent element, an oxide of a trivalent element, or an oxide of a tetravalent element. The CMAS-resistant barrier coating layer comprises greater than 0 mol. % and less than about 7 mol. % of the at least one secondary oxide.

An article may include a substrate, a plurality of cooling holes in the substrate, wherein each of the plurality of cooling holes defines substantially the same diameter measured parallel to an outer surface of the substrate, and a coating on the surface of the substrate. In accordance with these examples, the coating covers and substantially blocks a first set of cooling holes from the plurality of cooling holes and leaves a second set of cooling holes from the plurality of cooling holes substantially uncovered. In some examples, an article including a substrate, a plurality of cooling holes in the substrate, and a coating on the substrate. In accordance with these examples, the coating covers and partially occludes each cooling hole of the plurality of cooling holes, and the coating does not extend into any of the plurality of cooling holes.

Damage tolerant cooling of high temperature mechanical system component including a coating

An article for use in a high-temperature environment that includes a substrate including a superalloy material, a ceramic, or a ceramic matrix composite, and an abradable coating on the substrate, the abradable coating including a rare earth silicate and a dislocator phase, the dislocator phase forms one or more distinct phase regions in the abradable coating and comprises at least one of hafnium diboride (HfB), zirconium diboride (ZrB), tantalum nitride (TaN or TaN), tantalum carbide (TaC), titanium diboride (TiB), zirconium carbide (ZrC), hafnium carbide (HfC), tantalum diboride (TaB), hafnium nitride (HfN), or niobium carbide (NbC).

Low porosity abradable coating

A method that includes introducing a suspension comprising a coating material and a carrier into a heated plume of a thermal spray device. The coating material may include silicon or a silicon alloy. The method further includes directing the coating material using the heated plume toward a substrate that includes a ceramic or a ceramic matrix composite and depositing the coating material to form a bond coat directly on the substrate such that the bond coat defines a porosity of less than about 3 percent by volume.

High density bond coat for ceramic or ceramic matrix composites

An article includes a substrate, a bond coat on the substrate, and a multilayer environmental barrier coating (EBC) on the bond coat. The multilayer EBC includes a first EBC layer defining a first thickness and a second EBC layer defining a second thickness. The first EBC layer includes a first rare earth disilicate and a first concentration of a sintering aid that includes alumina. The second EBC layer includes a second rare earth disilicate and a second concentration of the sintering aid that includes alumina, less than the first concentration of the sintering aid.

Multilayer environmental barrier coating

In some examples, method including forming an EBC layer on a substrate, wherein the EBC layer exhibits an initial porosity; forming a layer of silicate glass on a surface of the EBC layer; and melting the silicate glass on the surface of the EBC layer to infiltrate the EBC layer with the molten silicate glass to decrease the porosity of the EBC layer from the initial porosity to a final porosity.

Dense environmental barrier coatings

An article may include a substrate including a ceramic or a CMC; a bond layer on the substrate; and a diffusion barrier layer between the substrate and the bond layer. The diffusion barrier layer may include at least one of molybdenum metal, tantalum metal, tungsten metal, or niobium metal. In some examples, the article may include a stabilizing layer that includes at least one of a silicide of molybdenum (MoSi), tantalum (TaSi), tungsten (WSi), or niobium (NbSi), between the diffusion barrier layer and the bond layer.

Diffusion barrier layers for ceramic matrix composites

A barrier coating for isolating a metallic support component from a composite component in a gas turbine engine is provided. The barrier coating may be applied to the metallic support component so that when the ceramic component is mounted on the metallic support component the barrier coating is engaged.

Coating for isolating metallic components from composite components

An article may include a substrate, a diffusion barrier layer formed on the substrate, and a protective layer formed on the diffusion barrier coating. The diffusion barrier layer may include iridium.

Interfacial diffusion barrier layer including iridium on a metallic substrate

In some examples, an article may include a superalloy substrate and a coating on the superalloy substrate. In accordance with this example, the coating includes a diffusion barrier layer on the substrate and a wear resistant oxide layer over the diffusion barrier layer. The diffusion barrier layer may include iridium and the wear resistant oxide layer may include at least one of silica, zirconia, or chromia.

Coating system including diffusion barrier layer including iridium and oxide layer

This invention relates to high purity yttria or ytterbia stabilized zirconia powders comprising from about 0 to about 0.15 weight percent impurity oxides, from about 0 to about 2 weight percent hafnium oxide (hafnia), from about 6 to about 25 weight percent yttrium oxide (yttria) or from about 10 to about 36 weight percent ytterbium oxide (ytterbia), and the balance zirconium oxide (zirconia). Thermal barrier coatings for protecting a component such as blades, vanes and seal surfaces of gas turbine engines, made from the high purity yttria or ytterbia stabilized zirconia powders, have a density greater than 88% of the theoretical density with a plurality of verticalzA macrocracks homogeneously dispersed throughout the coating to improve its thermal fatigue resistance.

Growing community of inventors

Indianapolis, IN, United States of America

Ann Bolcavage