Petro-canada

Energy, Mines & Resources - Canada

Anil K Jain

Barry B Pruden

Theo J De Bruijn

Dirkson D Liu

Chandra P Khulbe

Keith Belinko

William H Dawson

Paul L Sears

Serge Rivard

Dennis Lambiris

A heavy hydrocarbon oil, a substantial portion of which boils above 524.degree. C., is subjected to hydrocracking with a fractionated heavy oil recycle stream containing active additive particles. In the process, a slurry feed of (1) fresh heavy hydrocarbon oil feedstock and a heavy hydrocarbon recycle and (2) from about 0.01-4% by weight (based on fresh feedstock) of iron sulphate additive particles having sizes less than 45 .mu.m, is passed upwardly through a confined vertical hydrocracking zone. A mixed effluent is removed from the top of the hydrocracking zone, which is then passed through a hot separator vessel. From the bottom of the separator is withdrawn a liquid heavy hydrocarbon stream comprising heavy hydrocarbons and particles of the iron sulphate additive converted mainly to an iron sulphide phase. This separated liquid heavy hydrocarbon stream is fractionated to obtain a heavy oil which boils above 450.degree. C., containing the additive particles. The fractionated heavy oil containing the additive particles is then recycled to and mixing with the hydrocracking zone feed slurry in an amount up to 40% by weight of the combined feed slurry.

Hydrocracking of heavy hydrocarbon oils with heavy hydrocarbon recycle

A process for the conversion of a heavy hydrocarbon oil in the presence of hydrogen and iron-petroleum coke catalyst is described in which the iron-petroleum coke catalyst is prepared by grinding petroleum coke particles and particles of an iron compound in oil to form an additive slurry or paste and mixing the petroleum coke-iron oil slurry or paste with the heavy hydrocarbon oil to form a feedstock to hydroconverter.

Hydrocracking of heavy oils in presence of petroleum coke derived from

A process for the conversion of a heavy hydrocarbon oil in the presence of hydrogen and a catalyst or additive is described. It is shown that conversion can be increased by injecting an anti-foaming agent or a solution of anti-foaming agent in light oil into the reactor. Significantly better results are obtained when the anti-foam or the solution of anti-foam is injected directly into the top section of the reactor.

Antifoam to achieve high conversion in hydroconversion of heavy oils

A hydroconversion process is described in which a feed slurry comprising a heavy hydrocarbon oil and an iron compound additive is contacted with a hydrogen-containing gas in a hydroconversion zone at hydroconversion conditions to convert at least a portion of said oil to lower boiling products. The process is characterized by the use of an iron compound having particle sizes of less than 45 .mu.m, preferably with at least 50 wt % of particles of less than 5 .mu.m.

Hydrocracking of heavy oil in presence of ultrafine iron sulphate

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Oakville, Canada

Anil K Jain