International Paper Company

The Procter Gamble Company

Weyerhaeuser Nr Company

Weyerhaeuser Company Limited

Wyerhauser Nr Company

Angel Stoyanov

Charles E Miller

Torsten Lindner

Karen Brogan

Maike Siemons

Holger Beruda

Ludwig Busam

Shahrokh A Naieni

Jörg Endres

R Scott Stephens

Joerg Endres

Bleached polyacrylic acid crosslinked cellulose fibers with reduced furfural content are disclosed. The reduced furfural content is accompanied by a strong reduction of malodor associated with crosslinked fibers. Methods of furfural reduction include treatment with hydrogen peroxide in the absence of alkaline or other bleaching agents subsequent to curing polyacrylic acid crosslinked cellulose fibers. Some embodiments of treated polyacrylic acid crosslinked cellulose fibers have a furfural content lower than 1.3 ppm. In some embodiments, the reduction of furfural content of the treated crosslinked fibers compared to untreated crosslinked fibers is at least 55%. in some embodiments, furfural content decreases with aging of the treated crosslinked fibers.

Reduced furfural content in polyacrylic acid crosslinked cellulose fibers

Grafted, crosslinked cellulosic materials include cellulose fibers and polymer chains composed of at least one monoethylenically unsaturated acid group-containing monomer (such as acrylic acid) grafted thereto, in which one or more of said cellulose fibers and said polymer chains are crosslinked (such as by intra-fiber chain-to-chain crosslinks). Some of such materials are characterized by a wet bulk of about 10.0-17.0 cm3/g, an IPRP value of about 1000 to 7700 cm2/MPa&#xb7;sec, and/or a MAP value of about 7.0 to 38 cm H2O. Methods for producing such materials may include grafting polymer chains from a cellulosic substrate, followed by treating the grafted material with a crosslinking agent adapted to effect crosslinking of one or more of the cellulosic substrate or the polymer chains. Example crosslinking mechanisms include esterfication reactions, ionic reactions, and radical reactions, and example crosslinking agents include pentaerythritol, homopolymers of the graft species monomer, and hyperbranched polymers.

Grafted crosslinked cellulose

Grafted, crosslinked cellulosic materials used in absorbent articles, the grafted crosslinked cellulosic materials including cellulose fibers and polymer chains composed of at least one monoethylenically unsaturated acid group-containing monomer (such as acrylic acid) grafted thereto, in which one or more of the cellulose fibers and the polymer chains are crosslinked (such as by intra-fiber chain-to-chain crosslinks). Some of such materials are characterized by a wet bulk of about 10.0-17.0 cm/g, an IPRP value of about 1000 to 7700 cm/MPa&#xb7;sec, and/or a MAP of about 7.0 to 38 cm HO. Methods for producing such materials may include grafting polymer chains from a cellulosic substrate, followed by treating the grafted material with a crosslinking agent adapted to effect crosslinking of one or more of the cellulosic substrate or the polymer chains.

Grafted crosslinked cellulose used in absorbent articles

Grafted, crosslinked cellulosic materials include cellulose fibers and polymer chains composed of at least one monoethylenically unsaturated acid group-containing monomer (such as acrylic acid) grafted thereto, in which one or more of said cellulose fibers and said polymer chains are crosslinked (such as by intra-fiber chain-to-chain crosslinks). Some of such materials are characterized by a wet bulk of about 10.0-17.0 cm/g, an IPRP value of about 1000 to 7700 cm/MPa&#xb7;sec, and/or a MAP value of about 7.0 to 38 cm HO. Methods for producing such materials may include grafting polymer chains from a cellulosic substrate, followed by treating the grafted material with a crosslinking agent adapted to effect crosslinking of one or more of the cellulosic substrate or the polymer chains. Example crosslinking mechanisms include esterfication reactions, ionic reactions, and radical reactions, and example crosslinking agents include pentaerythritol, homopolymers of the graft species monomer, and hyperbranched polymers.

Absorbent articles comprising bleached polycrylic acid crosslinked cellulose fibers with reduced furfural content are disclosed. The reduced furfural content is accompanied by a strong reduction of malodor associated with crosslinked fibers. Methods of furfural reduction include treatment with hydrogen peroxide in the absence of alkaline or other bleaching agents subsequent to curing polyacrylic acid crosslinked cellulose fibers. Some embodiments of treated polycrylic acid crosslinked cellulose fibers have a furfural content lower than 1.3 ppm. In some embodiments, the reduction of furfural content of the treated crosslinked fibers compared to untreated crosslinked fibers is at least 55%. In some embodiments, furfural content decreases with aging of the treated crosslinked fibers.

Reduced furfural content in polyacrylic acid crosslinked cellulose fibers used in absorbent articles

A crosslinked cellulose fiber that has been crosslinked with a low molecular weight polyacrylic acid crosslinking agent, having phosphorous incorporated into the polymer chain and a method of crosslinking the fiber.

Cellulose fibers crosslinked with low molecular weight phosphorous containing polyacrylic acid and method

The process of making crosslinked cellulose pulp fiber comprising plasma treating a sheet of cellulose pulp fiber before the sheet is impregnated with a crosslinking formulation which comprises a crosslinking agent and a catalyst, then defiberizing the treated cellulose pulp sheet to form treated defiberized cellulose pulp, then heating and curing the treated defiberized cellulose pulp to form intrafiber crosslinked cellulose pulp fibers.

Reduction of fiber knots of cellulose crosslinked fibers by using plasma pre-treated pulpsheets

Bleached polyacrylic acid crosslinked cellulosic fibers, methods for making the fibers, and products including the fibers. The bleached polyacrylic acid crosslinked cellulosic fibers are polyacrylic acid crosslinked cellulosic fibers that have been treated with one or more bleaching agents to provide crosslinked cellulosic fibers having improved whiteness.

Bleached polyacrylic acid crosslinked cellulosic fibers

A method for making bleached crosslinked cellulosic fibers having high color and brightness properties is disclosed. In the method cellulosic fibers which have been with a crosslinking agent in the presence of a polyol are treated with a bleaching agent to yield cellulosic fibers with high color and brightness.

Growing community of inventors

Federal Way, WA, United States of America

Angel Stoyanov