Johnson Matthey Public Limited Company

Other

Johnson Matthey Inc.

Andrew Newman

Neil Greenham

Jing Lu

Isabel Zoe Tingay

Guy Richard Chandler

Rainer Leppelt

Gudmund Smedler

Mikael Larsson

David Micallef

Kaneshalingam Arulraj

Olivier Sonntag

Tim Genschow

Paul Richard Phillips

Hai-Ying Chen

Joseph Michael Fedeyko

Agnes Suganya Raj

Colin Russell Newman

Lee Alexander Gilbert

Oliver Hemming

Per Marsh

Heledd Howells

Zuharia Arshad

Nicholas Spencer

Rob Walker

Oliver Rowe

Christopher Smith

Methods and compositions related to a selective catalytic reduction catalyst comprising iron and vanadium, wherein the vanadium is present as (1) one or more vanadium oxides, and (2) metal vanadate of the form FeMVOwhere x=0.2 to 1 and y=1&#x2212;x, and where M comprises one or more non-Fe metals when y&#x3e;0.

Vanadium SCR catalysts

A catalyst article for treating a flow of a combustion exhaust gas comprises: a catalytically active substrate comprising one or more channels extending along an axial length thereof through which, in use, a combustion exhaust gas flows, the one or more channels having a first surface for contacting a flow of combustion exhaust gas; wherein the substrate is formed of an extruded vanadium-containing SCR catalyst material, wherein a first layer is disposed on at least a portion of the first surface, wherein the first layer comprises a washcoat of an ammonia slip catalyst composition comprising one or more platinum group metals supported on a particulate metal oxide support material, and wherein a layer comprising a washcoat of SCR catalyst composition is disposed on a surface in the one or more channels, wherein at least the portion of the first surface on which the first layer is disposed comprises a compound of copper, iron, cerium or zirconium or a mixture of any two or more thereof.

Catalyst article for use in an emission treatment system

A catalytic article for treating an exhaust gas stream containing particulate matter, hydrocarbons, CO, and ammonia, the article may include: (a) a substrate having an inlet end and an outlet end defining an axial length; (b) a first catalyst coating including: 1) a platinum group metal distributed on a molecular sieve, and 2) a base metal distributed on a molecular sieve; and (c) a second catalyst coating including: 1) a platinum group metal distributed on a molecular sieve, and 2) a base metal distributed on a molecular sieve.

ASC with platinum group metal in multiple layers

A catalyst article including a substrate with an inlet end and an outlet end, a first zone and a second zone, where the first zone comprises: a) an ammonia slip catalyst (ASC) bottom layer comprising a platinum group metal on a support; and b) an SCR layer comprising a second SCR catalyst, the SCR layer located over the ASC bottom layer; where the second zone comprises a catalyst ('second zone catalyst') selected from the group consisting of a diesel oxidation catalyst (DOC) and a diesel exotherm catalyst (DEC); wherein the ASC bottom layer extends into the second zone; and where the first zone is located upstream of the second zone. The ASC bottom layer may include a blend of: (1) the platinum group metal on a support and (2) a first SCR catalyst.

SCR with turbo and ASC/DOC close-coupled system

A catalyst article for treating a flow of a combustion exhaust gas comprises: a catalytically active substrate comprising one or more channels extending along an axial length thereof through which, in use, a combustion exhaust gas flows, the one or more channels having a first surface for contacting a flow of combustion exhaust gas; wherein the substrate is formed of an extruded vanadium-containing SCR catalyst material, wherein a first layer is provided on at least a portion of said first surface, wherein the first layer comprises an ammonia slip catalyst composition comprising one or more platinum group metals supported on titania, a silica-titania mixed oxide, a Ce&#x2014;Zr mixed oxide, or a mixture thereof, and a second layer is provided on at least a portion of the first layer and comprises an SCR catalyst composition.

A catalytic article having a flow-through substrate having an inlet, an outlet, and an axial length; an SCR zone containing a first SCR catalyst; and an oxidation zone containing (a) an ASC zone and a DOC zone or (b) a mixed ASC and DOC zone, where the oxidation zone contains an ammonia oxidation catalyst and a DOC catalyst, the SCR zone is positioned on the substrate from the inlet end and extends less than the axial length of the substrate from the inlet, the DOC zone or the mixed ASC and DOC zone is position on the substrate from the outlet end, and when the DOC zone is present, the ASC zone is located between the SCR zone and the DOC zone. In other catalytic articles, the ASC zone further comprises a DEC catalyst. Methods of using the catalytic articles in an SCR process, where the amount of ammonia slip is reduced, are also described.

Zoned exhaust system

Provided is a system for treating an exhaust gas comprising a first SCR catalyst zone comprising an iron loaded medium- or large-pore molecular sieve having a first ammonia storage capacity; and a second SCR catalyst zone comprising a copper loaded small-pore molecular sieve having a second ammonia storage capacity, wherein the first SCR catalyst zone is disposed upstream of the second SCR catalyst zone with respect to normal exhaust gas flow through the system and wherein the second ammonia storage capacity is greater than the first ammonia storage capacity. Also provided is a method for using the system to treat exhaust gas.

Zoned catalyst for treating exhaust gas

Provided is a system for treating an exhaust gas comprising a first SCR catalyst zone comprising vanadium loaded on a metal oxide selected from TiO, ZrO, SiO, CeO, and AlO; and a second SCR catalyst zone comprising a copper loaded small-pore molecular sieve, wherein the first SCR catalyst zone is disposed upstream of the second SCR catalyst zone with respect to normal exhaust gas flow through the system. Also provided is a method for using the system to treat exhaust gas.

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Royston, United Kingdom

Andrew Newman