Exxon Research and Engineering Company

Other

Andrew Kaldor

Paul Rabinowitz

Martin B Dines

Richard B Hall

Richard Kenneth Lyon

George M Kramer

Alexander Stein

The present invention teaches a unique laser radiometer capable of accurately measuring the radiation temperature of a radiant surface and independently measuring the surface's emissivity. A narrow-band radiometer is combined with a laser reflectometer to measure concurrently radiance and emissivity of a remote, hot surface. Together, radiance and emissivity yield the true surface temperature of the remote target. A narrow receiver bandwidth is attained by one of two methods; (a) heterodyne detection or (b) optical filtering. A direct measurement of emissivity is used to adjust the value obtained for the thermal radiation signal to substantially enhance the accuracy of the temperature measurement for a given subject surface. The technique provides substantially high detection sensitivity over a very narrow spectral bandwidth.

Laser radiometer

This application discloses a method of separating the isotopes of an element which form a volatile compound having an isotopically shifted but overlapping infrared absorption spectrum. In the method, IR radiation of first and second laser frequencies are employed. The first infrared laser frequency produces a selective excitation of the desired isotope of the compound, while the second infrared laser frequency produces a higher multiphoton excitation which allows conversion of the excited compound.

Isotope separation process

Novel compositions of matter are disclosed having the formula UO.sub.2 AA'L.sub.n, wherein n is 0 or 1, and in which A and A' are anions whose conjugate acids have boiling points less than about 200.degree. C. and pK.sub.a values of 4.8 or less, L is a neutral ligand having a boiling point less than about 190.degree. C. and having an equilibrium constant for the exchange reaction with tetrahydrofuran of between about 10.sup.-3 and 10.sup.3, and the combination of A, A' and L satisfy five or six coordination sites of the central uranium atom.

Volatile uranyl compounds

The instant invention relates to a process for separating a material into two or more parts in each of which the abundances of the isotopes of a given element differ from the abundances of the isotopes of the same material in said material. More particularly, the invention relates to a method for the isotopically selective excitation of gas phase UF.sub.6 by infrared photon absorption followed by selective reaction of said excited UF.sub.6 with atomic chlorine, bromine, or iodine to form a product which may be separated by means known in the art.

The claimed invention is a method of isotope separation based on the unimolecular decomposition of vibrationally excited negative ions which are produced in the reaction of thermal electrons and molecules which have been vibrationally excited in an isotope selective manner. This method is especially applicable to molecules represented by the formula MF.sub.6 wherein M is selected from the group consisting of U, S, W, Se, Te, Mo, Re, and Tc.

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Berkeley Heights, NJ, United States of America

Andrew Kaldor