Eastman Chemical Company

Andrew E Brink

Jeffrey Todd Owens

Thomas Joseph Pecorini

Gerald Timothy Keep

Alan J Oshinski

Bruce C Bell

The present invention relates to a composite made by the process of melt mixing (a) a polymer having at least one isocyanate reactive group, wherein the polymer is from 30 to 90% by weight of the composite; (b) a thermoplastic polyurethane at from 0.1 to less than 10% by weight of the composite; and (c) a reinforcing fiber at from 9.9 to 60% by weight of the composite, wherein the sum of the weight percentages of components (a)-(c) is equal to 100%, wherein the polymer (a) is not a polyamide. The invention further relates to a composite prepared by the process of melt mixing (a) a polymer having at least one isocyanate reactive group, wherein the polymer is from 25 to 90% by weight of the composite; (b) a thermoplastic polyurethane at from 0.1 to 10% by weight of the composite; (c) a reinforcing fiber at from 9.8 to 60% by weight of the composite, and (d) an epoxy compound at from 0.1 to 5% by weight of the composite, wherein the sum of the weight percentages of components (a)-(d) is equal to 100%. The invention further relates to the methods for making the composites of the present invention. The invention further relates to articles containing the composites of the present invention.

Thermoplastic polyurethane additives for improved polymer matrix composites and methods of making and using therefor

The use of a specified molecular weight range of poly(alkylene ether)s, such as poly(ethylene glycol) (PEG), poly(tetramethylene glycol) (PTMG), and poly(propylene glycol) (PPG), and end-capped poly(alkylene ether)s, as plasticizers for polyesters such as poly(ethylene terephthalate) (PET), poly(propylene terephthalate) (PPT), poly(butylene terephthalate) (PBT), poly(ethylene naphthalate) (PEN), and poly(1,4-cyclohexanedimethylene terephthalate) (PCT), that are non-volatile during drying processes as well as during melt processing. Such poly(alkylene ether)s and end-capped poly(alkylene ether)s decrease the melt viscosity of the polymer matrix and depress the glass transition temperature, and thereby improve the processability of polyesters.

Non-volatile plasticizers and flow aids for polyesters

A process for preparing a high strength fiber reinforced polymer composite comprising:

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Durham, NC, United States of America

Andrew E Brink