Dow Corning Corporation

Andrew Bruce Gammie

Roland L Halm

Christopher Darren Gatti

Dennis Gene Van Koevering

Christopher James Kozenski

Roland Lee Halm

Chlorosilanes such as dimethyldichlorosilane are hydrolyzed in a first super-azeotropic hydrochloric acid distillation column A to produce cyclosiloxanes, chlorosiloxanes, and hydrogen chloride gas. The cyclosiloxanes and the chlorosiloxanes are washed and separated according to their volatility in a second sub-azeotropic hydrochloric acid distillation column B, to produce a substantially chloride free volatile cyclosiloxane stream and a substantially chloride free non-volatile siloxane stream. The process is substantially chloride efficient.

Reactive distillation of chlorosilanes

Chlorosilanes are hydrolyzed to a hydrolysate in a looped system containing a hydrolysis reactor, an HCl purifier, a wash means, and a separator. The steps of the method comprise:

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Florence, KY, United States of America

Andrew Bruce Gammie