Eastman-kodak Company

University of Texas System

Andrei Andrievsky

David T Southby

Dale E DeCann

Jonathan L Sessler

Richard L Parton

Thomas L Penner

William J Harrison

Steven Evans

Helmut Weber

Samuel Chen

Petra I Sansom

William E Allen

Christopher T Brown

Andreas Gebauer

Vincent Lynch

Philip A Gale

James Albert Reczek

Bruce C Campbell

Vladimir A Kr Al

Vladimír A Král

Vladim&iacute;r A Kr&aacute;l

John W Genge

The present invention provides calixpyrrole, calixpyridinopyrrole, and calixpyridine macrocycles, having 4, 5, 6, 7, or 8 heterocyclic rings, as well as syntheses, derivatives, conjugates, multimers, and solid supports thereof. Such macrocycles have proved to be effective and selective ion- and neutral molecule-binding agents forming supramolecular ensembles, and ion- and neutral molecule-separation agents. The macrocycles are fully meso-non-hydrogen-substituted porphyrinogens, a few molecules of which were previously known but not recognized as possessing anion- or molecule-binding properties. The binding mode is noncovalent, primarily that of hydrogen-bonding, thereby providing a new mode for liquid chromatography, that of Hydrogen Bonding Liquid Chromatography. Further useful applications of the macrocycles provided herein include environmental remediation by removal of undesired ions or neutral molecules, and removal of phosphate for kidney dialysis.

Calixpyrroles

An ink jet ink composition of water, humectant and a self-assembling colorant that is capable of spontaneously forming a nanoparticulate dispersion without any prior physical attrition or surface modification, the colorant having the formula: (A)&#x2014;Q&#x2014;(Z)wherein: Q represents a chromophore; each A independently represents an organic or inorganic group capable of hydrogen bonding or other non-covalent bonding; each Z independently represents an organic or inorganic group capable of electrostatic bonding; and m and n each independently represents an integer from 0 to 10; with the proviso that n+m is at least 1; and with the further proviso that at least about 50 wt. % of the colorant is present in the composition as particles.

Ink jet ink composition

An ink jet printing process having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink jet recording elements having a support having thereon an image-receiving layer; C) loading the printer with an ink jet ink composition of water, humectant and a self-assembling colorant that is capable of spontaneously forming a nanoparticulate dispersion without any prior physical attrition or surface modification, the colorant having the formula: (A) &mdash;Q&mdash;(Z) wherein: Q represents a chromophore; each A independently represents an organic or inorganic group capable of hydrogen bonding or other non-covalent bonding; each Z independently represents an organic or inorganic group capable of electrostatic bonding; and m and n each independently represents an integer from 0 to 10; with the proviso that n&plus;m is at least 1; and with the further proviso that at least about 50 wt. % of the colorant is present in the composition as particles; and D) printing on the image-receiving layer using the ink jet ink in response to the digital data signals.

Ink jet printing process

An ink jet ink composition including water, humectant and a metallized, phthalocyanine colorant, the metallized, phthalocyanine colorant having the formula: MPc(SO X) (SO NRR&prime;) wherein: M represents a metal; Pc represents a phthalocyanine nucleus; each X independently represents hydrogen, alkali metal or an organic cation; a is from 0 to 3; b is from 1 to 4; each R independently represents a substituted or unsubstituted alkyl group having from 1 to about 15 carbon atoms, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group; and each R&prime; independently represents R or hydrogen; with the proviso that a&plus;b is an average of from 2 to 4; and with the further proviso that at least about 50 wt. % of the metallized, phthalocyanine colorant is present in the composition as particles.

Ink jet composition

An ink jet printing process having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink jet recording elements having a support having thereon an image-receiving layer; C) loading the printer with an ink jet ink composition including water, humectant and a metallized, phthalocyanine colorant, the metallized, phthalocyanine colorant having the formula: MPc(SO X) (SO NRR&prime;) wherein: M represents a metal; Pc represents a phthalocyanine nucleus; each X independently represents hyrdrogen, alkali metal or an organic cation; a is from 0 to 3; b is from 1 to 4; each R independently represents a substituted or unsubstituted alkyl group having from 1 to about 15 carbon atoms, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic group; and each R&prime; independently represents R or hydrogen; with the proviso that a&plus;b is an average of from 2 to 4; and with the further proviso that at least about 50 wt. % of the metallized, phthalocyanine colorant is present in the composition as particles; and D) printing on the image-receiving layer using the ink jet ink in response to the digital data signals.

Photographic material having improved color reproduction

Color photographic material having enhanced light absorption

Calixpyrroles, calixpyridinopyrroles and calixpyridines

A silver halide color photographic material comprises at least one silver halide emulsion comprising silver halide grains having associated therewith at least two dye layers comprising

The present invention provides novel sapphyrin dimers, trimers, oligomers and polymers, which multimers may include repeating units of sapphyrin or sapphyrin derivatives alone, or may further incorporate other units such as nucleobases.

Sapphyrin multimers

Growing community of inventors

Webster, NY, United States of America

Andrei Andrievsky