Henkel Ag & Company, Kgaa

Nitrochemie Aschau Gmbh

Andrea Gutacker

Johann Klein

Esteban Mejia

Annika Dietrich

Udo Kragl

Therese Hemery

Helene Boudet

Adrian Duracu

Ligang Zhao

Sebastien Lanau

Sebastian Kapusta

Jan-Erik Damke

Horst Beck

Claudia Meckel-Jonas

Johannes Gerardus De Vries

Klaus Helpenstein

Adrian Brandt

Ralf Dunekake

Markus Bonigut

Christian Kastner

Kerstin Unger

Jens Baumgard

Henrik Lund

Steve Hillbrandt

Dengxu Wang

Martha Hoehne

Nayereh Mohebbati

Sergey Tin

Niklas Schafhausen

Felix Geitner

Andrea Dellacqua

Esteban Meija

Martha HÖHNE

The present invention relates to radiation of dual radiation/moisture curable compositions based on (meth)acrylate- and silane-terminated polymers that can be used as 3D printing materials and provide isotropic and elastomeric properties. The invention further relates to the use thereof as 3D printing materials and printing methods using said compositions.

Radiation curable and printable composition

The invention relates to a bi-functionalized polysiloxane brush copolymer comprising at least one hydroxyl-terminated polyalkyleneglycol side chain and at least one onium-functionalized side chain as defined herein, and a method for preparing the bi-functionalized polysiloxane brush copolymer, a curable composition comprising the bi-functionalized polysiloxane brush copolymer and its use.

Bi-functionalized polysiloxane brush copolymers

The present disclosure relates to a radiation or radiation/moisture dual curable compositions based on (meth)acrylate polymers or (meth)acrylate- and silane-terminated polymers. The invention further relates to their use as an adhesive, sealant and/or coating material, and adhesive, sealant and/or coating materials comprising said curable composition thereof.

Radiation curable composition with improved mechanical properties

The present invention relates to an onium-functionalized siloxane having the general Formula (X) or (X-A) as defined herein; a method for preparing the onium-functionalized siloxane; and its use as an antimicrobial agent.

Onium-functionalized siloxanes

The invention relates to a curable composition comprising: a) at least one polymer having at least one silicon-containing group of formula —Si(R)(Y)as defined herein, and b) at least one hydroxyl-functionalized polysiloxane polyalkyleneglycol brush copolymer of the structure [A(-X—B)]as defined herein; and an adhesive, sealant, or coating material comprising said curable composition and use thereof.

Curable composition comprising polysiloxane polyalkyleneglycol brush copolymers

The present invention relates to a procedure in which a functionalized polysiloxane is synthesized in the presence of a platinum catalyst, and halogen-functionalized polysiloxanes obtained according to the procedure. The procedure is defined herein by reacting a) at least one polysiloxane comprising at least one hydrogen atom bonded to a silicon atom; b) at least one heterocyclic compound; and c) at least one halogen-containing compound, wherein the reaction is catalyzed by at least one platinum catalyst. The synthetic pathway is described as a halosilation reaction in which a heterocyclic molecule is ring-opened in the presence of a platinum catalyst and a halogen source, resulting in a formal insertion of the opened heterocycle into the SiH bond. On the final product, the heteroatom of the former heterocycle is bonded to the silicon atom from the former hydrosiloxane moiety while the halogen is bonded to the last carbon atom of the opened chain.

Method for preparing halogen-functionalized polysiloxanes

The present invention relates a hydroxyl-functionalized unimodal polysiloxane polyalkyleneglycol brush copolymer of the structure [A(-X—B)], wherein: A represents said polysiloxane backbone; B represents said polyalkyleneglycol side chain; X is a linker group characterized by including the moiety Si—C—C— of which said Si is a part of the polysiloxane backbone A; and s is an integer of from 1 to 100, wherein the polysiloxane backbone A contains less than 500 ppm mol % of SiH moiety based on the total moles of the silicon atom which constitutes the polysiloxane backbone, and said copolymer has a polydispersity index of from 1.3 to 5.0; and a method for producing said hydroxyl-functionalized unimodal polysiloxane polyalkyleneglycol brush copolymer.

Preparation of polysiloxane polyalkyleneglycol brush copolymers

The invention relates to a curable composition comprising

Paramagnetic titanium mixtures as vulcanization catalysts

The invention relates to a curable composition, containing

Curable silicone compositions

The invention relates to a curable composition comprising: a) at least one polymer having at least one silicon-containing group of formula &#x2014;Si(R)(Y)as defined herein; b) at least one titanium complex of formula TiL(OR)wherein each Ris independently selected from a Calkyl or aryl which may optionally contain one or more heteroatoms, preferably selected from silicon, sulfur, nitrogen or oxygen atoms, wherein preferably Ris selected from n-butyl or isopropyl, and L is a deprotonated, tridentate ligand, and c) optionally at least one compound which has a hydrolyzable silicon-containing group and a weight average molecular weight in the range of 100 to 1000 g/mol, preparations containing these compositions and use thereof.

Titanium complexes as vulcanization catalysts

The invention relates to silane compounds having the general formula (I): SiR(R)(I), as defined herein, to a method for preparing the silane compounds and use thereof as crosslinker or as adhesion promoter and to a curable composition comprising a reaction product of the at least one silane compound, at least one polyorganosiloxane, and at least one catalyst, and use thereof.

Silanes and curable compositions comprising said silanes

The invention relates to a silane of the formula (1),Si(R)(R)(R)&#x2003;&#x2003;(1)as defined herein, where the silane has at least one group of the general formula (3): as defined herein, to a method for preparing the silane, and to curable compositions, containing the silane and at least one polyorganosiloxane.

Silanes and curable compositions containing said silanes as crosslinkers

The invention relates to a curable composition comprising: a) at least one polymer having at least one silicon-containing group of formula &#x2014;Si(R)(Y)as defined herein; b) at least one titanium compound of formula Ti(L)(NX)or Ti(R)(L), where each X is independently a hydrogen atom, a hydrocarbon radical containing 1 to 20 C atoms, which may optionally contain one or more heteroatoms, in particular nitrogen atoms, or a silicon-containing organic group, or two X together with the nitrogen atom to which they are bound form a heterocyclic ring; each L is independently a hydrolyzable oxygen- or nitrogen-containing organic group, in particular an alkoxy group; Ris a hydrocarbon radical containing 1 to 20 C atoms, which may optionally contain one or more heteroatoms, in particular silicon atoms; and m is 1, 2, 3, or 4 and and n is 0, 1, 2, or 3, where m+n=4; and c) optionally at least one compound which has a hydrolyzable silicon-containing group and a molecular weight in the range of 100 to 1000 g/mol, preparations containing these compositions and use thereof.

This disclosure relates to a zinc complex formula (I), as defined herein, to the use of this zinc complex as a catalyst, in particular for the catalysis of a condensation reaction of organosilicon compounds. This disclosure also relates to preparations containing said compounds and to the use thereof.

Growing community of inventors

Langenfeld, Germany

Andrea Gutacker