Basf Se Corporation

Andre Fuchs

Dagmar Pascale Kunsmann-Keitel

Rolf Muelhaupt

Erhard Guenther

Hendrik Wagner

Giovanni D'Andola

Anne Asmacher

Edouard Loisel

Claudia Gisela Cordes

Vitalij Schimpf

Dagmar Pascale Kunsmann-keitel

Described herein are photocurable compositions, (A) a polyester urethane acrylate, or methacrylate (A), (B) an acrylamide, or methacrylamide component (B), and (C) a photoinitiator (C), where the polyester urethane acrylate, or methacrylate (A) is obtained by reacting (A1) a hydroxyalkylacrylate, or hydroxyalkylmethacrylate, (A2) an aliphatic diisocyanate, an aliphatic polyisocyanate, a cycloaliphatic diisocyanate, a cycloaliphatic polyisocyanate, an aromatic diisocyanate, or an aromatic polyisocyanate, or mixtures thereof, (A3) a polyester polyol, and (A4) optionally a second polyol. The compositions, from which cured three-dimensional shaped articles having high toughness, high E modulus and impact strength can be made, are particularly suitable for the production of three-dimensional articles by stereolithography.

Photocurable composition for use in 3D printing

The present invention relates to photocurable compositions, comprising (A1) a N-vinyloxazolidinone of formula (I), wherein R, R, Rand Rare independently of each other a hydrogen atom or an organic group having not more than 10 carbon atoms, (A2) optionally one, or more second reactive diluents, (B) one, or more oligomers, and (C) a photoinitiator (C), wherein the amount of component (A1) is 5 to 70% by weight based on the amount of components (A1), (A2) and (B), wherein the viscosity of said photocurable composition is in the range 10 to 3000 mPa·s, preferably 10 to 1500 mPa·s at 30° C. The compositions, from which cured three-dimensional shaped articles having balanced mechanical properties combining stiffness with high toughness can be made, are particularly suitable for the production of three-dimensional articles by stereolithography and photopolymer jetting.

UV curable composition for use in 3D printing

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Basel, Switzerland

Andre Fuchs