Other

The Sulfa Treat Company

Gas Sweetener Associates, Inc.

Alvin Samuels

Irwin Fox

Delbert C Scranton

Alan D Johnson

Thomas G Braga

Delbert C Scranton Jr

Irwin Fox, Deceased

The present invention relates to a compressed metal oxide composition particle comprised of metal oxide and an organic binder, with the binder preferably being a water insoluble cellulose composition. The present invention also relates to a method for forming a compressed metal oxide composition particle, with the preferred method including compressing a metal oxide and binder mixture to form compressed metal oxide composition particles having a final particle size of between about 0.1 mm and about 200 mm.

Method for removing sulfur compounds from fluids using compressed metal oxide composition particles

Compressed metal oxide composition

The present invention relates to a bound metal oxide particle comprised of metal oxide and a binder, with the binder preferably being a starch solution. The present invention also relates to a method for forming a bound metal oxide particle, with the preferred method including extruding and pelletizing a metal oxide and binder composition to form pelletized metal oxide particles.

Compressed metal oxide product

Bloated minerals previously used as aggregates for light-weight concrete are here fragmented, wetted, and intermixed with particulate chemical reactants or catalysts, to serve as inert carriers therefor in industrial processes. One use is in the deep-bed flow-through process of reacting and removing hydrogen sulfide as contained in natural gas.

Bloated mineral oxide carrier for packed-bed fluid stream chemical

The present invention provides a method for separately removing mercaptans and hydrogen sulfide from a hydrocarbon gas stream by passing the gas through a bed which includes iron oxide which catalyzes the formation of disulfides and trisulfides from mercaptans and also reacts with at least part of the hydrogen sulfide to form acid-stable solids; causing the di- and trisulfides to exit the bed in the gas phase; and removing and recovering the di- and trisulfides by adsorption or condensation. Any remaining hydrogen sulfide may be scavenged from the gas stream by passage through a bed containing iron oxide similar to that used first above. If the gas stream contains substantial amounts of hydrocarbon aerosols, they should be filtered out in advance of the bed.

Separately removing mercaptans and hydrogen sulfide from gas streams

A mineral carrier for those iron oxides which react to remove hydrogen sulfide and mercaptans from fluid streams. The new carrier avoids the problem encountered with wood chip beds of bed solidification which occurs when reacted oxide particles adhere to each other. Calcined montmorillonite, for example, possesses the necessary crush strength, porosity, insolubility in water and wettability, to maintain bed perviousness and avoid caking as reaction continues to the full capacity of the oxide.

Disposable oxide carrier for scavenging hydrogen sulfide

Non-hydrated iron oxides utilized in moistened permeable beds to react hydrogen sulfide present in natural gas do not totally lose their reactivity when the beds give up their moisture to dry gas. Lessening of their reactivity attendant to dryness is signalled by a rise in H.sub.2 S level in the gas at or somewhat in advance of the reactor outlet. On such signal water is injected into the inflowing gas stream, reviving the bed's reactivity and permitting continuation of gas sweetening until the reactive potential of the oxide is substantially fully utilized, with minimal water addition.

Restoring reactivity of gas sweetening oxide beds

Adding sodium sulfite in the slurry of the iron oxide slurry process for scavenging hydrogen sulfide described in U.S. Pat. No. 4,246,244, eliminates excessive foaming on start-up, stabilizes the suspension of the oxide particles in the slurry, lessens clogging of reacted particles, which otherwise interferes with cleaning out the reactor vessel, and so materially buffers the slurry as to minimize corrosion of the reactor vessel and piping. Further, adding small amounts of oxygen to the gas stream, which would be expected to cause corrosion, does not do so; instead it prolongs the usefulness of the reactant oxide particles and affords increased acid-stability to the reaction products.

Sulfite-oxide process for scavenging hydrogen sulfide

A composition suitable for scavenging oxygen from aqueous systems, for example those used in well drilling, is provided which comprises a mixture of an oxygen-reactive sulfite and/or bisulfite (sulfite component) and an amount of iron oxide particles sufficient to catalyze the reaction between oxygen and the sulfite component. These particles have certain properties as further described herein. These compositions also serve as corrosion inhibitors in aqueous systems, such as drilling muds, to protect steel components from corrosion. A method is also provided for using such compositions in aqueous systems to scavenge oxygen from such systems, and also H.sub.2 S, if present.

Scavenging oxygen from aqueous systems

A system of apparatus is especially adapted to react gaseous contaminates of natural gas streams with a slurry of reactant particles and incorporates a contactor tower with a bottom gas inlet having a screen at its dynamic liquid level to confine downwardly a fill of packer-spacer material. Gas entering through the bottom inlet of the tower is divided by the packer-spacer material in tortuous flow paths maintained by the confining screen. In advance of the contactor tower, after an inlet scrubber, is a heater which elevates the temperature of the gas before it enters the contactor tower. This avoids formation of clogging hydrates and liquefication of the gas. Using an outlet scrubber assures against entrance of droplets of any liquid into the pipeline.

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New Orleans, LA, United States of America

Alvin Samuels