3M Innovative Properties Company

Other

Dyneon Gmbh

Allan T Worm

Klaus Hintzer

Erik D Hare

Zai-Ming Qiu

George G I Moore

Miguel Antonio Guerra

Werner Schwertfeger

William D Coggio

Tatsuo Fukushi

Jay F Schulz

Guy Van Gool

Harald Kaspar

Werner M A Grootaert

Greggory S Bennett

Friedrich Kloos

Ralph Kaulbach

Christopher L Gross

Dirk H Arren

Franz M&auml;rz

Douglas S Parker

Paul N Nelson

Franz März

Nikolai Vladimirovich Veretennikov

Margarita Alekseevna Volkova

Sergey Vasilievich Sokolov

Zai-Ming Qui

A compound is prepared, suitable for forming fluoroelastomers, having the unique features of a low glass transition temperature and desirable permeation resistance. The compound generally comprises two primary components. The first component is an amorphous copolymer including interpolymerized units derived from one or more perfluorinated ethers. The second component is a curable component including at least one filler having at least 10 parts per 100 parts of the first component. Upon vulcanization the resulting elastomeric compound has desirable physical characteristics as indicated by the durometer, the retraction at lower temperatures (TR-10) and permeation resistance.

Fluoroelastomers with improved permeation resistance and method for making the same

The present invention is based on quad-fluoropolymer suitable for the preparation of a fluoroelastomer. The fluoropolymer comprises repeating units derived from 10 to 40 mol % of tetrafluoroethylene, 40 to 65 mol % of vinylidene fluoride, 1 to 30 mol % of a perfluorinated vinyl ether of the formula CF&#x2550;CFOCFCFCFOCF, 1 to 20 mol % of perfluoromethyl vinylether.

Fluoroelastomers having low temperature characteristics and solvent resistance

Provided is a co-curable blend comprising (a) a fluoroplastic comprising (i) bromine atoms, iodine atoms, and combinations thereof, and (ii) units derived from a fluorinated monomer, and a peroxide curable fluoroelastomer gum. The invention also provides a composition comprising a fluoroplastic comprising (i) bromine atoms, iodine atoms, and combinations thereof and (ii) units derived from a fluorinated monomer, peroxide curable fluoroelastomer gum, a peroxide curative, and optionally a coagent. The fluoroplastic has an MFI no greater than 5 g/10 min., and/or an average particle size greater than 100 nm. The invention also provides a method of making a fluoropolymer blend and cured articles.

Co-curable blends featuring bromine-and iodine-containing fluoroplastic polymers

Perfluoroelastomers having a low glass transition temperature and method of making them

A method for the preparation of a perfluorinated acid fluoride (especially 3-alkoxy propionic acid fluoride) is provided. The method results in high yields of the acid fluoride.

Perfluorinated acid fluorides and preparation thereof

A fluorocarbon polymer which includes: repeating units derived from one or more perfluorinated ethers of the formula CF,&boxH;CFO&mdash;(CF,),&mdash;(O(CF,),),&mdash;OR,wherein R,is a perfluorinated (C,-C,)alkyl group, m&equals;1-4, n&equals;0-6, and p&equals;1-2; and repeating units derived from vinylidene fluoride; wherein the polymer has a glass transition temperature of &minus;50&deg; C. or lower and an oxygen to carbon ratio of at least about 0.2.

Low temperature fluorocarbon elastomers

The present invention describes a novel process for the preparation of perfluoro allyl ethers. The process involves providing a hydrogen-containing precursor comprising at least one 1,2-dichloro alkyl ether moiety, fluorinating the precursor to provide a perfluorinated intermediate, and dechlorinating the perfluorinated intermediate to the corresponding perfluorinated ether. A reaction product of a perfluorinated olefin and an allyl ether may also be used as a precursor. Such a reaction product is chlorinated before the fluorination step. Perfluoro vinyl or allyl ethers may be used in place of the perfluorinated olefin. Novel perfluoro alkoxy compounds are also described.

Fluorine containing allylethers and higher homologs

The present invention describes a novel process for the preparation of perfluorovinyl ethers. The process involves providing a hydrocarbon precursor that may be partially halogenated, fluorinating the precursor to provide a perfluorinated intermediate, and converting the perfluorinated intermediate to the desired perfluorinated ether. Novel perfluorovinyl ethers are also provided.

Fluorine containing vinyl ethers

Compositions and techniques useful to effectively recycle crosslinked (i.e., vulcanized or cured) fluoroelastomers are disclosed. The invention utilizes an additive system that includes a cure-enhancing additive, a crosslinking agent, and an accelerator.

Recycle of vulcanized fluorinated elastomers

The present invention provides a process of curing a fluorocarbon elastomeric composition comprising: providing a mixture of a saturated elastomeric gum comprising repeating interpolymerized units derived from vinylidene fluoride and a perfluorinated ether of the formula CF.sub.2 .dbd.CF(CF.sub.2).sub.m --O--R.sub..function. wherein m =1-4, R.sub..function. is a perfluorinated aliphatic group optionally containing O atoms, at least one crosslinking agent, and an acid acceptor; shaping the mixture; and curing the resulting shaped article.

Low temperature perfluoroether-containing fluoroelastomers

A compound having the formula: ##STR1## where Q is an onium ion; A.sup.- is a counterion; R.sup.1, R.sup.2, R.sup.3, and R.sup.4, independently, comprise (a) a non-fluorinated alkyl, cycloalkyl, aryl, or aralkyl group; (b) an onium-containing group; or (c) a group having the formula --(CH.sub.2).sub.n --Y--R.sup.5 in which n is at least two; Y is a spacer arm comprising a --CH.sub.2 --, --O--, --OCH.sub.2 --, --S--, --SO.sub.2 --, or --Z--SO.sub.2-- group; Z is an --R.sup.6 --O--, --N(R.sup.7)--, or --N(H)-- group; R.sup.6 is a substituted or unsubstituted phenylene group; R.sup.7 is a non-fluorinated alkyl, cycloalkyl, aryl, or alkaryl group; and R.sup.5 is a fluorinated group, perfluorinated group, or combination thereof, with the proviso that (i) at least one of R.sup.1, R.sup.2, R.sup.3, and R.sup.4 comprises a group having the formula --(CH.sub.2).sub.n --Y--R.sup.5 ; (ii) the total number of fluorine atoms in said compound is at least 5; and (iii) when Q is a sulfonium ion, there is no R.sup.4 group. The invention further includes curable compositions comprising vinylidene fluoride-containing polymers and the above-described compounds, as well as a method for curing such compositions.

Fluorinated onium salts, curable compositions containing same, and

A gum stock composition comprising polyepichlorohydrin gum, polyphenol, organo-onium compound, and acid acceptor is shaped and cured to form shaped elastomeric articles.

Epichlorohydrin elastomer compositions

A thermally stable, curable fluoroelastomer composition containing sulfonium curing agent is described. The composition is curable in reactive admixture with an inorganic acid acceptor and includes:

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North St. Paul, MN, United States of America

Allan T Worm