University of Central Florida Research Foundation Inc

Other

Ali Tabatabaie-Raissi

Nazim Z Muradov

Eric C Martin

Nahid Mohajeri

Gary Bokerman

Franklyn Smith

Philip W Fairey, Iii

Peter H Peng

A (H) sensor composition includes a gas permeable matrix material intermixed and encapsulating at least one chemochromic pigment. The chemochromic pigment produces a detectable change in color of the overall sensor composition in the presence of Hgas. The matrix material provides high Hpermeability, which permits fast permeation of Hgas. In one embodiment, the chemochromic pigment comprises PdO/TiO. The sensor can be embodied as a two layer structure with the gas permeable matrix material intermixed with the chemochromic pigment in one layer and a second layer which provides a support or overcoat layer.

Gas permeable chemochromic compositions for hydrogen sensing

A novel process and apparatus is disclosed for sustainable, continuous production of hydrogen and carbon by catalytic dissociation or decomposition of hydrocarbons at elevated temperatures using in-situ generated carbon particles. Carbon particles are produced by decomposition of carbonaceous materials in response to an energy input. The energy input can be provided by at least one of a non-oxidative and oxidative means. The non-oxidative means of the energy input includes a high temperature source, or different types of plasma, such as, thermal, non-thermal, microwave, corona discharge, glow discharge, dielectric barrier discharge, or radiation sources, such as, electron beam, gamma, ultraviolet (UV). The oxidative means of the energy input includes oxygen, air, ozone, nitrous oxide (NO) and other oxidizing agents. The method, apparatus and process of the present invention is applicable to any gaseous or liquid hydrocarbon fuel and it produces no or significantly less COemissions compared to conventional processes.

Apparatus for hydrogen and carbon production via carbon aerosol-catalyzed dissociation of hydrocarbons

A chemochromic Hsensor includes supports including a plurality of metal oxide particles exclusive of titania, and a platinum group metal (PGM) compound on the supports. The PGM compound is an oxide, hydroxide hydrated oxide, PGM salt or a PGM complex. When the PGM compound is a PGM salt or a PGM complex, the supports can include titania particles.

Chemochromic hydrogen sensors

A method of generating hydrogen includes the steps of providing an amine borane (AB) complex, at least one hydrogen generation catalyst, and a solvent, and mixing these components. Hydrogen is generated. The hydrogen produced is high purity hydrogen suitable for PEM fuel cells. A hydrolytic in-situ hydrogen generator includes a first compartment that contains an amine borane (AB) complex, a second container including at least one hydrogen generation catalyst, wherein the first or second compartment includes water or other hydroxyl group containing solvent. A connecting network permits mixing contents in the first compartment with contents in the second compartment, wherein high purity hydrogen is generated upon mixing. At least one flow controller is provided for controlling a flow rate of the catalyst or AB complex.

Catalytic dehydrogenation of amine borane complexes

Hydrogen production is provided via integrated closed-loop processing of landfill gas (LFG) and solid biomass feedstocks such as various agricultural wastes with minimal environmental impact. LFG is purified of harmful contaminants over a bed of activated charcoal (AC) and is catalytically reformed to synthesis gas, which is further processed to pure hydrogen via CO-shift and pressure-swing adsorption stages. Biomass is gasified in the presence of steam with production of a producer gas and AC. The producer gas is mixed with LFG and is processed to hydrogen as described above. High-surface area AC produced in the gasifier is used for the purification of both LFG and producer gas. An integrated processing of LFG and biomass offers a number of advantages such as a high overall energy efficiency, feedstock flexibility, substantial reduction in greenhouse gas emissions and production of value-added product-biocarbon that can be used as a soil enhancer.

Process for hydrogen production via integrated processing of landfill gas and biomass

A method of generating hydrogen includes the steps of providing an amine borane (AB) complex, at least one hydrogen generation catalyst, and a solvent, and mixing these components Hydrogen is generated. The hydrogen produced is high purity hydrogen suitable for PEM fuel cells. A hydrolytic in-situ hydrogen generator includes a first compartment that contains an amine borane (AB) complex, a second container including at least one hydrogen generation catalyst, wherein the first or second compartment includes water or other hydroxyl group containing solvent. A connecting network permits mixing contents in the first compartment with contents in the second compartment, wherein high purity hydrogen is generated upon mixing. At least one flow controller is provided for controlling a flow rate of the catalyst or AB complex.

A new method for design and scale-up of thermocatalytic processes is disclosed. The method is based on optimizing process energetics by decoupling of the process energetics from the DRE for target contaminants. The technique is applicable to high temperature thermocatalytic reactor design and scale-up. The method is based on the implementation of polymeric and other low-pressure drop support for thermocatalytic media as well as the multifunctional catalytic media in conjunction with a novel rotating fluidized particle bed reactor.

Method and apparatus for decoupled thermo-catalytic pollution control

An apparatus based on optimizing photoprocess energetics by decoupling of the process energy efficiency from the DRE for target contaminants. The technique is applicable to both low- and high-flux photoreactor design and scale-up. An apparatus for high-flux photocatalytic pollution control is based on the implementation of multifunctional metal oxide aerogels and other media in conjunction with a novel rotating fluidized particle bed reactor.

Apparatus for high flux photocatalytic pollution control using a rotating fluidized bed reactor

A new method for design and scale-up of photocatalytic and thermocatalytic processes is disclosed. The method is based on optimizing photoprocess energetics by decoupling of the process energy efficiency from the DRE for target contaminants. The technique is applicable to photo-thermocatalytic reactor design and scale-up. At low irradiance levels, the method is based on the implementation of low pressure drop biopolymeric and synthetic polymeric support for titanium dioxide and other band-gap media. At high irradiance levels, the method utilizes multifunctional metal oxide aerogels and other media within a novel rotating fluidized particle bed reactor.

Apparatus for decoupled thermo-photocatalytic pollution control

A new method for design and scale-up of photocatalytic and thermocatalytic processes is disclosed. The method is based on optimizing photoprocess energetics by decoupling of the process energy efficiency from the DRE for target contaminants. The technique is applicable to both low and high-flux photoreactor design and scale-up. The low-flux method is based on the implementation of natural biopolymeric and other low-pressure drop media support for titanium dioxide and other band-gap photocatalysts. The high-flux method is based on the implementation of multifunctional metal oxide aerogels and other media in conjunction with a novel rotating fluidized particle bed reactor.

Apparatus and method for low flux photocatalytic pollution control

Method and apparatus for decoupled thermo-photocatalytic pollution control

Method for decoupled thermo-catalytic pollution control

A new method for design and scale-up of photocatalytic and thermocatalytic processes is disclosed. The method is based on optimizing photoprocess energetics by decoupling of the process energy efficiency from the DRE for target contaminants. The technique is applicable to both low- and high-flux photoreactor design and scale-up. The low-flux method is based on the implementation of natural biopolymeric and other low-pressure drop media support for titanium dioxide and other band-gap photocatalysts. The high-flux method is based on the implementation of multifunctional metal oxide aerogels and other media in conjunction with a novel rotating fluidized particle bed reactor.

Method for high flux photocatalytic pollution control

A new apparatus for design and scale-up of photocatalytic and thermocatalytic processes is disclosed. The apparatus is based on optimizing photoprocess energetics by decoupling of the process energy efficiency from the DRE for target contaminants and is applicable to both low- and high-flux photoreactor design and scale-up. The low-flux apparatus is based on the implementation of natural biopolymeric and other low-pressure drop media support for titanium dioxide and other band-gap photocatalysts and is further based on the implementation of multifunctional metal oxide aerogels and other media in conjunction with a novel rotating fluidized particle bed reactor.

Growing community of inventors

Melbourne, FL, United States of America

Ali Tabatabaie-Raissi