Eni S.p.a.

Snamprogetti S.p.a.

Eniricerche S.p.a.

Enitecnologie S.p.a.

Agip S.p.a.

Enitechnologie S.p.a.

Alberto Delbianco

Mario Marchionna

Nicoletta Panariti

Romolo Montanari

Sergio Rosi

Ermanno Girardi

Luigi Patron

Salvatore Meli

Giambattista De Ghetto

Fabrizio Stroppa

Sebastiano Correra

A process for converting a heavy charge such as a heavy crude oil, a tar from oil sand and a distillation residue, by combining a hydroconversion with catalysts in slurry phase process, a distillation or flash process, and a deasphalting process, wherein the three processes operate on mixed streams consisting of fresh charge and recycled streams.

Process for the conversion of heavy charges such as heavy crude oils and distillation residues

Process for the extraction of hydrocarbons contained in oil sands and oil shale comprising feeding said oil sands or oil shale to a suitable apparatus in which they are heated, directly and/or by means of a suitable vector fluid, making use of solar energy collected by means of optical concentration systems.

Process for the extraction of hydrocarbons from oil sands and oil shale

A process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues from crude oil or coming from catalytic treatment, visbreaker tars, thermal tars, bitumens from oil sands, liquids from coats of different origins and other high-boiling feedstocks of a hydrocarbon nature known as 'black oils.'

Process for the total conversion of heavy feedstocks to distillates

A process for the conversion of heavy feedstocks using hydrotreatment, distillation or flash, and deasphalting that includes mixing a heavy feedstock with a hydrogenation catalyst and subjecting the thus-formed mixture to a hydrotreatment reactor for reaction with one or more of hydrogen and hydrogen sulfide to form a first product stream; subjecting the first product stream to a distillation or flash to form a plurality of distillate fractions; and recycling heavies from the distillation residue and/or tar by deasphalting in the presence of a solvent; where the hydrotreatment reaction product is pre-separated under high pressure to form light and heavy fractions and sending the heavy fraction to the distillation and/or flash.

Process for the conversion of heavy feedstocks such as heavy crude oils and distillation residues

Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues from crude oil or catalytic treatment, 'visbreaker tars', 'thermal tars', bitumens from &#x201c;oil sands&#x201d; liquids from coals of different origins and other high boiling feedstocks of a hydrocarbon origin.

Process for the conversion of heavy feedstocks selected from heavy crude oils, distillation residues, heavy oils coming from catalytic treatment, thermal tars, oil sand bitumens, various kinds of coals and other high-boiling feedstocks of a hydrocarbon origin known as black oils, by the combined use of the following three process units: hydroconversion with catalysts in slurry phase (HT), distillation or flash (D), and deasphalting (SDA).

Heavy hydrocarbon charges are converted in a deasphalting section in the presence of solvents and obtaining two streams, one consisting of deasphalted oil and the other one containing asphaltenes, mixing the deasphalted oil stream with a hydrogenation catalyst and passing the thus obtained mixture to a hydroprocessing section containing hydrogen or hydrogen/HS, mixing the stream consisting of asphaltenes discharged from the deasphalting section with an appropriate hydrogenation catalyst and passing the obtained mixture to a second hydroprocessing section where it is reacted with hydrogen or a mixture of hydrogen and HS, passing both the stream containing the reaction product with dispersed catalyst from the hydroprocessing section and the stream containing the reaction product with dispersed catalyst from the second hydroprocessing section, to one or more distillation or flash stages, whereby the more volatile fractions are separated from the distillation residue (tar) or from the liquid discharged from the flash unit, sending the distillation residue (tar) or the liquid discharged from the flash unit, containing the catalyst in the dispersed phase, with a high content of metal sulphides, produced by demetallization of the charge, to a second deasphalting section thereby obtaining deasphalted oil and asphaltenes.

The process for the conversion of heavy crude oils or distillation residues to distillates comprises the following steps:

Process for the conversion of heavy crude oils and distillation residues

Process for the dissolution of asphaltene sediments in oil wells which consists in introducing a solubilizing composition for the above asphaltenes into the oil wells, characterized in that the solubilizing composition comprises:

Composition effective in removing asphaltenes

A process for the single-step coal liquefaction is disclosed, which comprises reacting coal in an aqueous suspension with carbon monoxide in the presence of a CO-conversion catalyst selected from the group consisting of an alkaline hydroxide and a carbonate, and in the presence of a hydrogenation catalyst selected from the group consisting of transition metals and compounds thereof, by operating at temperatures within the range of from 300.degree. to 450.degree. C. for a reaction time within the range of from 30 to 80 minutes.

Single-step coal liquefaction process

A process for the single-step coal liquefaction is disclosed, which comprises reacting the coal in an aqueous suspension with carbon monoxide in the presence of a CO-conversion catalyst selected from an alkaline hydroxide or carbonate, wherein the reaction takes place at a temperature maintained for a time of up to about 20 minutes equal to a value selected within the range of from about 300.degree. to 370.degree. C., and then is increased over a time within the range of from about 20 to 40 minutes, until a temperature value is reached, within the range of from about 420.degree. to 450.degree. C. and is kept constant for a time of up to about 20 minutes.

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Robecco sul Naviglio, Italy

Alberto Delbianco