The Standard Oil Company

Ineos USA LLC

Albert R Shuki

Wilfrid G Shaw

Dev D Suresh

Michael J Seely

Maria Strada Friedrich

Edward J Sockell

Louis R Trott

Kenneth P Keckler

Steve J Miko

Vincent G Reiling

Kenneth L Bigler

Paul E Bott

Mark C Cesa

Anne M Graham

Kenneth Keckler

Frank John Kocjancic

Thomas L Szabo

Steven J Rowe

Thomas L Bowman

Frank J Kojancic

A process for the recovery of unreacted ammonia from the effluent from a reaction zone used to produce acrylonitrile or methacrylonitrile comprising quenching the reactor effluent with an aqueous solution of ammonium phosphate in at least two stages, thereby capturing the ammonia component of the effluent. The captured ammonia may be recovered by heating the aqueous ammonium phosphate, which then may be recycled. Contaminants present in the aqueous ammonium phosphate may be removed, for example by solvent extraction or wet oxidation, prior to recycle.

Process for recovery and recycle of ammonia from a vapor stream

A process for upgrading aqueous acrylonitrile waste streams containing organic material comprising atomizing an acrylonitrile waste water stream containing organic material, introducing the atomized acrylonitrile waste water stream at a temperature below the decomposition temperature of the organics present in the waste water stream, into a reaction zone containing a catalyst and at least one reactant gas, reacting the atomized waste water stream and reactant gas in the presence of the catalyst to convert at least some of the organics in the waste water stream into at least one compound selected from the group consisting of acetonitrile, hydrogen cyanide and acrylonitrile.

Oxidation and ammoxidation of acrylonitrile process waste water organics

A process for the substantial or complete elimination of ammonium sulfate generated during the production of acrylonitrile by the direct ammoxidation of propylene/propane, ammonia and an oxygen containing gas (e.g. air) over a fluid bed catalyst wherein the improvement comprises introducing methanol into said reactor in the upper portion of the reactor at a location where the methanol reacts with at least a portion if not substantially all of the excess ammonia without affecting the acrylonitrile yield. Preferably, methanol is introduced into the reactor at below its coking temperature. In particular, when an oxygen lean fluid bed catalyst is utilized, an additional oxygen containing gas is introduced into the reaction at a distance between about 8 to 14 inches from the methanol feed location.

Process for elimination of waste material during manufacture of

A process for the substantial or complete elimination of ammonium sulfate generated during the production of acrylonitrile by the direct ammoxidation of propylene/propane, ammonia and an oxygen containing gas (e.g. air) over a fluid bed catalyst wherein the improvement comprises introducing an organic compound(s) into said reactor at a location where the compound(s) reacts with substantially all of the excess ammonia without affecting the acrylonitrile yield. Preferably, the organic compound is methanol which is introduced into the reactor at below its coking temperature.

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Sagamore Hills, OH, United States of America

Albert R Shuki