Eastman-kodak Company

Nanosystems L.l.c.

Alan R Pitt

Trevor J Wear

Ian M Newington

David Erdtmann

Andrew M Howe

Danuta Gibson

Jeffrey W Leon

Peter John Ghyzel

John H Hone

Dennis E Smith

Jeanne Ellen Kaeding

David J Young

Julian C Caesar

Stephen P Singer

Christine Joanne Landry-Coltrain

Mark Lelental

Thomas W Martin

Gregory E Missell

Bernard A Clark

Gary Norman Barber

Julie Baker

William J Harrison

David A Dickinson

Thomas E Kocher

David R Foster

Alice G Moon

Scott A King

Catherine B Briggs

John F Padday

Paul B Merkel

Mary Christine Brick

Pranab Bagchi

David Darrell Miller

James A Friday

Gregory L McIntire

John W Boettcher

Michael W Orem

Gary W Visconte

Colin J Gray

Sui-Ming Wong

James L Wakley

Joanne S Hunt

F Miguel Joos

Elaine M Liversidge

Elizabeth A Simister

John T Wear

Rachel Richardson

Jack M Shaw

Katie E Adams

Jeanne E Keading

Dennis E Smth

A thermally-responsive dispersant for an aqueous dispersion of positively- or negatively-charged or chargeable solid or liquid particulates, comprises a compound having an anchoring moiety linked to a thermally-responsive polymeric stabilizing moiety, other than a polyalkylene oxide, the polymeric moiety having a lower affinity for the surface than the anchoring group below the thermal transition temperature, the particulates being positively-charged or chargeable when the anchoring moiety contains an acid and/or hydroxy group and has a net acidity or neutrality and the particulates being negatively-charged or chargeable when the anchoring moiety has a basic group and has a net basicity, wherein the dispersion exhibits a change in sign from negative to positive and an increase in magnitude of a rheological property (viscosity at low shear and/or complex modulus at low amplitude oscillatory shear), on increasing the temperature from below to above the thermal transition temperature.

Thermally-responsive dispersants for media formulations

The invention provides a dispersant for an aqueous dispersion of negatively charged or chargeable solid particulates which comprises a compound having an anchoring moiety linked to a polymeric hydrophilic moiety, the anchoring moiety containing at least one basic group and having an overall basicity and the polymeric moiety having a lower affinity for the particulate surface than the anchoring moiety. The invention also provides a coating composition containing the dispersant, an inkjet recording element containing the dispersant and methods of coating or reducing viscosity using the dispersant.

Coating composition containing a dispersant

The invention provides a dispersant for an aqueous dispersion of positively charged or chargeable solid particulates which comprises a compound having an anchoring moiety linked to a polymeric hydrophilic moiety, the anchoring moiety containing at least one acid and/or hydroxy group and having an overall acidity or neutrality and the polymeric moiety having a lower affinity for the particulate surface than the anchoring moiety. The anchoring moiety preferably contains at least two acid groups, preferably carboxylic acid groups, attached either in a [1,1], [1,2] or [1,3] relationship and is linked to the polymeric moiety, which is preferably derived from acrylamide or methacrylamide monomer units, preferably by a sulfur atom. The dispersant can reduce the viscosity of an aqueous dispersion of positively charged or chargeable solid particulates and can reduce the tendency of the resulting dispersion to form a gel or a yield stress material. The dispersant facilitates the processing of the resulting compositions in manufacturing operations and it may be used, for example, as a component of a coating material, a ceramic, paint, refractory material, filler or in an inkjet recording paper or film. Additionally, the dispersant can allow the use of higher concentrations of solid particulates and enable control of the yield stress, as some yield is often beneficial in helping prevent or reduce sedimentation.

Dispersant for reducing viscosity of particulate solids

The invention provides a coating composition containing boehmite particles and a dispersant which comprises a compound having an anchoring moiety linked to a polymeric hydrophilic moiety, the anchoring moiety containing at least one acid and/or hydroxy group and having overall acidity or neutrality and the polymeric moiety having a lower affinity for a boehmite surface than the anchoring moiety. The anchoring moiety preferably contains at least two acid groups, preferably carboxylic acid groups, attached either in a [1,1], [1,2] or [1,3] relationship and is linked to the polymeric moiety, which is preferably derived from acrylamide or methacrylamide monomer units, preferably by a sulfur atom. The dispersant can reduce the viscosity of the boehmite dispersion and the tendency of the boehmite dispersion to increase in viscosity and/or form a gel or a yield stress material following periods of high shear stress.

Coating composition comprising boehmite particles and one or more dispersants and a method of coating a substrate using said coating composition

The invention relates to an image-recording element comprising a support and an image-receiving layer, wherein the image-receiving layer comprises anionic colloidal silica particles, hydrophilic polymeric binder, and fluorosurfactant, wherein the binder is present in an amount of between 2% and 15% weight of the image-receiving layer, the image-recording element has a 60-degree gloss of greater than 25, and a dry time of less than 1 minute.

Image-recording element with fluorosurfactant and colloidal particles

The invention provides a method of making a material, said method comprising generating a foamed hydrophilic polymer solution, especially of a gelatin or derivative thereof, and treating said foamed hydrophilic polymer solution with sufficient energy and for a sufficiently short time that a polymer foam having an open-cell structure is formed. The invention also provides a material comprising a support and an ink receiving layer supported on the support, the ink receiving layer comprising porous hydrophilic polymer, especially gelatin, and is formed by coating a solution of foamed hydrophilic polymer, especially gelatin, onto a support substrate and drying the coated substrate for a time period selected to be short enough such that an open-cell foam is formed.

Foamed material and a method of making a foamed material

The present invention discloses a water dispersible polymer particle stabilized by a hydrophobically capped oligomeric acrylamide dispersant. The present invention also discloses a heterogeneous method for forming polymer particles comprising providing a water immiscible organic phase comprising at least one monomer dispersed in a continuous water phase and a hydrophobically capped oligomeric acrylamide, and polymerizing said organic phase to yield polymer particles stabilized with hydrophobically capped oligomeric acrylamide. Also disclosed in the present invention is a heterogeneous method for forming polymer particles comprising providing a water immiscible organic dispersed in a continuous water phase, polymerizing said organic phase, and adding bydrophobically capped oligomeric acrylamide to yield polymer particles stabilized with hydrophobically capped oligomeric acrylamide.

Polymer particle stabilized by dispersant and method of preparation

The present invention discloses an ink printing method including the steps of:

Ink printing method utilizing stabilized polymeric particles

The invention provides a method of making a material comprising the steps of: coating a support with a solution comprising a polymer, a blowing agent and a surfactant. Either prior to or after the step of coating the support, the solution is interacted with to cause the blowing agent to generate bubbles within the solution causing foaming of the polymer. The surfactant is selected in dependence on whether or not it satisfies one or more predetermined criteria, to control the size of the bubbles.

Method of making a material

A water dispersible polymer particle stabilized by a hydrophobically capped oligomeric acrylamide dispersant or a heterogeneous method for forming polymer particles comprising providing a water immiscible organic phase comprising at least one monomer dispersed in a continuous water phase and a hydrophobically capped oligomeric acrylamide, and polymerizing the organic phase to yield polymer particles stabilized with hydrophobically capped oligomeric acrylamide. Also, a heterogeneous method for forming polymer particles comprising providing a water immiscible organic dispersed in a continuous water phase, polymerizing the organic phase, and adding hydrophobically capped oligomeric acrylamide to yield polymer particles stabilized with hydrophobically capped oligomeric acrylamide.

An ink recording element is described comprising a support having thereon at least one image-receiving layer comprising polymeric particles in a polymeric binder, wherein the polymeric particle is stabilized by a hydrophobically-capped oligomeric acrylamide dispersant.

Ink recording element containing stabilized polymeric particles

Method of making a silver halide photographic material having enhanced light absorption and low fog and containing a scavenger for oxidized developer

Method of making a silver halide photographic material having enhanced light absorption and low fog

A method for measuring the dynamic surface tension (DST) of a proposed outer layer of a liquid composition, to be curtain or slide hopper coated, over a range of surfactant levels to determine the surfactant concentration which produces the maximum resistance to air currents. Measurements are made by the Wilhelmy Blade Method, in which a surface of a pool of composition to be measured is placed in contact with the lower edge of a suspended blade. The static method is modified such that the surface of the composition touching the blade is continually refreshed to simulate the formation of fresh curtain surface by pumping the composition upwards through an open cylinder and allowing the composition to spill over the edges (&ldquo;overflowing weir&rdquo;). The bulk surfactant concentration providing maximum resistance to coated streakiness or mottle is highly correlated with the concentration providing maximum surface tension gradients in the overflowing weir apparatus. Thus, for new or non-optimized air-contact layers, the optimum surfactant concentration can be predicted quickly and inexpensively through off-line measurement of surface tension using the overflowing weir technique.

Coating method with improved coating uniformity by choice of surfactant composition

The present disclosure relates to dispersions of silver (carboxylate-n-alkyl thiolate). The carboxylates are typically silver salts of long chain fatty acids and the n-alkyl thiolate is preferably 1-dodecanethiol. These silver (carboxylate-n-alkyl thiolate) particles can be used to formulate imaging forming compositions that are useful in aqueous thermographic or photothermographic imaging elements.

Silver (carboxylate-n-alkyl thiolate) particles for photothermographic of thermographic imaging

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Sandridge, United Kingdom

Alan R Pitt