Societe Francaise Hoechst

Societe Francaise Hoechst of Tour Roussel-hoechst

Axim

Alain Blanc

Didier Wilhelm

Fernand Cuirassier

Frederic Mabire

Didier Wilheim

Paul Mallo

Yani Christidis

Christian Sidot

Antonio Gelabert

Michel Soreau

Francine J Chastrette

Catherine Fontaine

Farid Hamedi-Sangsari

Gabrielle Claud

A hydraulic-cement setting retarder included in concrete, mortars, or grouts to control setting time as a function of the retarder dosage. Specifically, the retarder is a cyclic amino resin of formula (I): ##STR1## where (a) R1 is a hydrogen atom, a hydroxymethal radial or a group of formula (II)

Setting-retarder and its application to concrete, mortars and/or grouts

Process and use of decahydro pyrazino [2,3-b] pyrazine for the reduction of the proportion of free or combined hydrogen sulphide present in a fluid.

Use of decahydro pyrazino [2,3-b] pyrazine for the reduction of the

Substituted succinimides of formula (I) ##STR1## in which R represents an alkyl radical containing 5 to 15 carbon atoms and R.sub.1 represents an oxo-2 morpholino radical or a (carboxymethyl)(hydroxy-2 ethyl) amino radical and their salts, and use for obtaining concentrates intended for metal-working, particularly for combatting corrosion.

Substituted succinimides as corrosion inhibitors

Diallyloxyacetic acid and its basic addition salts, their preparation process and their application as cross-linking agents. Diallyloxyacetic acid and its basic addition salts, preparation process and application as cross-linking agents.

Method of cross-linking ethylene monomers using diallyloxyacetic acid

Processes for eliminating the diethanolamine present in triethanolamine and the preparation of triethanolamine or compositions containing triethanolamine substantially free from diethanolamine in which the triethanolamine containing diethanolamine is treated with glyoxal in a molar ratio of glyoxal to diethanolamine greater than or equal to 1, then if desired the triethanolamine obtained or the composition containing it is isolated, and their use.

Process for eliminating the diethanolamine present in triethanolamine

Glycerol derivatives of general formula (I) ##STR1## in which R=allyl, methylallyl, acryloyl or methacryloyl, R.sub.1 =R.sub.2 =glyoxyloyl, R.sub.1, R.sub.2 =H, glyoxyloyl; their preparation process, their use as cross-linking agnets and cross-linking or cross-linkable compositions containing them. These compounds are useful as crosslinking agents for woven and non-woven fibrous mats and textiles.

Glycerol derivatives, their preparation process, cross-linking

Glycerol derivatives of general formula (I)

The invention concerns new polyfunctional ethylenic monomers of the general formula (I): ##STR1## where R.sub.1 and R.sub.2 each represent --CHR.sub.3 R.sub.4 where R.sub.3 and R.sub.4 may be identical or different and represent H or an alkyl, alkenyl or aralkyl group. R.sub.1 and R.sub.2 may, alternatively, together form a radical --CH.sub.2 --(CR.sub.5 R.sub.6).sub.n --CHR.sub.7 where n=0 or 1 and R.sub.5, R.sub.6 and R.sub.7 may be identical or different and represent H or CH.sub.3. Particular monomers are:

Polyfunctional ethylenic monomers

The invention concerns new polyfunctional ethylenic monomers of the general formula (I): ##STR1## where R=cyano, substituted or unsubstituted acyl, substituted or unsubstituted alkoxycarbonyl or substituted or unsubstituted aryloxycarbonyl; R.sub.1 and R.sub.2 each represent --CHR.sub.3 R.sub.4 where R.sub.3 and R.sub.4 may be identical or different and represent H or an alkyl, alkenyl or aralkyl group. R.sub.1 and R.sub.2 may, alternatively, together form a radical --CH.sub.2 --(CR.sub.5 R.sub.6).sub.n --CHR.sub.7 where n=0 or 1 and R.sub.5, R.sub.6 and R.sub.7 may be identical or different and represent H or CH.sub.3. Particular monomers are: 2-cyano-4,4-dimethoxy-3-hydroxy-1-butene; 2-cyano-4,4-dibutoxy-3-hydroxy-1-butene; 4,4-dibutoxy-2-ethoxycarbonyl-3-hydroxy-1-butene; 2-butoxycarbonyl-4,4-dibutoxy-3-hydroxy-1-butene; 4,4-dimethoxy-2-hydroxythoxycarbonyl-1-butene; 4,4-dimethoxy-2-dimethylaminoethoxycarbonyl -3-hydroxy-1-butene; and 4,4-dimethoxy-2-ethoxycarbonyl-3-hydroxy-1-butene.

These aqueous dispersions contain a copolymerizate containing 90 to 99% by weight of repeating units resulting from the polymerization of a mixture of monomers (a) based on 0.1 to 10% by weight of alpha,beta-ethylenic mono- and/or di-carboxylic C.sub.3 -C.sub.5 acid and/or their amides, 0 to 10% by weight of styrene and/or acrylonitrile, the remainder of the esters of (meth)acrylic acid with C.sub.1 -C.sub.12 alkanols; and 10 to 1% by weight of repeating units of general formula (I) ##STR1## where R=H or --CH.sub.3, R.sub.1 =H or C.sub.1 -C.sub.4 alkyl and R.sub.2 and R.sub.3 =C.sub.1 -C.sub.8 alkyl or a --CH.sub.2 --CR.sub.4 R.sub.5 --(CH.sub.2).sub.n --group in which n=0 or 1 and R.sub.4 and R.sub.5 =H or --CH.sub.3.

Aqueous dispersions of thermally cross-linkable polymers based on alkyl

They have the formula: ##STR1## where either R.sub.1 and R.sub.2 are identical and represent --CH.sub.2 R where R=H or a C.sub.1 to C.sub.4 alkyl group or R.sub.1 and R.sub.2 together form the --CH.sub.2 (CR.sub.4 R.sub.4).sub.n --CH.sub.2 group where n=0 or 1, R.sub.4 =H or --CH.sub.3, R.sub.3 =H or --CH.sub.2 R.sub.5 where R.sub.5 =H or a C.sub.1 to C.sub.4 alkyl group. A and A.sub.1 are either identical and represent H or A and A.sub.1 together form an ethylene, trimethylene or --CH(OCH.sub.2 R.sub.6)--CH(OCH.sub.2 R.sub.6)-- radical where R.sub.6 =H or a C.sub.1 to C.sub.4 alkyl group or, when R.sub.3 =H, a 1,2 dihydroxy-ethylene group. They are obtained by reacting a disubstituted ethanal ##STR2## with a urea ANH--CO--NHA, followed if required by etherification with an alcohol R.sub.5 CH.sub.2 OH.

Substituted ureas for ennobling cellulose fibres

This process for the preparation of products of general formula (I): ##STR1## wherein either R.sub.1 and R.sub.2, which are identical, represent a --CHRR.sub.3 group, in which R and R.sub.3, which are identical or different, represent an alkyl, alkenyl or aralkyl group, or R.sub.1 and R.sub.2, which are identical, represent a --CH.sub.2 R group, in which R represents a hydrogen atom, an alkyl, alkenyl or aralkyl radical, or R.sub.1 and R.sub.2 together form a --CH.sub.2 --(CRR).sub.n --CHR-- radical, in which n represents 0 or 1 and R retains the meaning given previously, is characterized by reacting glyoxal in the presence of an acid catalyst with an excess of the corresponding alcohol of general formula (II) RR.sub.3 CHOH, (III) RCH.sub.2 OH or (IV) --(CRR).sub.n --CHROH, in which R, R.sub.3 and n retain the meaning given previously, then stopping the reaction as soon as the concentration of the desired monoacetal of general formula (I) decreases in the reaction medium in favor of bisacetal. Application to the preparation of the novel product: 2,2-diallyloxy ethanal.

Process for the preparation of glyoxal monoactals

The invention concerns a process for producing cyclic ureas of the general formula (II): ##STR1## in which R is selected from the group comprising hydrogen atom and C.sub.1 -C.sub.4 alkyl radicals through condensation in aqueous medium at a pH of between 4 and 7 and at a temperature of between 40.degree. and 60.degree. C. of glyoxal with or without excess of a urea having the general formula (I):

Process for producing 4,5-dihydroxy-2-imidazolidinones

Process for producing hydroxyalkylaminoacetic acids having the general formula (I):

Process for producing hydroxyalkylaminoacetic acids

Novel perhydro-[2,3-c]-oxazolo-1,4-oxazines, having the general formula (I): ##STR1## in which R represents a hydrogen atom or a C.sub.1 -C.sub.5 -alkyl radical, and the process for preparation thereof comprising reacting at a temperature lower than 30.degree. C. one mole of glyoxal with one mole of diethanolamine having the general formula (II): ##STR2## in which R has the same meaning as above.

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Paris, France

Alain Blanc