Kao Corporation

Akira Kawamata

Genji Imokawa

Yukihiro Ohashi

Yuji Suzuki

Shinji Yano

Yukihiro Yada

Makoto Torizuka

Masahiko Asahi

Tadayuki Tokunaga

Kazuhiko Higuchi

Mituo Suda

Jouji Okada

Naotake Takaishi

Noboru Nagatani

Taketoshi Fujimori

Shuichi Akazaki

Koji Yoshino

Ken Takeuchi

Yasushi Shioya

Tsutomu Fujimura

Takashi Komori

Yoshinori Takema

Masakazu Yamaguchi

Tsuyoshi Ohtomo

Ayumi Ogawa

Yoshihiro Minematsu

Hiroko Joukura

Mitsuko Zama

Toshiyuki Suzuki

Minoru Nagai

Kazue Tsukahara

Kouichi Niinaka

Shinichi Masuda

Yoko Kikuchi

Shinji Yamada

Minehiro Okuda

Yukiko Sakaino

Hiroshi Kusuoku

Shingo Odajima

Nobuyuki Isshiki

Akira Kiyomine

Masahide Hoshino

Minoru Goto

Michihiro Hattori

Mitsuru Sugiyama

Hideyuki Abe

Hitoshi Otsuka

Hiroyuki Ohsu

Hidetoshi Oga

Koichi Niinaka

Yoko Mastui

A process of producing a wax composition mainly comprising a wax, including the step of mixing the wax and a component to be mixed with the wax by applying an external force at a temperature lower than the melting completion temperature of the wax.

Wax composition and method for production thereof

Provided is a hair dye composition to be used as a mixture of a first part containing an alkali agent and a second part containing an oxidizing agent, wherein the composition comprises (a) a triazacyclononane compound (1) or salt thereof, (b) 0.1 to 12 wt. %, in terms of hydrogen peroxide, of an oxidizing agent, and (c) 0.05 to 10 wt. % of an alkali agent, and the mixture has a pH of from 7.5 to 12. (Rto R: H or Calkyl which may be substituted by OH, Rto R: H, (substituted) Calkyl, (substituted) aralkyl, (substituted) heteroarylalkyl, (substituted) aryl, (substituted) heteroaryl, (substituted) Cacyl, or a group (2) (in which Rto Rrepresents H, Calkyl, aralkyl or aryl and n stands for 2 to 30). The hair dye composition of the present invention has excellent hair bleaching power, can dye the hair into a bright favorable color tone, and moreover has less hair damage and less scalp irritation.

Hairdye composition

Compounds represented by the following general formula: ##STR1## wherein Rf and Rf' mean a perfluoroalkyl group having 1-20 carbon atoms or a (.omega.-H-perfluoroalkyl group represented by the formula H(CF.sub.2).sub.t in which t stands for an integer of 1-20, R.sup.2 denotes a hydrogen atom, a straight-chain or branched aliphatic hydrocarbon group having 1-20 carbon atoms, an alicyclic or aromatic hydrocarbon group having 5-10 carbon atoms, a perfluoroalkyl group having 1-20 carbon atoms, or .omega.-H-perfluoroalkyl group represented by the formula H(CF.sub.2).sub.u - in which u stands for an integer of 1-20, X and Y mean individually a single bond, --CO-- or a divalent hydrocarbon group having 1-6 carbon atoms, l stands for a number of 2-16, and m and n are individually a number of 1-6. The compounds are useful for preparing fluorine-modified silicone derivatives suitable for cosmetic compositions.

Fluoroalkyl substituted ethylenically unsaturated compounds

The present invention is directed to cosmetic compositions containing a fluorine-modified silicon derivative the organopolysiloxane chain which is partly substituted by the siloxane chain of the following general formula (1), (2) or (3) ##STR1## wherein Rf and Rf' mean individually a perfluoroalkyl group having 1-20 carbon atoms or a .omega.-H-perfluoroalkyl group represented by the formula H(CF.sub.2).sub.t -- in which t stands for an integer of 1-20, R.sup.1 may be identical with or different from each other and means a straight-chain or branched aliphatic hydrocarbon group having 1-20 carbon atoms, or an alicyclic or aromatic hydrocarbon group having 5-10 carbon atoms, R.sup.2 denotes a hydrogen atom, a straight-chain or branched aliphatic hydrocarbon group having 1-20 carbon atoms, an alicyclic or aromatic hydrocarbon group having 5-10 carbon atoms, a perfluoroalkyl group having 1-20 carbon atoms, or a .omega.-H-perfluoroalkyl group represented by the formula H(CF.sub.2).sub.u -- in which u stands for an integer of 1-20, R.sup.3 is a divalent hydrocarbon group having 2-16 carbon atoms, X and Y mean individually a single bond, --CO-- or a divalent hydrocarbon group having 1-6 carbon atoms, l stands for a number of 2-16, m and n are individually a number of 1-6, and r is a number of 0-50.

Fluorine-modified silicone derivative, production thereof, and cosmetic

The amide derivative of the present invention is one represented by the following general formula (I) and the dermatologic preparation of the present invention is one containing said amide derivative. ##STR1## wherein R.sup.1 represents a straight-chain or branched, saturated or unsaturated hydrocarbon group carrying 10 to 40 carbon atoms; R.sup.2 represents a straight-chain or branched, saturated or unsaturated hydrocarbon group carrying 3 to 39 carbon atoms; R.sup.3 represents a group containing at least one group represented by the formula: ##STR2## wherein R.sup.4 and R.sup.5 each represents a hydrogen atom or a straight-chain or branched or cyclic, saturated or unsaturated hydrocarbon group, or R.sup.4 and R.sup.5 may form a hydrocarbon group together; and X represents ##STR3##

Amide derivatives and dermatologic preparations containing the same

Amine derivative and dermatologic preparation containing the same

The present invention is directed to a fluorine-modified silicone derivative the organopolysiloxane chain which is partly substituted by the siloxane chain of the following general formula (1), (2) or (3), a preparation process thereof, intermediates useful for the preparation thereof and cosmetic compositions containing this derivative. ##STR1## wherein Rf and Rf' mean individually a perfluoroalkyl group having 1-20 carbon atoms or a .omega.-H-perfluoroalkyl group represented by the formula H(CF.sub.2).sub.t -- in which t stands for an integer of 1-20, R.sup.1 may be identical with or different from each other and means a straight-chain or branched aliphatic hydrocarbon group having 1-20 carbon atoms, or an alicyclic or aromatic hydrocarbon group having 5-10 carbon atoms, R.sup.2 denotes a hydrogen atom, a straight-chain or branched aliphatic hydrocarbon group having 1-20 carbon atoms, an alicyclic or aromatic hydrocarbon group having 5-10 carbon atoms, a perfluoroalkyl group having 1-20 carbon atoms, or a .omega.-H-perfluoroalkyl group represented by the formula H(CF.sub.2).sub.u --in which u stands for an integer of 1-20, R.sup.3 is a divalent hydrocarbon group having 2-16 carbon atoms, X and Y mean individually a single bond, --CO-- or a divalent hydrocarbon group having 1-6 carbon atoms, l stands for a number of 2-16, m and n are individually a number of 1-6, and r is a number of 0-50. Cosmetic compositions containing this compound have excellent water and oil repellency and are also good in lastingness of makeup and feeling upon use.

A composition for external skin care comprising an amine derivative represented by the following formula (1), ##STR1## wherein R.sup.1 is a linear, branched, or cyclic saturated or unsaturated hydrocarbon group having 4-40 carbon atoms, and R.sup.2, R.sup.3, R.sup.4, R.sup.5, and R.sup.6 are individually a hydrogen atom or a hydrocarbon group having 1-10 carbon atoms, which may be substituted or unsubstituted by 1 or more hydroxy groups; or an acid addition salt thereof, in an amount from 0.0001 to less than 0.1% by weight; and a method of curing wrinkles and keratinization of the skin characterized by applying said amine derivative or its salt to the skin.

Composition for external skin care

Fluorine-modified silicone derivative, production thereof and cosmetic

The invention relates to UV absorbers and cosmetic compositions containing a naphthalenemethylenemalonic diester represented by the following formula (1): ##STR1## wherein NAP represents a naphthalene group which may optionally have a substituent, and R.sup.1 and R.sup.2 each independently represent a hydrocarbon group, an alkoxyalkyl group, or an alkoxyalkylenoxyalkyl group. The UV absorbers and the cosmetic compositions of the invention exhibit excellent ultraviolet ray absorbing action, and are stable to light.

Naphthalenemethylenemalonic diesters, and UV absorbers and cosmetic

Silicone derivatives having polysiloxane units represented by the following general formulae (A), (B) and (C): ##STR1## are useful as ingredients in cosmetic compositions.

Cholesteryl silicone derivative and cosmetic composition comprising the

Novel siloxane derivatives represented by general formula (1): ##STR1## A method for producing the siloxane derivatives and agents such as cosmetic preparations, emulsifying dermatotherapeutic external agents and the like including at least one of the siloxane derivatives are also disclosed.

Siloxane derivatives, producing method thereof and agents including

A fluorine-modified silicon compound having a polymerization degree of from 1 to 400 and containing at least one siloxane unit represented by formula (1): ##STR1## wherein R.sup.1 represents an aliphatic straight-chain or branched hydrocarbon group having 1 to 20 carbon atoms or an alicyclic hydrocarbon group having 5 to 10 carbon atoms or an aromatic hydrocarbon compound having 6 to 10 carbon atoms; and m represents 0 or an integer of from 1 to 10; a process for preparing the same; and a cosmetic containing the same are disclosed. The fluorine-modified silicone derivative exhibits high water- and oil-repellency to provide cosmetics which wear long and have a good feel on use.

Fluorine-modified silicone, process for preparing the same, and

Growing community of inventors

Utsunomiya, Japan

Akira Kawamata