Panasonic Intellectual Property Management Co., Ltd.

Akira Kano

Kensuke Nakura

Ryohei Miyamae

Kiyohiro Isii

Nobuhiko Hojo

Junichi Sakamoto

Kazuko Asano

Masahisa Fujimoto

Tooru Matsui

Junko Matsushita

Takayuki Nakatsutsumi

Hirotetsu Suzuki

Go Tei

Shuji Ito

Ryuichi Natsui

Naomi Nishiki

Kiyoshi Kanamura

Kiyohiro Hine

Toshiro Kume

Tsuyoshi Ichinose

Mayumi Maenishi

Tetsuyuki Okano

Masahiro Takahata

Yukihiro Umetani

Shoshi Terada

Suzuki Hirotetsu

A lithium secondary battery including a positive electrode, a negative electrode, a lithium ion conductive nonaqueous electrolyte, and a separator disposed between the positive electrode and the negative electrode; on the negative electrode, a lithium metal deposits at the time of charging, the lithium metal dissolves in the nonaqueous electrolyte at the time of discharging; the nonaqueous electrolyte contains a cation and an anion; the cation includes a lithium ion, and at least one cation X selected from the group consisting of Na, K, Rb, Cs, Fr, Mg, Ca, Sr, Ba, and Al; and the anion includes an oxalate complex anion Y.

Lithium secondary battery

A lithium secondary battery includes a positive electrode, a negative electrode, a lithium ion conductive nonaqueous electrolyte, and a separator disposed between the positive electrode and the negative electrode. On the negative electrode, lithium metal deposits during charging, and the lithium metal is dissolved during discharging; the negative electrode includes a negative electrode current collector, and a plurality of layers stacked on the negative electrode current collector; the plurality of layers include a first layer, a second layer, and a third layer; of the first to third layers, the first layer is closest to the negative electrode current collector, and the third layer is farthest from the negative electrode current collector; the first layer contains a material capable of storing lithium ions; the second layer contains lithium metal, and the third layer has an insulation property and a lithium ion permeability.

A lithium secondary battery according to the present disclosure comprises a cathode, an anode; and a non-aqueous electrolyte having lithium ion conductivity. A lithium metal is precipitated on a surface of the anode during charge of the lithium secondary battery. The lithium metal is dissolved from the surface of the anode in the non-aqueous electrolyte during discharge of the lithium secondary battery. The non-aqueous electrolyte contains a solvent and a lithium salt. The lithium salt includes a first lithium salt and a second lithium salt. The second lithium salt is different from the first lithium salt. The first lithium salt is composed of a lithium ion and an ate complex anion. A sum of concentration of the first lithium salt and the second lithium salt which are contained in the non-aqueous electrolyte is not less than 3.0 mol/L.

Provided is a lithium secondary battery comprising a cathode, an anode, and a non-aqueous electrolyte having lithium ion conductivity. A lithium metal is precipitated on a surface of the anode during charge of the lithium secondary battery. The lithium metal is dissolved from the surface of the anode in the non-aqueous electrolyte during discharge of the lithium secondary battery. The non-aqueous electrolyte contains a solvent and a lithium salt. The solvent includes a fluorinated ether. The fluorinated ether has a fluorination ratio of more than 0% and not more than 60%.

A lithium secondary battery includes a positive electrode, a negative electrode, a separator, and a nonaqueous electrolyte having lithium-ion conductivity. A negative electrode current collector includes a layer having a first surface and a second surface opposite to the first surface, first protrusions protruding from the first surface, and second protrusions protruding from the second surface. The first and second surfaces are surfaces on which lithium metal is deposited during charge. When viewed in a direction of a normal to the first surface, a total area of overlap between the first protrusions and the second protrusions is &#xbd; or less of a total area of the first protrusions.

Lithium secondary battery including nonaqueous electrolyte having lithium-ion conductivity

A lithium secondary battery includes an electrode group and a nonaqueous electrolyte having lithium ion conductivity. A negative electrode includes a negative electrode current collector. The negative electrode current collector has a first surface facing an outward direction of winding of the electrode group and a second surface facing an inward direction of the winding of the electrode group. Lithium metal is deposited on the first surface and the second surface by charge. The negative electrode further includes first protrusions protruding from the first surface and second protrusions protruding from the second surface. A ratio A/Ais greater than a ratio A/A. Ais a sum of projected areas of the first protrusions on the first surface. Ais an area of the first surface. Ais a sum of projected areas of the second protrusions on the second surface. Ais an area of the second surface.

A lithium secondary battery comprises an electrode group and a nonaqueous electrolyte having lithium-ion conductivity. A negative electrode current collector has a first surface facing outward of winding of the electrode group and a second surface facing inward of the winding of the electrode group. At least the first surface or the second surface includes a first region and a second region that is closer to an innermost circumference of the winding of the electrode group than the first region. Protrusions include outer-circumference-side protrusions disposed on the first region and inner-circumference-side protrusions disposed on the second region. In at least the first surface or the second surface, a first area rate is larger than a second area rate.

A lithium secondary battery includes a positive electrode, negative electrode, a separator, and a nonaqueous electrolyte having lithium-ion conductivity. The positive electrode contains a positive electrode active material containing lithium. The negative electrode faces the positive electrode. The separator is disposed between the positive and negative electrodes. The negative electrode includes a negative electrode current collector. The negative electrode current collector includes a layer having a first surface, and protrusions protruding from the first surface. The first surface is a surface on which lithium metal is deposited during charge. The protrusions do not divide the first surface into parts.

A lithium metal secondary battery includes a positive electrode, a negative electrode, a separator, and a nonaqueous electrolyte. The positive electrode and the negative electrode are wound to form an electrode group. The positive and negative electrodes face each other with the separator between the positive and negative electrodes. The electrode group has a space for accommodating at least part of the nonaqueous electrolyte when fully discharged. X and Y satisfy 1.00&#x2264;X/Y&#x3c;1.20, where X is a calculated thickness of the lithium metal which is calculated from design capacity per unit area of the positive electrode, and Y is a virtual thickness of the space when the space is assumed to be formed only between the negative electrode and the separator.

Lithium metal secondary battery and method for producing the same

A cathode active material for magnesium secondary batteries includes a material containing magnesium, boron, and carbon. The material has a layered structure.

Cathode active material containing boron and carbon, and magnesium secondary battery using the same

A lithium secondary battery includes: a positive electrode; a negative electrode; a separator disposed between the positive electrode and the negative electrode; and a nonaqueous electrolyte solution filled between the positive electrode and the negative electrode. The negative electrode includes: an electrically conductive layer having a surface; and lithium metal pieces arranged spaced from each other on the surface of the electrically conductive layer. There is no lithium metal on an imaginary line extending from a first end to a second end opposite to the first end of the surface of the electrically conductive layer and traversing a space between the lithium metal pieces.

Lithium secondary battery including lithium metal as negative electrode active material

A lithium secondary battery includes a positive electrode, a negative electrode, a separator, and a nonaqueous electrolyte having lithium-ion conductivity. The positive electrode contains a positive electrode active material containing lithium. The negative electrode faces the positive electrode. The separator is disposed between the positive and negative electrodes. The negative electrode includes a negative electrode current collector. The negative electrode current collector includes a layer and protrusions. The layer has a first surface on which lithium metal is deposited during charge. The protrusions protrude from the first surface. At least one of the protrusions includes a conductive material and an insulative material.

A lithium secondary battery includes: a positive electrode; a negative electrode including a negative electrode collector having a surface, on which a lithium metal is deposited during charge; a separator disposed between the positive electrode and the negative electrode; and a nonaqueous electrolyte solution filled between the positive electrode and the negative electrode. The negative electrode collector includes projection portions projecting from the surface toward the separator. There is no projection portion on an imaginary line extending from a first end to a second end opposite to the first end of the surface of the negative electrode collector and traversing a space between the projection portions.

A lithium secondary battery includes an electrode group and a nonaqueous electrolyte having lithium ion conductivity. A negative electrode includes a negative electrode current collector. The negative electrode current collector has a first surface facing an outward direction of winding of the electrode group and a second surface facing an inward direction of the winding of the electrode group. Lithium metal is deposited on the first surface and the second surface by charge. The negative electrode further includes first protrusions protruding from the first surface and second protrusions protruding from the second surface. A ratio A/Ais less than a ratio A/A. Ais a sum of projected areas of the first protrusions on the first surface. Ais an area of the first surface. Ais a sum of projected areas of the second protrusions on the second surface. Ais an area of the second surface.

Lithium secondary battery incuding nonaqueous electrolyte having lithium-ion conductivity

A lithium secondary battery comprises an electrode group and a nonaqueous electrolyte having lithium-ion conductivity. A negative electrode current collector has a first surface facing outward of winding of the electrode group and a second surface facing inward of the winding of the electrode group. At least the first surface or the second surface includes a first region and a second region that is closer to an innermost circumference of the winding of the electrode group than the first region. Protrusions include outer-circumference-side protrusions disposed on the first region and inner-circumference-side protrusions disposed on the second region. A first average height of the outer-circumference-side protrusions is smaller than a second average height of the inner-circumference-side protrusions.

Growing community of inventors

Osaka, Japan

Akira Kano